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Kafe 바로가기국가/구분 | United States(US) Patent 등록 |
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국제특허분류(IPC7판) |
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출원번호 | US-0841499 (2001-04-24) |
발명자 / 주소 |
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출원인 / 주소 |
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인용정보 | 피인용 횟수 : 230 인용 특허 : 274 |
A hydrocarbon containing formation may be treated using an in situ thermal process. A mixture of hydrocarbons, H 2 , and/or other formation fluids may be produced from the formation. Heat may be applied to the formation to raise a temperature of a portion of the formation to a pyrolysis temperature
A hydrocarbon containing formation may be treated using an in situ thermal process. A mixture of hydrocarbons, H 2 , and/or other formation fluids may be produced from the formation. Heat may be applied to the formation to raise a temperature of a portion of the formation to a pyrolysis temperature. Heat input into the formation may be controlled to raise the temperature of portion at a selected rate.
1. A method of treating a hydrocarbon containing formation in situ, comprising:providing heat from one or more heaters to at least a portion of the formation;allowing the heat to transfer directly from the one or more heaters to a part of the formation;producing a mixture from the formation through
1. A method of treating a hydrocarbon containing formation in situ, comprising:providing heat from one or more heaters to at least a portion of the formation;allowing the heat to transfer directly from the one or more heaters to a part of the formation;producing a mixture from the formation through at least one production well of one or more production wells;monitoring a temperature at or in at least one production well; andcontrolling heat input to raise the monitored temperature at a rate of less than about 3° C. per day. 2. The method of claim 1, wherein the one or more heaters comprise at least two heaters, and wherein superposition of heat from at least the two heaters pyrolyzes at least some hydrocarbons in the part of the formation. 3. The method of claim 1, wherein at least one of the heaters comprises an electrical heater. 4. The method of claim 1, wherein at least one of the heaters comprises a surface burner. 5. The method of claim 1, wherein at least one of the heaters comprises a flameless distributed combustor. 6. The method of claim 1, wherein at least one of the heaters comprises a natural distributed combustor. 7. The method of claim 1, further comprising controlling a pressure and a temperature in at least a majority of the part of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure. 8. The method of claim 1, wherein the heat is controlled such that an average heating rate of the part is less than about 1° C. per day when the average temperature of the part is in a pyrolysis temperature range. 9. The method of claim 1, wherein providing heat from one or more heaters to at least the portion of the formation comprises:heating a selected volume (V) of the hydrocarbon containing formation from one or more of the heaters, wherein the formation has an average heat capacity (C v ), and wherein the heating pyrolyzes at least some hydrocarbons in the selected volume of the formation; andwherein heating energy/day (Pwr) provided to the selected volume is equal to or less than h*V*C v *ρ B , wherein pis formation bulk density, and wherein an average heating rate (h) of the selected volume is less than about 3° C./day. 10. The method of claim 1, wherein allowing the heat to transfer comprises transferring heat substantially by conduction. 11. The method of claim 1, wherein allowing the heat to transfer increases a thermal conductivity of at least a portion of the part to greater than about 0.5 W/(m °C.). 12. The method of claim 1, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°. 13. The method of claim 1, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1% by weight to about 15% by weight of the condensable hydrocarbons are olefins. 14. The method of claim 1, wherein the produced mixture comprises non-condensable hydrocarbons, wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons is less than about 0.15, and wherein the ratio of ethene to ethane is greater than about 0.001. 15. The method of claim 1, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1% by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen. 16. The method of claim 1, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1% by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen. 17. The method of claim 1, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1% by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur. 18. The method of claim 1, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5% by weight to about 30% by weight of the condensable hydrocarbons comprise o xygen containing compounds, and wherein the oxygen containing compounds comprise phenols. 19. The method of claim 1, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20% by weight of the condensable hydrocarbons are aromatic compounds. 20. The method of claim 1, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5% by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings. 21. The method of claim 1, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3% by weight of the condensable hydrocarbons are asphaltenes. 22. The method of claim 1, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5% by weight to about 30% by weight of the condensable hydrocarbons are cycloalkanes. 23. The method of claim 1, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises molecular hydrogen, wherein the molecular hydrogen is greater than about 10% by volume of the non-condensable component at 25° C. and one atmosphere absolute pressure, and wherein the molecular hydrogen is less than about 80% by volume of the non-condensable component at 25° C. and one atmosphere absolute pressure. 24. The method of claim 1, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05% by weight of the produced mixture is ammonia. 25. The method of claim 1, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer. 26. The method of claim 1, further comprising controlling a pressure in at least a majority of the part of the formation, wherein the controlled pressure is at least about 2.0 bars absolute. 27. The method of claim 1, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H 2 , wherein a partial pressure of H 2 in the mixture is greater than about 0.5 bar. 28. The method of claim 27, wherein the partial pressure of H 2 is measured when the mixture is at a production well. 29. The method of claim 1, further comprising altering a pressure in the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25. 30. The method of claim 1, further comprising recirculating a portion of hydrogen from the mixture in the formation. 31. The method of claim 1, further comprising:providing H 2 to the part to hydrogenate hydrocarbons in the part; andheating a portion of the part with heat from hydrogenation. 32. The method of claim 1, wherein the produced mixture comprises hydrogen (H 2 ) and condensable hydrocarbons, and further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen. 33. The method of claim 1, wherein allowing the heat to transfer increases a permeability of a majority of the part to greater than about 100 millidarcy. 34. The method of claim 1, wherein allowing the heat to transfer increases a permeability of a majority of the part such that the permeability of the majority of the part is substantially uniform. 35. The method of claim 1, further comprising controlling the heat to yield greater than about 60% by weight of condensable hydrocarbons, as measured by the Fischer Assay. 36. The method of claim 1, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heaters are disposed in the formation for each production well. 37. The method of claim 1, wherein the one or more heaters comprise at least three heaters located in the formation in a unit of heaters, and wherein the unit of heaters comprises a triangular pattern. 38. The method of claim 36, wherein at least about 20 heaters are disposed in the formation for each production well. 39. The method of claim 1, further comprising prov iding hydrogen (H 2 ) to the part when the average temperature in the part is at or above about 270° C. 40. The method of claim 39, wherein at least a portion of the H 2 provided to the part comprises H 2 separated from the mixture. 41. The method of claim 1, further comprising heating the part to quickly raise temperature in the part to a temperature sufficient to pyrolyze hydrocarbons in the part. 42. The method of claim 1, wherein controlling the heat input comprises controlling the heat input to raise the monitored temperature at the rate of less than about 3° C. per day when the monitored temperature is at or above about 250° C. 43. The method of claim 1, wherein controlling the heat input comprises controlling the heat input to raise the monitored temperature at the rate of less than about 3° C. per day when the monitored temperature is at or above about 270° C. and less than about 400° C. 44. The method of claim 43, further comprising raising the monitored temperature to a temperature sufficient to produce synthesis gas after the monitored temperature exceeds 400° C., and introducing a synthesis gas generating fluid into the part. 45. A method of treating a hydrocarbon containing formation in situ, comprising:allowing heat to transfer directly from one or more heaters to a part of the formation;producing a mixture from the formation through at least one production well of one or more production wells;monitoring a temperature at or in at least one production well; andcontrolling heat input to raise the monitored temperature at a rate of less than about 3° C. per day. 46. The method of claim 45, wherein the one or more heaters comprise at least two heaters, and wherein superposition of heat from at least the two heaters pyrolyzes at least some hydrocarbons in the part of the formation. 47. The method of claim 45, wherein at least one of the heaters comprises a natural distributed combustor. 48. The method of claim 45, further comprising controlling a pressure and a temperature in at least a majority of the part of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure. 49. The method of claim 45, wherein the heat is controlled such that an average heating rate of the part is less than about 1° C. per day in a pyrolysis temperature range. 50. The method of claim 45, wherein allowing the heat to transfer from the one or more heaters to at least the part of the formation comprises:heating a selected volume (V) of the hydrocarbon containing formation from the one or more heaters, wherein the formation has an average heat capacity (C v ), and wherein the heating pyrolyzes at least some hydrocarbons in the selected volume of the formation; andwherein heating energy/day (Pwr) provided to the selected volume is equal to or less than h*V*C v *ρ B , wherein ρ B is formation bulk density, and wherein an average heating rate (h) of the selected volume is less than about 3° C./day. 51. The method of claim 45, wherein allowing the heat to transfer comprises transferring heat substantially by conduction. 52. The method of claim 45, wherein allowing the heat to transfer increases a thermal conductivity of at least a portion of the part to greater than about 0.5 W/(m °C.). 53. The method of claim 45, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°. 54. The method of claim 45, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1% by weight to about 15% by weight of the condensable hydrocarbons are olefins. 55. The method of claim 45, wherein the produced mixture comprises non-condensable hydrocarbons, wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons is less than about 0.15, and wherein the ratio of ethene to ethane is greater than about 0.001. 56. The method of claim 45, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1% by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen. 57. The method of claim 45, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1% by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen. 58. The method of claim 45, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1% by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur. 59. The method of claim 45, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5% by weight to about 30% by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols. 60. The method of claim 45, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20% by weight of the condensable hydrocarbons are aromatic compounds. 61. The method of claim 45, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5% by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings. 62. The method of claim 45, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3% by weight of the condensable hydrocarbons are asphaltenes. 63. The method of claim 45, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5% by weight to about 30% by weight of the condensable hydrocarbons are cycloalkanes. 64. The method of claim 45, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises molecular hydrogen, wherein the molecular hydrogen is greater than about 10% by volume of the non-condensable component at 25° C. and one atmosphere absolute pressure, and wherein the molecular hydrogen is less than about 80% by volume of the non-condensable component at 25° C. and one atmosphere absolute pressure. 65. The method of claim 45, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05% by weight of the produced mixture is ammonia. 66. The method of claim 45, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer. 67. The method of claim 45, further comprising controlling a pressure in at least a majority of the part of the formation, wherein the controlled pressure is at least about 2.0 bars absolute. 68. The method of claim 45, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H 2 , wherein a partial pressure of H 2 in the mixture is greater than about 0.5 bar. 69. The method of claim 68, wherein the partial pressure of H 2 is measured when the mixture is at a production well. 70. The method of claim 45, further comprising altering a pressure in the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater than about 25. 71. The method of claim 45, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation. 72. The method of claim 45, further comprising:providing H 2 to the heated part of the formation to hydrogenate hydrocarbons in the part of the formation; andheating a portion of the part of the formation with heat from hydrogenation. 73. The method of claim 45, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen. 74. The method of claim 45, wherein allowing the heat to transfer increases a permeability of a majority of the part of the formation to greater than about 100 millidarcy. 75. The method of claim 45, wherein allowing the heat to transfer increases a permeability of a majority of the part of the formation such that the permeability of the part of the formation is substantially uniform. 76. The method of claim 45, further comprising controlling the heat to yield greater than about 60% by weight of condensable hydrocarbons, as measured by the Fischer Assay. 77. The method of claim 45, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heaters are disposed in the formation for each production well. 78. The method of claim 77, wherein at least about 20 heaters are disposed in the formation for each production well. 79. The method of claim 45, further comprising providing H 2 to the part of the formation. 80. The method of claim 45, further comprising providing H 2 to at least a portion of the formation to hydrogenate hydrocarbons in the formation. 81. The method of claim 45, further comprising providing hydrogen (H 2 ) to the part when the monitored temperature in the part is at or above about 270° C. 82. The method of claim 81, wherein at least a portion of the H 2 provided to the part comprises H 2 separated from the mixture. 83. The method of claim 45, further comprising heating the part to quickly raise temperature in the part to a temperature sufficient to pyrolyze hydrocarbons in the part. 84. The method of claim 45, wherein controlling the heat input comprises controlling the heat input to raise the monitored temperature at the rate of less than about 3° C. per day when the monitored temperature is at or above about 250° C. 85. The method of claim 45, wherein controlling the heat input comprises controlling the heat input to raise the monitored temperature at the rate of less than about 3° C. per day when the monitored temperature is at or above about 270° C. and less than about 400° C. 86. A method of treating a hydrocarbon containing formation in situ, comprising:providing heat from one or more heaters to at least a portion of the formation;allowing the heat to transfer from the one or more heaters to a part of the formation;producing a mixture from the formation through at least one production well of one or more production wells;monitoring a temperature at or in at least one production well; andcontrolling heat input to raise the monitored temperature at a rate of less than about 1.5° C. per day. 87. The method of claim 86, wherein the one or more heaters comprise at least two heaters, and wherein superposition of heat from at least the two heaters pyrolyzes at least some hydrocarbons in the part of the formation. 88. The method of claim 86, wherein at least one of the heaters comprises a natural distributed combustor. 89. The method of claim 86, further comprising controlling a pressure and a temperature in at least a majority of the part of the formation, wherein the pressure is controlled as a function of temperature, or the temperature is controlled as a function of pressure. 90. The method of claim 86, wherein the heat is controlled such that an average heating rate of the part is less than about 1° C. per day in a pyrolysis temperature range. 91. The method of claim 86, wherein providing heat from the one or more heaters to at least the portion of the formation comprises:heating a selected volume (V) of the hydrocarbon containing formation from the one or more heaters, wherein the formation has an average heat capacity (C v ), and wherein the heating pyrolyzes at least some hydrocarbons in the selected volume of the formation; andwherein heating energy/day (Pwr) provided to the selected volume is equal to or less than h*V*C v *ρ B , wherein ρ B is formation bulk density, and wherein an average heating rate (h) of the selected volume is less than about 1.5° C./day. 92. The method of claim 86, wherein allowing the heat to transfer comprises transferring heat substant ially by conduction. 93. The method of claim 86, wherein allowing the heat to transfer increases a thermal conductivity of at least a portion of the part to greater than about 0.5 W/(m ° C.). 94. The method of claim 86, wherein the produced mixture comprises condensable hydrocarbons having an API gravity of at least about 25°. 95. The method of claim 86, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 0.1% by weight to about 15% by weight of the condensable hydrocarbons are olefins. 96. The method of claim 86, wherein the produced mixture comprises non-condensable hydrocarbons, wherein a molar ratio of ethene to ethane in the non-condensable hydrocarbons is less than about 0.15, and wherein the ratio of ethene to ethane is greater than about 0.001. 97. The method of claim 86, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1% by weight, when calculated on an atomic basis, of the condensable hydrocarbons is nitrogen. 98. The method of claim 86, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1% by weight, when calculated on an atomic basis, of the condensable hydrocarbons is oxygen. 99. The method of claim 86, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 1% by weight, when calculated on an atomic basis, of the condensable hydrocarbons is sulfur. 100. The method of claim 86, wherein the produced mixture comprises condensable hydrocarbons, wherein about 5% by weight to about 30% by weight of the condensable hydrocarbons comprise oxygen containing compounds, and wherein the oxygen containing compounds comprise phenols. 101. The method of claim 86, wherein the produced mixture comprises condensable hydrocarbons, and wherein greater than about 20% by weight of the condensable hydrocarbons are aromatic compounds. 102. The method of claim 86, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 5% by weight of the condensable hydrocarbons comprises multi-ring aromatics with more than two rings. 103. The method of claim 86, wherein the produced mixture comprises condensable hydrocarbons, and wherein less than about 0.3% by weight of the condensable hydrocarbons are asphaltenes. 104. The method of claim 86, wherein the produced mixture comprises condensable hydrocarbons, and wherein about 5% by weight to about 30% by weight of the condensable hydrocarbons are cycloalkanes. 105. The method of claim 86, wherein the produced mixture comprises a non-condensable component, wherein the non-condensable component comprises molecular hydrogen, wherein the molecular hydrogen is greater than about 10% by volume of the non-condensable component at 25° C. and one atmosphere absolute pressure, and wherein the molecular hydrogen is less than about 80% by volume of the non-condensable component at 25° C. and one atmosphere absolute pressure. 106. The method of claim 86, wherein the produced mixture comprises ammonia, and wherein greater than about 0.05% by weight of the produced mixture is ammonia. 107. The method of claim 86, wherein the produced mixture comprises ammonia, and wherein the ammonia is used to produce fertilizer. 108. The method of claim 86, further comprising controlling a pressure in at least a majority of the part of the formation, wherein the controlled pressure is at least about 2.0 bars absolute. 109. The method of claim 86, further comprising controlling formation conditions to produce a mixture of condensable hydrocarbons and H 2 , wherein a partial pressure of H 2 in the mixture is greater than about 0.5 bar. 110. The method of claim 109, wherein the partial pressure of H 2 is measured when the mixture is at a production well. 111. The method of claim 86, further comprising altering a pressure in the formation to inhibit production of hydrocarbons from the formation having carbon numbers greater t han about 25. 112. The method of claim 86, wherein controlling formation conditions comprises recirculating a portion of hydrogen from the mixture into the formation. 113. The method of claim 86, further comprising:providing H 2 to the heated part of the formation to hydrogenate hydrocarbons in the part of the formation; andheating a portion of the part of the formation with heat from hydrogenation. 114. The method of claim 86, wherein the produced mixture comprises hydrogen and condensable hydrocarbons, the method further comprising hydrogenating a portion of the produced condensable hydrocarbons with at least a portion of the produced hydrogen. 115. The method of claim 86, wherein allowing the heat to transfer increases a permeability of a majority of the part of the formation to greater than about 100 millidarcy. 116. The method of claim 86, wherein allowing the heat to transfer increases a permeability of a majority of the part of the formation such that the permeability of the part of the formation is substantially uniform. 117. The method of claim 86, further comprising controlling the heat to yield greater than about 60% by weight of condensable hydrocarbons, as measured by the Fischer Assay. 118. The method of claim 86, wherein producing the mixture comprises producing the mixture in a production well, and wherein at least about 7 heaters are disposed in the formation for each production well. 119. The method of claim 118, wherein at least about 20 heaters are disposed in the formation for each production well. 120. The method of claim 86, further comprising providing H 2 to at least a portion of the formation. 121. The method of claim 86, further comprising providing H 2 to at least a portion of the formation to hydrogenate hydrocarbons in the formation. 122. The method of claim 86, further comprising providing hydrogen (H 2 ) to the part when the average temperature in the part is at or above about 270° C. 123. The method of claim 122, wherein at least a portion of the H 2 provided to the part comprises H 2 separated from the mixture. 124. The method of claim 86, wherein controlling the heat input comprises controlling the heat input to raise the monitored temperature at the rate of less than about 1.5° C. per day when the monitored temperature is at or above about 250° C. 125. The method of claim 86, wherein controlling the heat input comprises controlling the heat input to raise the monitored temperature at the rate of less than about 1.5° C. per day when the monitored temperature is at or above about 270° C. and less than about 400° C. 126. The method of claim 125, further comprising raising the monitored temperature to a temperature sufficient to produce synthesis gas after the monitored temperature exceeds 400° C., and introducing a synthesis gas generating fluid into the part. 127. The method of claim 86, further comprising heating the part to quickly raise temperature in the part to a temperature sufficient to pyrolyze hydrocarbons in the part.
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