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The present invention pertains to a process for sulfiding a catalyst composition comprising at least one hydrogenation metal component of Group VI and/or Group VIII of the Periodic Table, and an organic additive wherein the catalyst composition is first contacted with an organic liquid, followed by

The present invention pertains to a process for sulfiding a catalyst composition comprising at least one hydrogenation metal component of Group VI and/or Group VIII of the Periodic Table, and an organic additive wherein the catalyst composition is first contacted with an organic liquid, followed by the catalyst being contacted with hydrogen and a sulfur-containing compound in the gaseous phase, wherein less than about 40%, preferably less than about 35%, more preferably less than about 25%, most preferably less than about 15%, of the sulfur present in the sulfided catalyst is added with the organic liquid. The process of the present invention makes it possible to use additive-containing catalysts without loss of activity in units which cannot effect gas phase start-up or are required to carry out a pressure test. The organic liquid may be a hydrocarbon with a boiling range of about 150-500° C., preferably gasoline, white spirit, diesel, gas oil, mineral lube oil, or white oil. The step of contacting the catalyst with hydrogen and a sulfur-containing compound may take place in one step at a temperature of about 150-450° C. It may also take place in two steps, with the first step being performed at a temperature which is lower than that of the second step, with the first step being carried out at a temperature of about 100-250° C. and the second step at a temperature of about 150-450° C.

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1. A process for sulfiding a catalyst composition comprising at least one hydrogenation metal component selected from the group consisting of Group VI and Group VIII of the Periodic Table, and an organic additive, wherein the catalyst composition is first contacted with an organic liquid, followed b

1. A process for sulfiding a catalyst composition comprising at least one hydrogenation metal component selected from the group consisting of Group VI and Group VIII of the Periodic Table, and an organic additive, wherein the catalyst composition is first contacted with an organic liquid, followed by the catalyst being contacted with hydrogen and a sulfur-containing compound in the gaseous phase, wherein less than about 40% of the sulfur present in the sulfided catalyst is added with the organic liquid, said catalyst being dried subsequent to addition of said organic additive and prior to said contact with said organic liquid. 2. The process of claim 1 wherein the sulfur-containing compound applied in the gaseous phase is H 2 S. 3. The process of claim 1 wherein the organic liquid is a hydrocarbon with a boiling range of about 150-500° C. 4. The process of claim 3 wherein the organic liquid is selected from the group consisting of gasoline, white spirit, diesel, gas oil, mineral lube oil, and white oil. 5. The process of claim 1 wherein the organic liquid comprises less than about 12 wt. % of oxygen. 6. The process of claim 1 wherein the organic liquid comprises less than about 8 wt. % of oxygen. 7. The process of claim 1 wherein the organic liquid comprises less than about 5 wt. % of oxygen. 8. The process of claim 1 wherein the organic liquid comprises less than about 2 wt. % of oxygen. 9. The process of claim 1 wherein the organic liquid comprises less than about 0.5 wt. % of oxygen. 10. The process of claim 1 wherein the organic liquid has an iodine number of about 50 or less. 11. The process of claim 1 wherein the organic liquid has an iodine number of about 30 or less. 12. The process of claim 1 wherein the organic liquid contains less than about 10 wt. % of sulfur. 13. The process of claim 1 wherein the organic liquid contains less than about 5 wt. % of sulfur. 14. The process of claim 1 wherein the amount of organic liquid contacted with the catalyst is about 20-500% of the catalyst pore volume which can be filled with the liquid under the conditions at which contact occurs. 15. The process of claim 1 wherein the organic additive comprises at least one carbon atom and at least one hydrogen atom. 16. The process of claim 15 wherein the organic additive comprises the group of compounds comprising at least two oxygen atoms and 2- about 20 carbon atoms and the compounds built up from these compounds. 17. The process of claim 16 wherein the organic additive is selected from the group of compounds comprising at least two hydroxyl groups and 2- about 10 carbon atoms per molecule, and the ethers and polyethers of these compounds. 18. The process of claim 1 wherein the organic additive is incorporated into the catalyst composition prior to, subsequent to, or simultaneously with the incorporation of the hydrogenation metal components. 19. The process of claim 1 wherein the organic additive comprises about 0.01-2.5 moles of additive per mole of hydrogenation metals present in the catalyst. 20. The process of claim 1 wherein the catalyst has a metal content in the range of about 0.1 to about 50 wt. % calculated as oxides on the dry weight of the catalyst not containing the organic additive. 21. The process of claim 1 wherein the Group VIB metal is present in an amount of about 5-40 wt. %, calculated as trioxide. 22. The process of claim 1 wherein the Group VIII metal is present in an amount of about 1-10 wt. %, calculated as monoxide. 23. The process of claim 1 wherein the group VI metals are selected from Mo and/or W and the group VIII metals are selected from Co and/or Ni. 24. The process of claim 22 wherein the amount of sulfur incorporated into the catalyst is selected to correspond to about 50-500% of the stoichiometric sulfur quantity necessary to convert the hydrogenation metals into Co 9 S 8 , MoS 2 , WS 2 , and/or Ni 3 S 2 , respectively. 25. The process of claim 1 wherein the contacting of the catalyst with hydrogen and a sulfur-containing compound in the gaseous phase takes place in one step at a final temperature of about 150-500° C. 26. The process of claim 1 wherein the contacting of the catalyst with hydrogen and a sulfur-containing compound in the gaseous phase is carried out in two steps, with the first step being performed at a final temperature which is lower than that of the second step. 27. The process of claim 22 wherein the first step is carried out at a final temperature of about 100-250° C. and the second step is carried out at a final temperature of about 150-500° C. 28. The process of claim 1 wherein the organic additive is an organic compound which comprises at least two nitrogen atoms and at least two carbonyl moieties. 29. The process of claim 1 wherein both the contacting with the organic liquid and the contacting with hydrogen and a sulfur-containing compound are carried out ex situ. 30. The process of claim 28 wherein the ex situ sulfided catalyst is passivated after the treatment with hydrogen and the sulfur-containing compound. 31. The process of claim 1 wherein less than about 35% of the sulfur present in the sulfided catalyst is added with the organic liquid. 32. The process of claim 1 wherein less than about 25% of the sulfur present in the sulfided catalyst is added with the organic liquid. 33. The process of claim 1 wherein less than about 15% of the sulfur present in the sulfided catalyst is added with the organic liquid. 34. A catalyst composition obtained by the process of claim 1.