[특허]Catalyst structure and method of Fischer-Tropsch synthesis

Catalyst structure and method of Fischer-Tropsch synthesis 원문보기

IPC분류정보
국가/구분	United States(US) Patent 등록
국제특허분류(IPC7판)	C07C-027/00 B01J-023/00 B01J-023/56
출원번호	US-0375610 (1999-08-17)
발명자 / 주소	Yong Wang David P. Vanderwiel Anna Lee Y. Tonkovich Yufei Gao Eddie G. Baker
출원인 / 주소	Battelle Memorial Institute
대리인 / 주소	Paul W. Zimmerman
인용정보	피인용 횟수 : 49 인용 특허 : 16

초록 ▼

The present invention includes a catalyst structure and method of making the catalyst structure for Fischer-Tropsch synthesis that both rely upon the catalyst structure having a first porous structure with a first pore surface area and a first pore size of at least about 0.1 .mu.m, preferably from about 10 .mu.m to about 300 .mu.m. A porous interfacial layer with a second pore surface area and a second pore size less than the first pore size is placed upon the first pore surface area. Finally, a Fischer-Tropsch catalyst selected from the group consisting of cobalt, ruthenium, iron and combinations thereof is placed upon the second pore surface area. Further improvement is achieved by using a microchannel reactor wherein the reaction chamber walls define a microchannel with the catalyst structure placed therein through which pass reactants. The walls may separate the reaction chamber from at least one cooling chamber. The present invention also includes a method of Fischer-Tropsch synthesis.

대표청구항 ▼

1. A method of Fischer-Tropsch reaction, comprising the steps of:(a) providing a catalyst structure having a first porous structure with a first pore surface area and a first pore size of at least about 0.1 .mu.m; a porous interfacial layer with a second pore surface area and a second pore size less than said first pore size, said porous interfacial layer placed upon said first pore surface area; a Fischer-Tropsch catalyst selected from the group consisting of cobalt, ruthenium, iron, rhenium, osmium and combinations thereof placed upon said second pore surface area; and (b) passing a feed stream having a mixture of hydrogen gas with carbon monoxide gas through said catalyst structure and heating said catalyst structure to at least 200.degree. C. at an operating pressure, said feed stream having a residence time within said catalyst structure less than 5 seconds, thereby obtaining a product stream of at least 25% conversion of carbon monoxide, and at most 25% selectivity toward methane.

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Kim Chang J. (Seoul KRX), Water addition for increased CO/H₂ hydrocarbon synthesis activity over catalysts comprising cobalt, ruthen.
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IPC	Description
A	생활필수품
A62	인명구조; 소방(사다리 E06C)
A62B	인명구조용의 기구, 장치 또는 방법(특히 의료용에 사용되는 밸브 A61M 39/00; 특히 물에서 쓰이는 인명구조 장치 또는 방법 B63C 9/00; 잠수장비 B63C 11/00; 특히 항공기에 쓰는 것, 예. 낙하산, 투출좌석 B64D; 특히 광산에서 쓰이는 구조장치 E21F 11/00)
A62B-1/08	.. 윈치 또는 풀리에 제동기구가 있는 것

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연합인증

Catalyst structure and method of Fischer-Tropsch synthesis 원문보기

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이 특허를 인용한 특허 (49)

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Catalyst structure and method of Fischer-Tropsch synthesis 원문보기

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