초록

The present invention relates to a process and apparatus for the removal of nitrous oxide from a feed gas stream using an adsorbent having a nitrogen diffusion parameter of 0.12 sec-1or higher and a nitrous oxide capacity of 79 mmol/g/atm or higher at 30° C.

대표청구항 ▼

1. A process for removing water, carbon dioxide and nitrous oxide from a feed gas stream, comprising passing the feed gas stream through a first adsorbent to adsorb water, a second adsorbent to adsorb carbon dioxide and a third adsorbent to adsorb nitrous oxide and to form a purified feed gas stream

1. A process for removing water, carbon dioxide and nitrous oxide from a feed gas stream, comprising passing the feed gas stream through a first adsorbent to adsorb water, a second adsorbent to adsorb carbon dioxide and a third adsorbent to adsorb nitrous oxide and to form a purified feed gas stream, wherein the third adsorbent has a nitrogen diffusion parameter of 0.12 sec-1or higher and a nitrous oxide capacity of 79 mmol/g/atm or higher at 30° C. and the first, second and third adsorbents may optionally be the same material. 2. A process as claimed in claim 1, wherein the third adsorbent has a nitrogen diffusion parameter of 0.15 sec-1or higher. 3. A process as claimed in claim 1, wherein the second and third adsorbents are the same material, and are different from the first adsorbent. 4. A process as claimed in claim 1, wherein the feed gas is air. 5. A process as claimed in claim 4, further comprising cryogenic distillation of the purified feed gas stream to separate a nitrogen rich stream and/or an oxygen rich stream. 6. A process as claimed in claim 1, wherein the adsorbents are regenerated by thermal swing adsorption. 7. A process as claimed in claim 6, wherein the adsorbents are regenerated at a temperature of 50 to 400° C. 8. A process as claimed in claim 6, wherein the adsorbents are regenerated at a pressure of 0.1 to 20 atm. 9. A process as claimed in claim 6, wherein oxygen, nitrogen, methane, hydrogen, argon or a mixture of two or more thereof is passed over the adsorbents as they are regenerated. 10. A process as claimed in claim 1, wherein the feed gas stream is at a temperature of 0 to 50° C. 11. A process as claimed in claim 1, wherein the feed gas stream is at a pressure of 3 to 20 atm. 12. A process as claimed in claim 1, wherein the first adsorbent is selected from alumina, silica gel, impregnated alumina, zeolite A and zeolite X. 13. A process as claimed in claim 1, wherein the second adsorbent is selected from impregnated alumina, impregnated composite alumina/zeolite, zeolite A and zeolite 20 X. 14. A process as claimed in claim 1, wherein the second and third adsorbents are the same material, and this material is calcium exchanged X zeolite. 15. A process for removing nitrous oxide from a feed gas stream, comprising passing the feed gas stream over an adsorbent having a nitrogen diffusion parameter of 0.12 sec-1or higher and a nitrous oxide capacity of 79 mmol/g/atm or higher at 30° C. 16. Apparatus for removing water, carbon dioxide and nitrous oxide from a feed gas stream comprising in fluid series connection a first adsorbent to adsorb water, a second adsorbent to remove carbon dioxide and a third adsorbent to remove nitrous oxide, wherein the third adsorbent has a nitrogen diffusion parameter of 0.12 sec-1or higher and a nitrous oxide capacity of 79 mmol/g/atm or higher at 30° C. and the first, second and third adsorbents may optionally be the same material. 17. Apparatus as claimed in claim 16, further comprising in fluid series connection a cryogenic air separation unit.