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A process for forming microcapsules having substantially impermeable microcapsule walls comprising the steps of: forming an emulsion of an internal phase in a continuous aqueous phase, the internal phase including a photosensitive composition and a polyvalent isocyanate, the continuous aqueous phase

A process for forming microcapsules having substantially impermeable microcapsule walls comprising the steps of: forming an emulsion of an internal phase in a continuous aqueous phase, the internal phase including a photosensitive composition and a polyvalent isocyanate, the continuous aqueous phase including a sulfonated polystyrene, at least one of the internal phase or the continuous aqueous phase further including a hydrophilic polymer; and enwrapping particles of the internal phase in an amine-formaldehyde condensation product produced by in situ condensation of an amine and formaldehyde is disclosed.

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1. A process for forming microcapsules having substantially impermeable microcapsule walls comprising the steps of: forming an emulsion of an internal phase in a continuous aqueous phase, said internal phase including a photosensitive composition and a polyvalent isocyanate, said continuous aqueo

1. A process for forming microcapsules having substantially impermeable microcapsule walls comprising the steps of: forming an emulsion of an internal phase in a continuous aqueous phase, said internal phase including a photosensitive composition and a polyvalent isocyanate, said continuous aqueous phase including a sulfonated polystyrene, a polygalacturonic acid and an additional hydrophilic polymer; and enwrapping particles of said internal phase in an amine-formaldehyde condensation product produced by in situ condensation of an amine and formaldehyde, whereby said hydrophilic polymer becomes incorporated into said microcapsule walls thereby improving humidity stability of said microcapsules. 2. The process according to claim 1 wherein said polygalacturonic acid is pectin. 3. The process of claim 1 wherein said hydrophilic polymer is selected from the group consisting of gelatin, gelatin derivatives, gum arabic, starch, cellulose derivatives and combinations thereof. 4. The process of claim 3 wherein said hydrophilic polymer is gelatin. 5. The process of claim 1 wherein said amine is urea or melamine. 6. The process of claim 1 wherein said photosensitive composition is a photopolymerizable composition. 7. The process of claim 6 wherein said photopolymerizable composition contains an ethylenically unsaturated compound. 8. Process for forming photosensitive amine-formaldehyde microcapsules having substantially impermeable walls comprising the steps of: emulsifying a photosensitive hydrophobic oil containing a polyvalent isocyanate in a continuous aqueous phase containing a sulfonated polystyrene, a polygalacturonic acid and a hydrophilic polymer selected from the group consisting of gelatine, gum arabic, starch, cellulose and combinations thereof, wherein said polyvalent isocyanate reacts with water of said aqueous phase to form a substantially impermeable pre-wall around droplets of said hydrophobic oil; and enwrapping the pre-wall coated droplets of said hydrophobic oil in an amineformaldehyde condensation product produced by in situ condensation of an amine and formaldehyde, wherein said hydrophilic polymer is incorporated into said microcapsule walls thereby improving the humidity stability of said microcapsules. 9. The process of claim 8 wherein said amine is melamine. 10. The process of claim 8 wherein said hydrophilic polymer is gelatin. 11. The process of claim 8 wherein said polygalacturonic acid is pectin. 12. The process of claim 8 wherein said photosensitive hydrophobic oil comprises a monomer and said hydrophilic polymer is present in said aqueous phase in an amount of about 0.01 to 10% by weight based on said monomer. 13. The process of claim 12 wherein said hydrophilic polymer is present in said aqueous phase in an amount of about 0.15 to 3% by weight based on said monomer. 14. The process of claim 13 wherein said hydrophilic polymer comprises gelatin.