국가/구분 |
United States(US) Patent
등록
|
국제특허분류(IPC7판) |
|
출원번호 |
US-0361690
(2003-02-11)
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우선권정보 |
JP-0046424 (2002-02-22); JP-0144613 (2002-05-20); JP-0238810 (2002-08-20); JP-0360580 (2002-12-12); JP-0011098 (2003-01-20) |
발명자
/ 주소 |
- Funaki, Atsushi
- Sumi, Naoko
- Nishi, Eiichi
|
출원인 / 주소 |
- Asahi Glass Company, Limited
|
대리인 / 주소 |
Oblon, Spivak, McClelland, Maier & Neustadt, P.C.
|
인용정보 |
피인용 횟수 :
8 인용 특허 :
9 |
초록
▼
A fluorocopolymer which comprises (A) polymerized units based on tetrafluoroethylene, (B) polymerized units based on ethylene and (C) polymerized units based on itaconic anhydride or citraconic anhydride, wherein the molar ratio of (A)/(B) is from 20/80 to 80/20, and the molar ratio of (C)/((A)+(B))
A fluorocopolymer which comprises (A) polymerized units based on tetrafluoroethylene, (B) polymerized units based on ethylene and (C) polymerized units based on itaconic anhydride or citraconic anhydride, wherein the molar ratio of (A)/(B) is from 20/80 to 80/20, and the molar ratio of (C)/((A)+(B)) is from 1/10000 to 5/100, and which has a volume flow rate of from 1 to 1000 mm3/sec. The fluorocopolymer is excellent in the fuel barrier properties and in the adhesive properties to a non-fluorinated polymer.
대표청구항
▼
1. A fluorocopolymer which comprises (A) polymerized units of tetrafluoroethylene, (B) polymerized units of ethylene and (C) polymerized units of itaconic anhydride or citraconic anhydride, wherein the molar ratio of(A)/(B) is from 20/80 to 80/20, and the molar ratio of(C)/((A)+(B)) is from 1/10000
1. A fluorocopolymer which comprises (A) polymerized units of tetrafluoroethylene, (B) polymerized units of ethylene and (C) polymerized units of itaconic anhydride or citraconic anhydride, wherein the molar ratio of(A)/(B) is from 20/80 to 80/20, and the molar ratio of(C)/((A)+(B)) is from 1/10000 to 5/100, and which has a volume flow rate of from 1 to 1000 mm3/sec. 2. The fluorocopolymer according to claim 1, wherein the molar ratio of(C)/((A)+(B)) is from 1/1000 to 5/100. 3. The fluorocopolymer according to claim 1, which further comprises (D) polymerized units of another monomer, in an amount of from 0.01 to 20 mol %, based on the total polymerized units in the fluorocopolymer. 4. The fluorocopolymer according to claim 3, wherein said another monomer is a compound represented by CH2=CX(CF2)nY wherein each of X and Y which are independent of each other, is a hydrogen atom or a fluorine atom, and n is an integer of from 2 to 8. 5. The fluorocopolymer according to claim 4, wherein n is from 2 to 4. 6. The fluorocopolymer according to claim 1, wherein the molar ratio of(A)/(B) is from 50/50 to 60/40. 7. The fluorocopolymer according to claim 1, wherein the molar ratio of(C)/((A)+(B)) is from 3/2000 to 3/100. 8. The fluorocopolymer according to claim 3, wherein said another monomer is CH2=CH(CF2)nF wherein n is from 2 to 4. 9. The fluorocopolymer according to claim 1, wherein the molar ratio of(C)/((A)+(B)) is from 3/1000 to 3/100. 10. A multilayer laminate comprising a layer of the fluorocopolymer as defined in claim 1 and a layer of a non-fluorinated polymer, directly bonded thereto. 11. A laminate comprising a layer of the fluorocopolymer as defined in claim 1 and a layer of a polyamide, directly bonded thereto. 12. The fluorocopolymer according to claim 1, wherein the volume flow rate is from 5 to 500 mm3/sec. 13. The fluorocopolymer according to claim 1, wherein the volume flow rate is from 10 to 200 mm3/sec. 14. The fluorocopolymer according to claim 1, wherein the fluorocopolymer has a functional group reactive with a non-fluorinated polymer, wherein the functional group is selected from the group consisting of an ester group, a carbonate group, a hydroxyl group, a carboxyl group, a carbonyl fluoride group or a combination thereof. 15. The fluorocopolymer according to claim 1, wherein the polymerized units (C) are present in an amount of from 0.01 to 5% based on the total molar ratio of tetrafluoroethylene and ethylene. 16. The fluorocopolymer according to claim 1, wherein the polymerized units (C) are present in an amount of from 0.1 to 1% based on the total molar ratio of tetrafluoroethylene and ethylene. 17. The fluorocopolymer according to claim 1, further comprising polymerized units of a vinyl ester (E). 18. The fluorocopolymer according to claim 17, wherein the vinyl ester is selected from the group consisting of vinyl acetate, vinyl chloroacetate, vinyl butanoate and vinyl pivalate. 19. The fluorocopolymer according to claim 1, further comprising polymerized units of vinyl acetate. 20. The fluorocopolymer according to claim 4, further comprising polymerized units of vinyl acetate.
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