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A coating material is deposited on a substrate by vacuum or low-pressure pulsed detonation coating. A detonation chamber receives a detonable mixture containing a coating precursor. The detonable mixture is ignited to produce detonation products laden with the coating precursor. The detonation produ

A coating material is deposited on a substrate by vacuum or low-pressure pulsed detonation coating. A detonation chamber receives a detonable mixture containing a coating precursor. The detonable mixture is ignited to produce detonation products laden with the coating precursor. The detonation products are accelerated in a low-pressure or vacuum chamber and discharged through a nozzle into contact with a substrate situated in low pressure to produce a high quality coating.

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1. A method for producing a coating on a substrate using a pulsed detonation gun, the method comprising: providing a pulsed detonation gun having a detonation chamber, wherein said detonation chamber comprises ignition means and a nozzle for discharging detonation products; forming a detonable

1. A method for producing a coating on a substrate using a pulsed detonation gun, the method comprising: providing a pulsed detonation gun having a detonation chamber, wherein said detonation chamber comprises ignition means and a nozzle for discharging detonation products; forming a detonable mixture containing at least one coating precursor in said detonation chamber; igniting said detonable mixture to produce detonation products containing said coating precursor; accelerating said detonation products containing said coating precursor under low pressure; and contacting said accelerated coating precursor with said substrate to produce a coating on said substrate. 2. The method of claim 1 wherein said at least one coating precursor is selected from the group consisting of metals, cermets, ceramics, and combinations thereof.3. The method of claim 2 wherein said particles have a mean particle size of less than about 50 &mgr;m.4. The method of claim 3 wherein said mean particle size is less than about 10 &mgr;m.5. The method of claim 4 wherein said mean particle size is less than about 1 &mgr;m.6. The method of claim 5 wherein said mean particle size is less than about 100 nm.7. The method of claim 6 wherein said mean particle size is less than about 10 nm.8. The method of claim 1 wherein said at least one coating precursor is a gaseous or liquid metalorganic compound selected from the group consisting of silane, disilane, germane, tungsten hexaflurade, trimethylboron, cadmium acetate, magnesium ethoxide, tantalum V-methoxide, tungsten V-ethoxide, zinc naphenate, and zirconium n-butoxide.9. The method of claim 8 where said metalorganic compound is mixed into said detonable mixture.10. The method of claim 9 where said metalorganic compound is used as fuel for detonation.11. The method of claim 1 wherein said step of igniting said detonable mixture is intermittently performed at a frequency of from about 1 to about 1,000 Hz.12. The method of claim 1 wherein the detonation products are accelerated under a pressure of less than about 10−1atmospheres.13. A method for producing a coating on a substrate using a pulsed detonation gun, the method comprising: providing at least one coating precursor and a detonable mixture; providing a detonation chamber having a first region containing ignition means and a second region having a nozzle for discharging detonation products; injecting said detonable mixture into the first region of said detonation chamber; injecting said coating precursor into the second region of said detonation chamber; igniting said detonable mixture to produce detonation products, wherein said detonation products displace said coating precursor toward said nozzle; accelerating said coating precursor under low pressure; and contacting said accelerated coating precursor with said substrate to produce a coating on said substrate. 14. The method of claim 13 wherein said at least one coating precursor comprises an inert gas or a suspension containing particles having a mean particle size of less than about 50 &mgr;m.15. The method of claim 14 wherein said mean particle size is less than about 10 &mgr;m.16. The method of claim 15 wherein said mean particle size is less than about 1 &mgr;m.17. The method of claim 16 wherein said mean particle size is less than about 100 nm.18. The method of claim 17 wherein said mean particle size is less than about 10 nm.19. The method of claim 13 wherein the detonation products are accelerated under a pressure of less than about 10−1atmospheres.20. A method of producing a coating on a substrate using a pulsed detonation coating gun, the method comprising: providing a pulsed detonation gun having a detonation chamber, wherein said detonation chamber comprises an igniter and a nozzle for discharging detonation products; providing a suspension of at least one coating precursor in a detonable fuel; injecting said suspension into said detonat ion chamber and forming a detonable mixture; igniting said detonable mixture to produce detonation products containing said coating precursor; accelerating said detonation products containing said coating precursor under low pressure; and contacting said accelerated coating precursor with said substrate to produce a coating on said substrate. 21. The method of claim 20 wherein said at least one coating precursor comprises particles selected from the group consisting of metals, cermets, ceramics, and combinations thereof, wherein said particles have a mean particle size of less than about 50 &mgr;m.22. The method of claim 21 wherein said mean particle size is less than about 10 &mgr;m.23. The method of claim 22 wherein said mean particle size is less than about 1 &mgr;m.24. The method of claim 23 wherein said mean particle size is less than about 100 nm.25. The method of claim 24 wherein said mean particle size is less than about 10 nm.26. The method of claim 20 wherein the detonation products are accelerated under a pressure of less than about 10−1atmospheres.27. An apparatus for producing a coating on a substrate by a pulsed detonation coating, the apparatus comprising: a pulsed detonation gun having a detonation chamber for receiving a detonable mixture and a coating precursor, wherein said detonation chamber comprises an igniter for igniting said detonable mixture and a nozzle for discharging detonation products from said detonation chamber toward a substrate; and a low-pressure chamber for accelerating detonation products containing said coating precursor discharged from said nozzle, wherein said low-pressure chamber is external to said pulsed detonation gun and wherein low pressure is maintained in said low-pressure chamber. 28. The apparatus of claim 27 wherein said ignition means intermittently ignites said detonable mixture at a frequency of from about 1 to about 1,000 Hz.29. The apparatus of claim 27 wherein said low-pressure means maintains a pressure not exceeding about 10−1atmospheres in said low-pressure chamber.30. The apparatus of claim 27 wherein said nozzle is displaceable to a plurality of coating positions.31. The apparatus of claim 27 wherein said nozzle comprises a converging nozzle.32. The apparatus of claim 27 wherein said nozzle comprises a converging-diverging nozzle.33. The apparatus of claim 27 wherein said pulsed detonation gun has a length of about 50 cm or less.34. The apparatus of claim 33 wherein the length of said pulsed detonation gun is about 25 cm or less.35. The apparatus of claim 34 wherein the length of said pulsed detonation gun is about 10 cm or less.36. The apparatus of claim 35 wherein the length of said pulsed detonation gun is about 5 cm or less.