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This is a hydrogen generation process for use with fuel cells which includes a preferential oxidation step to reduce the concentration of carbon monoxide. The preferential oxidation step includes contacting a fuel stream comprising hydrogen and carbon monoxide in the presence of an oxygen at a prefe

This is a hydrogen generation process for use with fuel cells which includes a preferential oxidation step to reduce the concentration of carbon monoxide. The preferential oxidation step includes contacting a fuel stream comprising hydrogen and carbon monoxide in the presence of an oxygen at a preferential oxidation temperature of between about 70° and about 160° C. with preferential oxidation catalyst for reducing the concentration of carbon monoxide to produce a treated fuel gas stream comprising less than about 50 ppm-vol carbon monoxide. The preferential oxidation catalyst comprises ruthenium metal dispersed on a shaped alumina carrier, wherein at least 60 percent of the ruthenium metal is present in a band extending from the surface towards the center and having a width of about 50 percent of the distance from the surface to the center of the shaped alumina carrier. Superior performance at low preferential oxidation temperatures below 130° C. was observed when the band comprised 50 percent of the alumina carrier and contained at least 60 percent of the ruthenium metal. The preferential oxidation catalyst may be employed to reduce carbon monoxide in fuel gas streams supplied to fuel cells wherein carbon monoxide will poison the active noble metal membrane and higher preferential oxidation temperatures may reduce the hydrogen content of the gas stream.

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1. A method for preparing a preferential oxidation catalyst comprising: a) contacting a shaped alumina carrier with a source of ruthenium metal comprising ruthenium nitrosyl nitrate at a pH of between about 1.0 and about 4.5 to provide a ruthenium-containing composition having a ruthenium content

1. A method for preparing a preferential oxidation catalyst comprising: a) contacting a shaped alumina carrier with a source of ruthenium metal comprising ruthenium nitrosyl nitrate at a pH of between about 1.0 and about 4.5 to provide a ruthenium-containing composition having a ruthenium content of between about 0.5 and about 3 weight percent ruthenium metal dispersed on a shaped alumina carrier, at least 60 percent of the ruthenium metal being present in a band extending from the surface towards the center and having a width of about 50 percent of the distance from the surface to the center of the shaped alumina carrier; and b) reducing the ruthenium-containing composition. 2. The method of claim 1 wherein the reduction is carried out by contacting the ruthenium-containing composition with a reducing gas at a reducing temperature of between about 200° and about 500° C. 3. The method of claim 1 wherein at least about 35 percent of the ruthenium metal is dispersed in the band wherein the band comprises 10 percent of the distance from the surface to the center of the shaped alumina carrier. 4. The method of claim 1 wherein at least about 40 percent of the ruthenium metal is dispersed in the band wherein the band comprises 10 percent of the distance from the surface to the center of the shaped alumina carrier. 5. The method of claim 4 wherein the band comprises more than 98 wt-% of the ruthenium metal. 6. The method of claim 1 wherein the shaped alumina carrier is selected from the group consisting of a sphere, an irregularly shaped particle, a cylinder, a coated monolith, and combinations thereof.