초록 ▼

Ozone is used to rapidly oxidize specific metallic elements. The insoluble oxidized compounds of the metals formed by the ozonation are then recovered for industrial use in a conventional sedimentation/filtration tank or pool. There is no requirement for pre-treating or neutralizing the acid mine di

Ozone is used to rapidly oxidize specific metallic elements. The insoluble oxidized compounds of the metals formed by the ozonation are then recovered for industrial use in a conventional sedimentation/filtration tank or pool. There is no requirement for pre-treating or neutralizing the acid mine discharge, even when iron is the dominant metal. If the pH of the untreated acid mine discharge is less than about 2.5, metals other than iron precipitated first. After that, the pH is raised and the iron is precipitated as ferric hydroxide. Aluminum is removed as hydrated aluminum compounds after removal of the iron prior to discharging the acid mine discharge to streams. Both the ozonation and neutralization processes are monitored and controlled using electrochemical sensors and feedback controllers.

대표청구항 ▼

1. A method for removing or recovering at least one metal as an insoluble compound, said at least one metal being selected from the group consisting of iron, manganese, lead, silver, nickel, cobalt, palladium, bismuth, and thallium, from acidic wastewater containing said at least one metal in soluti

1. A method for removing or recovering at least one metal as an insoluble compound, said at least one metal being selected from the group consisting of iron, manganese, lead, silver, nickel, cobalt, palladium, bismuth, and thallium, from acidic wastewater containing said at least one metal in solution as metal ion, consisting of:introducing ozone into the acidic waste water to form insoluble oxidized compounds of the metals while monitoring the Eh and the pH values of the waste water and adjusting the amount of ozone introduced to maintain an Eh and a pH at which ozone can form an insoluble metal oxide with each metal ion in the acidic wastewater.