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A process for preparing an aqueous dispersion of composite particles composed of addition polymer and finely divided inorganic solid, in which process at least one ethylenically unsaturated monomer is dispersely distributed in aqueous medium and is polymerized by the method of free-radical aqueous e

A process for preparing an aqueous dispersion of composite particles composed of addition polymer and finely divided inorganic solid, in which process at least one ethylenically unsaturated monomer is dispersely distributed in aqueous medium and is polymerized by the method of free-radical aqueous emulsion polymerization by means of at least one free-radical polymerization initiator in the presence of at least one dispersely distributed, finely divided inorganic solid and at least one dispersant.

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1. A process for preparing an aqueous dispersion of particles composed of addition polymer and finely divided inorganic solid, in which process at least one ethylenically unsaturated monomer is dispersely distributed in aqueous medium and is polymerized by the method of free-radical aqueous emulsion

1. A process for preparing an aqueous dispersion of particles composed of addition polymer and finely divided inorganic solid, in which process at least one ethylenically unsaturated monomer is dispersely distributed in aqueous medium and is polymerized by the method of free-radical aqueous emulsion polymerization by means of at least one free-radical polymerization initiator in the presence of at least one dispersely distributed, finely divided inorganic solid and at least one dispersant, whereina) a stable aqueous dispersion of said at least one inorganic solid is used, said dispersion having the characteristic features that at an initial solids concentration of ≧1% by weight, based on the aqueous dispersion of said at least one solid, it still contains in dispersed form one hour after its preparation more than 90% by weight of the originally dispersed solid and its dispersed solid particles have a weight-average diameter ≦100 nm,b) the dispersed particles of said at least one inorganic solid exhibit a nonzero electrophoretic mobility in an aqueous standard potassium chloride solution at a pH which corresponds to the pH of the aqueous reaction medium at the beginning of the emulsion polymerization, andc) the radical-generating component of said at least one free-radical polymerization initiator and/or the dispersive component of said at least one dispersant have at least one electrical charge whose sign is opposite to the sign of the electrophoretic mobility of the dispersed particles of said at least one solid as possessed by said particles in an aqueous standard potassium chloride solution at a pH which corresponds to the pH of the aqueous reaction medium at the beginning of the emulsion polymerization. 2. A process as claimed in claim 1, wherein said at least one inorganic solid comprises at least one element selected from the group consisting of magnesium, calcium, strontium, barium, boron, titanium, chromium, iron, cobalt, nickel, copper, zinc, tin, zirconium, cerium, yttrium, aluminum, silicon, phosphorus, antimony, and bismuth. 3. A process as claimed in claim 1, wherein said at least one inorganic solid is selected from the group consisting of silicon dioxide, aluminum oxide, hydroxyaluminum oxide, calcium carbonate, magnesium carbonate, calcium orthophosphate, magnesium orthophosphate, iron(II) oxide, iron(III) oxide, iron(II/III) oxide, tin dioxide, cerium dioxide, yttrium(III) oxide, titanium dioxide, hydroxyapatite, zinc oxide, and zinc sulfide. 4. A process as claimed in claim 1, wherein said at least one inorganic solid in water at 20° C. and 1 bar (absolute) has a solubility ≦1 g/1 water. 5. A process as claimed in claim 1, wherein said at least one dispersant is an anionic emulsifier. 6. A process as claimed in claim 1, wherein said at least one dispersant is a cationic emulsifier. 7. A process as claimed in claim 1, wherein said at least one dispersant is an anionic protective colloid. 8. A process as claimed in claim 1, wherein said at least one dispersant is a cationic protective colloid. 9. A process as claimed in claim 1, wherein said at least one free-radical polymerization initiator is selected from the group consisting of sodium peroxodisulfate, potassium peroxodisulfate, and ammonium peroxodisulfate. 10. A process as claimed in claim 1, wherein said at least one free-radical polymerization initiator is 2,2′-azobis(amidinopropyl) dihydrochloride.