SOx tolerant NOx trap catalysts and methods of making and using the same
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
B01D-053/56
출원번호
US-0771280
(2001-01-26)
발명자
/ 주소
Wu, Joseph H-Z.
Dettling, Joseph C.
출원인 / 주소
Engelhard Corporation
대리인 / 주소
Negin, Richard A.
인용정보
피인용 횟수 :
14인용 특허 :
10
초록▼
The present invention relates to sulfur tolerant catalyst composites useful for reducing contaminants in exhaust gas streams, especially gaseous streams containing sulfur oxide contaminants. More specifically, the present invention is concerned with improved NOx trap catalysts for use in diesel engi
The present invention relates to sulfur tolerant catalyst composites useful for reducing contaminants in exhaust gas streams, especially gaseous streams containing sulfur oxide contaminants. More specifically, the present invention is concerned with improved NOx trap catalysts for use in diesel engines as well as lean burn gasoline engines. The sulfur tolerant NOx trap catalyst composites comprise a platinum component, a support, and a NOx sorbent component prepared by hydrothermal synthesis. The NOx sorbent component comprises a first metal oxide and a second metal oxide. The metal in the first metal oxide is selected from the group consisting of aluminum, titanium, zirconium, silicon, and composites thereof, and the metal in the second metal oxide is selected from the group consisting of Group IIA metals, Group III metals, Group IV metals, rare earth metals, and transition metals. The metal in the first metal oxide is different from the metal in the second metal oxide. The sulfur tolerant NOx trap catalyst composites are highly effective with a sulfur containing fuel by trapping sulfur oxide contaminants which tend to poison conventional NOx trap catalysts. The sulfur tolerant NOx trap catalyst composites are particularly suitable for diesel engines because the composites can be regenerated at moderate temperatures with rich pulses, rather than at high temperatures.
대표청구항▼
The present invention relates to sulfur tolerant catalyst composites useful for reducing contaminants in exhaust gas streams, especially gaseous streams containing sulfur oxide contaminants. More specifically, the present invention is concerned with improved NOx trap catalysts for use in diesel engi
The present invention relates to sulfur tolerant catalyst composites useful for reducing contaminants in exhaust gas streams, especially gaseous streams containing sulfur oxide contaminants. More specifically, the present invention is concerned with improved NOx trap catalysts for use in diesel engines as well as lean burn gasoline engines. The sulfur tolerant NOx trap catalyst composites comprise a platinum component, a support, and a NOx sorbent component prepared by hydrothermal synthesis. The NOx sorbent component comprises a first metal oxide and a second metal oxide. The metal in the first metal oxide is selected from the group consisting of aluminum, titanium, zirconium, silicon, and composites thereof, and the metal in the second metal oxide is selected from the group consisting of Group IIA metals, Group III metals, Group IV metals, rare earth metals, and transition metals. The metal in the first metal oxide is different from the metal in the second metal oxide. The sulfur tolerant NOx trap catalyst composites are highly effective with a sulfur containing fuel by trapping sulfur oxide contaminants which tend to poison conventional NOx trap catalysts. The sulfur tolerant NOx trap catalyst composites are particularly suitable for diesel engines because the composites can be regenerated at moderate temperatures with rich pulses, rather than at high temperatures. ratively coupled to at least one said fluid inlet for at least one of spraying fluid onto and flushing fluid through a lumen of a medical instrument disposed in said reprocessing chamber; (b) at least one chemical sterilant component container; (c) at least one sterilant conduit extending between and fluidly coupling said at least one chemical sterilant component container to said reprocessing chamber; (d) at least one water conduit fluidly coupling a water supply to at least one of said reprocessing chamber, said at least one chemical sterilant component container, and the conduits extending therebetween; (e) a transfer control system for selectively transferring at least one chemical sterilant component from said at least one chemical sterilant component container to said reprocessing chamber, and for selectively transferring water from a water supply through said at least one water conduit; (f) a reaction vessel; and wherein at least one said sterilant conduit extends between and fluidly couples each said chemical sterilant component container to said reaction vessel, at least one said sterilant conduit extends between and fluidly couples said reaction vessel and said reprocessing chamber; and the transfer control system selectively transfers at least one chemical sterilant component from said at least one chemical sterilant component container to said reaction vessel, and selectively transfers sterilant from said reaction vessel to said reprocessing chamber; and (g) a
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