초록 ▼

In the reduction of quantities of Noxin the exhaust gases of lean bum engines such as diesel engines, using a selective reduction catalyst and a source of ammonia, the present invention improves overall conversion by supplying ammonia or a precursor intermittently so that it is adsorbed and desorbed

In the reduction of quantities of Noxin the exhaust gases of lean bum engines such as diesel engines, using a selective reduction catalyst and a source of ammonia, the present invention improves overall conversion by supplying ammonia or a precursor intermittently so that it is adsorbed and desorbed during the engine operating cycle.

대표청구항 ▼

1. A method of reducing the content of nitrogen oxides (NOx) in the exhaust gas of a diesel engine operating in a substantially continuously lean burn mode, which method comprises: passing the exhaust gases over a selective catalytic reduction catalyst comprising zeolite which both releasably ads

1. A method of reducing the content of nitrogen oxides (NOx) in the exhaust gas of a diesel engine operating in a substantially continuously lean burn mode, which method comprises: passing the exhaust gases over a selective catalytic reduction catalyst comprising zeolite which both releasably adsorbs ammonia and catalyses the reduction of NOx to nitrogen by ammonia during an engine cycle; supplying ammonia to the catalyst during the engine cycle from a source of ammonia, when the catalyst temperature is above a first pre-determined temperature; adsorbing ammonia to the catalyst during ammonia supply; discontinuing the ammonia supply when the catalyst is below a second pre-determined temperature; and reacting ammonia absorbed on the catalyst with NOx when the catalyst is below a second pre-determined temperature. 2. A method according to claim 1 wherein the zeolite is ZSM-5. 3. A method according to claim 1 wherein the zeolite catalyst is non-metallised. 4. A method according to claim 1 wherein the zeolite contains a metal. 5. A method according to claim 4 wherein the metal is selected from the group consisting of copper, iron, cerium and platinum. 6. A method according to claim 1 wherein the metal is Cu/ZSM-5. 7. A method according to claim 1 wherein the first pre-determined temperature is in the range of about 250-400° C. and the second pre-determined level is in the range of about 200-250° C. 8. An apparatus for reducing the content of nitrogen oxides (NOx) in the exhaust gas of a diesel engine operating in a substantially continuously lean burn mode comprising: (a) an exhaust apparatus capable of allowing exhaust gas to flow therethrough; (b) a selective catalytic reduction catalyst comprising zeolite located in the flow-path of the exhaust gas and being capable of both catalyzing the reduction of NOx in the exhaust gas to nitrogen and releasably adsorbing ammonia during the engine cycle; (c) means for supplying ammonia from an ammonia source to the catalyst; and (d) switching means for controlling the supply of ammonia during an engine cycle such that ammonia supply is switched on when the catalyst temperature rises above a first pre-determined temperature at which ammonia is adsorbed on the catalyst and the ammonia supply is switched off when the catalyst temperature falls below a second pre-determined temperature, whereby adsorbed ammonia is available to react with NOx when the catalyst is below the first pre-determined temperature. 9. An apparatus according to claim 8, wherein the first pre-determined temperature is in the range of about 250-400° C. and the second pre-determined temperature is in the range of about 200-250° C. 10. An apparatus according to claim 8 wherein the zeolite catalyst is ZSM-5. 11. An apparatus according claim 8 wherein the zeolite catalyst is non-metallised. 12. An apparatus according to claim 8 wherein the zeolite contains a metal. 13. An apparatus according to claim 12 wherein the metal is selected from the group consisting of copper, iron, cerium and platinum. 14. An apparatus of claim 12 wherein the metal is Cu/ZSM-5.