IPC분류정보
국가/구분 |
United States(US) Patent
등록
|
국제특허분류(IPC7판) |
|
출원번호 |
US-0575094
(2000-05-19)
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발명자
/ 주소 |
- Yang, Hu
- Ching, Ta Yen
- Cai, Gangfeng
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출원인 / 주소 |
- Chevron Phillips Chemical Company LP
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대리인 / 주소 |
Williams, Morgan & Amerson, P.C.
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인용정보 |
피인용 횟수 :
17 인용 특허 :
38 |
초록
▼
Herein is disclosed an oxygen barrier composition comprising ethylene/vinyl alcohol copolymer (EVOH), an oxygen scavenging polymer, and a transition metal salt. The composition can be in the form of a physical blend or a cross-linked blend, and can further comprise a compatibilizer, a transesterific
Herein is disclosed an oxygen barrier composition comprising ethylene/vinyl alcohol copolymer (EVOH), an oxygen scavenging polymer, and a transition metal salt. The composition can be in the form of a physical blend or a cross-linked blend, and can further comprise a compatibilizer, a transesterification catalyst, or both. Also disclosed is a packaging article comprising at least one high oxygen barrier layer comprising the blend of EVOH, the oxygen scavenging polymer, and the transition metal salt. The packaging article can be a single-layer or a multilayer article, and can be flexible or rigid. A multilayer packaging article can further comprise a structural layer or layers, an oxygen barrier layer, an oxygen scavenging layer, an oxygen permeable layer or layers, or an adhesive layer or layers, among others. In addition, herein is disclosed a method of making the blend of EVOH, the oxygen scavenging polymer, and the transition metal salt, comprising providing and blending the materials. The blend can be used in a method of making an oxygen scavenging packaging article.
대표청구항
▼
Herein is disclosed an oxygen barrier composition comprising ethylene/vinyl alcohol copolymer (EVOH), an oxygen scavenging polymer, and a transition metal salt. The composition can be in the form of a physical blend or a cross-linked blend, and can further comprise a compatibilizer, a transesterific
Herein is disclosed an oxygen barrier composition comprising ethylene/vinyl alcohol copolymer (EVOH), an oxygen scavenging polymer, and a transition metal salt. The composition can be in the form of a physical blend or a cross-linked blend, and can further comprise a compatibilizer, a transesterification catalyst, or both. Also disclosed is a packaging article comprising at least one high oxygen barrier layer comprising the blend of EVOH, the oxygen scavenging polymer, and the transition metal salt. The packaging article can be a single-layer or a multilayer article, and can be flexible or rigid. A multilayer packaging article can further comprise a structural layer or layers, an oxygen barrier layer, an oxygen scavenging layer, an oxygen permeable layer or layers, or an adhesive layer or layers, among others. In addition, herein is disclosed a method of making the blend of EVOH, the oxygen scavenging polymer, and the transition metal salt, comprising providing and blending the materials. The blend can be used in a method of making an oxygen scavenging packaging article. itiator. 15. The composition of claim 14; wherein the photoinitiator is selected from benzophenone derivatives containing at least two benzophenone moieties and having the formula: Aa(B)b wherein A is a bridging group selected from sulfur; oxygen; carbonyl; --SiR"2--, wherein each R" is individually selected from alkyl groups containing from 1 to 12 carbon atoms, aryl groups containing 6 to 12 carbon atoms, or alkoxy groups containing from 1 to 12 carbon atoms; --NR'"--, wherein R'" is an alkyl group containing 1 to 12 carbon atoms, an aryl group containing 6 to 12 carbon atoms, or hydrogen; or an organic group containing from 1 to 50 carbon atoms; a is an integer from 0 to 11; B is a substituted or unsubstituted benzophenone group; and b is an integer from 2 to 12. 16. The composition of claim 15, wherein the photoinitiator is selected from dibenzoyl biphenyl, substituted dibenzoyl biphenyl, benzoylated terphenyl, substituted benzoylated terphenyl, tribenzoyl triphenylbenzene, substituted tribenzoyl triphenylbenzene, benzoylated styrene oligomer, or substituted benzoylated styrene oligomer. 17. The composition of claim 1, further comprising an antioxidant. 18. The composition of claim 17, wherein the antioxidant is selected from 2,6-di(t-butyl)-4-methylphenol(BHT), 2,2'-methylene-bis(6-t-butyl-p-cresol), triphenylphosphite, tris-(nonylphenyl)phosphite, vitamin E, tetra-bismethylene 3-(3,5-ditertbutyl-4-hydroxyphenyl)-propionate methane, or dilaurylthiodipropionate. 19. The composition of claim 1, further comprising a structural polymer. 20. The composition of claim 19, wherein the structural polymer is selected from polyethylene, low density polyethylene, very low density polyethylene, ultra-low density polyethylene, high density polyethylene, polyethylene terephthalate (PET), polyvinyl chloride, ethylene-vinyl acetate, ethylene-alkyl (meth)acrylates, ethylene-(meth)acrylic acid, or ethylene-(meth)acrylic acid ionomers. 21. The composition of claim 20, wherein the structural polymer is PET.
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