초록 ▼

A process for burning coal to produce substantially pure hydrogen for use in fuel cells, together with "sequestration ready" carbon dioxide and a stream of oxygen depleted air for powering gas turbines, characterized by using a combination of two fluidized bed reactors and a third transfer line reac

A process for burning coal to produce substantially pure hydrogen for use in fuel cells, together with "sequestration ready" carbon dioxide and a stream of oxygen depleted air for powering gas turbines, characterized by using a combination of two fluidized bed reactors and a third transfer line reactor, the first reactor being supplied with coal particles or "char" and fluidized with high temperature steam; the second reactor being fluidized with high temperature steam and the third reactor being fluidized by compressed air. Solids circulated among these three reactors include a mixture of materials containing calcium compounds (present as CaO, CaCO3and mixtures thereof) and iron compounds (present as FeO, Fe2O3and mixtures thereof). The coal is gasified by the steam in the presence of CaO to produce CaCO3and relatively pure hydrogen for use in fuel cells per a CO2acceptor process. Because only part of the coal char input to the first reactor is gasified to produce hydrogen, the remainder can be burned to supply thermal energy necessary to regenerate the CaCO3back to CaO. Carbon in the middle bed fluidized bed reactor reacts with Fe2O3in the third reactor and the temperature in the middle fluidized bed reactor is sufficiently high to decompose CaCO3back into CaO.

대표청구항 ▼

1. A process for converting coal into fuel cell quality hydrogen and sequestration-ready carbon dioxide using unmixed combustion, comprising the steps of charging a first fluidized bed reactor with coal and high temperature steam which oxidizes a portion of the coal and produces substantially pur

1. A process for converting coal into fuel cell quality hydrogen and sequestration-ready carbon dioxide using unmixed combustion, comprising the steps of charging a first fluidized bed reactor with coal and high temperature steam which oxidizes a portion of the coal and produces substantially pure hydrogen gas and carbon dioxide; circulating a mixture of solids among said first reactor and second and third reactors containing coal, calcium compounds present as CaO, CaCO3,and mixtures thereof, and iron compounds present as FeO, Fe2O3and mixtures thereof; reacting the CaO present in said first reactor with carbon dioxide to form CaCO3; reacting the CaCO3in said second reactor to regenerate CaO while reacting coal and/or coal char with Fe2O3to form FeO and carbon dioxide; oxidizing the FeO present in said third reactor to regenerate Fe2O3and produce oxygen depleted air at an elevated temperature; and withdrawing substantially pure hydrogen, carbon dioxide and oxygen depleted air in separate streams from said first, second and third reactors. 2. The process according to claim 1, wherein the solids in said second reactor are fluidized using high temperature steam and the solids in said third reactor are fluidized using compressed air. 3. The process of claim 1, wherein the temperature in the first reactor is in the range 650° C. to 850° C. 4. The process of claim 1, wherein the temperature in the second reactor is in the range 1000° C. to 1100° C. 5. The process of claim 1, wherein the temperature in the third reactor is in the range 1400° C. to 1600° C. 6. The process of claim 1, wherein the pressure in the reactor system as a whole is in the range 2 to 20 atmospheres. 7. The process of claim 1, wherein the ratio of calcium atoms (present as CaO/CaCO3) to iron (present as FeO/Fe2O3) in said solids circulating between said fluidized beds is between 1.5 and 2. 8. The process of claim 1, wherein the rate of solids circulation between the second and third reactors is such that the ratio of FeO entering the third reactor to oxygen in the air entering the third reactor is greater than 4 moles of FeO to 1 mole of O2but less than 5 moles of FeO to 1 mole of oxygen. 9. The process of claim 1, wherein the pressure of said superheated steam is about 7 atmospheres. 10. The process of claim 1, wherein said oxygen depleted air at elevated temperature is used to generate electricity by expanding the heated air through a downstream gas turbine engine.