CATALYST FOR SELECTIVE OXIDATION OF CARBON MONOXIDE PRESENT IN HYDROGEN-CONTAINING GASES, AND ELIMINATION OF CARBON MONOXIDE AND SOLID POLYMER ELECTROLYTE FUEL CELL SYSTEM WHICH MAKE USE OF THE CATAL
A catalyst for selective oxidation of carbon monoxide present in a hydrogen-containing gas is provided in which the catalyst comprises ruthenium supported on an alumina hydrate. This catalyst has a high selective oxidation activity to carbon monoxide. A carbon monoxide elimination method using this
A catalyst for selective oxidation of carbon monoxide present in a hydrogen-containing gas is provided in which the catalyst comprises ruthenium supported on an alumina hydrate. This catalyst has a high selective oxidation activity to carbon monoxide. A carbon monoxide elimination method using this catalyst is also provided. In this method, to a gas containing at least hydrogen and carbon monoxide and being richer in the hydrogen than the carbon monoxide on the basis of volume, oxygen is added in an amount necessary for oxidizing at least part of carbon monoxide present in that gas, and thereafter the gas to which the oxygen has been added is brought into contact with the catalyst described above. Also provided is a solid polymer electrolyte fuel cell system that utilizes this method.
대표청구항▼
1. A solid polymer fuel cell system comprising: a fuel storage container, a reformer, a carbon monoxide selective-oxidation reactor using a catalyst, and a solid polymer electrolyte fuel cell which are disposed in this order, said catalyst comprising a ruthenium component supported on an alum
1. A solid polymer fuel cell system comprising: a fuel storage container, a reformer, a carbon monoxide selective-oxidation reactor using a catalyst, and a solid polymer electrolyte fuel cell which are disposed in this order, said catalyst comprising a ruthenium component supported on an alumina hydrate, said ruthenium component comprising ruthenium in the state of metal. 2. The solid polymer electrolyte fuel cell system according to claim 1, further comprises a shift reactor. 3. The solid polymer electrolyte fuel cell system according to claim 1, wherein steam reforming, autothermal reforming or partial-oxidation reforming is performed in said reformer. 4. The solid polymer electrolyte fuel cell system according to claim 1, wherein a fuel comprising an oxygen-containing hydrocarbon and/or a hydrocarbon is used. 5. The solid polymer electrolyte fuel cell system according to claim 4, wherein said fuel comprises methanol, gasoline, methane, or mixture thereof. 6. The solid polymer electrolyte fuel cell system according to claim 1, wherein the catalyst having a BET specific surface area of 150 m2or larger. 7. The solid polymer electrolyte fuel cell system according to claim 1, wherein the catalyst having a BET specific surface of 200 m2or larger. 8. The solid polymer electrolyte fuel cell system according to claim 1, wherein said alumina hydrate is a compound represented by the chemical formula: Al2O3·nH2O wherein n is an integer of 1 to 3. 9. The solid polymer electrolyte fuel cell system according to claim 1, wherein said alumina hydrate is at least one member selected form the group consisting of boehmite, pseudo-boehmite and boehmite gel. 10. The solid polymer electrolyte fuel cell system according to claim 1, wherein said ruthenium is present in an amount of from 0.1 to 20% by mass in terms of metallic ruthenium based on the electrolyte fuel cell system. 11. The solid polymer electrolyte fuel cell system according to claim 1, wherein said ruthenium is present in an amount of from 0.5 to 10% by mass based on the mass of the catalyst in terms of metallic ruthenium. 12. The solid polymer electrolyte fuel cell system according to claim 1, wherein the catalyst has been molded to a predetermined form. 13. The solid polymer electrolyte fuel cell system according to claim 12, wherein said predetermined form is a ball, a pellet, a cylinder, a honeycomb, a spiral, a granule, or a ring. 14. The solid polymer electrolyte fuel cell system according to claim 1, wherein said alumina hydrate has been molded into a predetermined form and said ruthenium is supported on the molded alumina hydrate. 15. The solid polymer electrolyte fuel cell system according to claim 14, wherein said predetermined form is a ball, a pellet, a cylinder, a honeycomb, a spiral, a granule, or a ring. 16. The solid polymer electrolyte fuel cell system according to claim 1, wherein said ruthenium component further comprises RuO, Ru2O3,RuO2,Ru(OH)3or mixture thereof.
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