Oxygen storing material with high thermal stability and a process for preparation and use thereof
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
B01J-008/00
B01J-023/00
출원번호
US-0056795
(1998-04-08)
우선권정보
DE-0014707 (1997-04-09)
발명자
/ 주소
Mussmann, Lothar
Van Yperen, Renee
Lindner, Dieter
Kreuzer, Thomas
Lox, Egbert
출원인 / 주소
Degussa Aktiengesellschaft
대리인 / 주소
Kalow & Springut LLP
인용정보
피인용 횟수 :
14인용 특허 :
10
초록▼
An oxygen storing material with high thermal stability is disclosed which contains cerium oxide and at least one stabilizer from the group praseodymium oxide, lanthanum oxide, yttrium oxide and neodymium oxide, wherein the stabilizer(s) and optionally cerium oxide are present in highly dispersed for
An oxygen storing material with high thermal stability is disclosed which contains cerium oxide and at least one stabilizer from the group praseodymium oxide, lanthanum oxide, yttrium oxide and neodymium oxide, wherein the stabilizer(s) and optionally cerium oxide are present in highly dispersed form on the specific surface area of a high surface area support material from the group aluminum oxide, zirconium oxide, titanium oxide, silicon dioxide, cerium oxide and mixed oxides thereof and the oxygen storing material still has a specific surface area of more than 20, preferably more than 30 m2/g, after calcination in air at 900° C. for a period of 10 hours.
대표청구항▼
An oxygen storing material with high thermal stability is disclosed which contains cerium oxide and at least one stabilizer from the group praseodymium oxide, lanthanum oxide, yttrium oxide and neodymium oxide, wherein the stabilizer(s) and optionally cerium oxide are present in highly dispersed for
An oxygen storing material with high thermal stability is disclosed which contains cerium oxide and at least one stabilizer from the group praseodymium oxide, lanthanum oxide, yttrium oxide and neodymium oxide, wherein the stabilizer(s) and optionally cerium oxide are present in highly dispersed form on the specific surface area of a high surface area support material from the group aluminum oxide, zirconium oxide, titanium oxide, silicon dioxide, cerium oxide and mixed oxides thereof and the oxygen storing material still has a specific surface area of more than 20, preferably more than 30 m2/g, after calcination in air at 900° C. for a period of 10 hours. 10. The reformer according to claim 9, wherein said one or more catalyst components contain a heat-resistant oxide and at least one metal element selected from the group consisting of those of groups VB to VIII, IB and IIB of the long-form periodic table. 11. The reformer according to claim 10, wherein said at least one metal element is at least one of those selected from the group consisting of metal elements of group VIII, V, Cr, Mo, W, Re, metal elements of group IB, and Zn. 12. The reformer according to claim 10, wherein said heat-resistant oxide is selected from the group consisting of Al2O3,SiO2,TiO2,ZrO2,MgO, zeolite, SAPO, ALPO, a layer structure compound and a compound oxide thereof. 13. The reformer according to claim 1, wherein one of said two or more catalyst units disposed at the most upstream position is positioned just after and downstream from said inlet for a feed reactant fluid whereby the catalyst treats only said feed reactant fluid. 14. A reformer for generating hydrogen from a reactant fluid containing an organic compound or carbon monoxide disposed in the flow path of a reactant fluid wherein the reactant fluid flows from an upstream position to a downstream position, said reformer comprising a reactant fluid supply means for supplying a hydrogen generating reactant fluid containing an organic compound or carbon monoxide, an inlet connected to said reactant fluid supply means for feeding said reactant fluid to said reformer, two or more catalyst units of a honeycomb structure in series in the reformer for generating hydrogen from the reactant fluid containing an organic compound or carbon monoxide, by catalysis, and an outlet for a reformed gas containing hydrogen downstream of the catalyst units , wherein at least two of said two or more catalyst units satisfy the following relationship: Cell density of the upstream-side catalyst unit
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이 특허에 인용된 특허 (10)
Brandenburg John T. (Port Neches TX) Crone ; Jr. John M. (Fishkill NY), Alumina catalyst stable at high temperatures.
Shelef Mordecai (Bloomfield Village MI) Usmen Rengin K. (Troy MI) Graham George W. (Ann Arbor MI) Watkins William L. H. (Toledo OH) McCabe Robert W. (Lathrup Village MI), Automotive catalysts with improved oxygen storage and metal dispersion.
Blanchard Gilbert,FRX ; Quemere Eric,FRX ; Touret Olivier,FRX ; Visciglio Valerie,FRX, Catalytic composition comprising a mixture of cerium oxide with manganese, iron or praseodymium oxide, process for its p.
Chopin Thierry (Saint Denis FRX) Vilmin Gabriel (Princeton NJ), Zirconium/cerium mixed oxide catalyst/catalyst support compositions having high/stable specific surfaces.
Taguchi,Kiyoshi; Ukai,Kunihiro; Wakita,Hidenobu; Fujihara,Seiji, CO removal catalyst, method of producing CO removal catalyst, hydrogen purifying device and fuel cell system.
Larcher, Olivier; Rohart, Emmanuel, Compositions based on cerium oxide, zirconium oxide and, optionally, another rare earth oxide, having a specific raised surface at 1100° C, method for the production and use thereof as a catalyst.
Yokota, Kazuhiko; Ohtake, Naotaka, High specific surface area mixed oxide of cerium and of another rare earth, preparation method and use in catalysis.
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