Water-stabilized organosilane compounds and methods for using the same
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
A01N-055/00
C07F-007/10
C07F-007/12
C07F-007/18
출원번호
US-0967486
(2001-09-28)
발명자
/ 주소
Elfersy, Jacques E.
Berkner, Joachim
Moses, Timothy C.
출원인 / 주소
Nova Biogenetics, Inc., International Biochemical Industries, Inc.
대리인 / 주소
Saliwanchik, Lloyd & Saliwanchik
인용정보
피인용 횟수 :
27인용 특허 :
41
초록▼
The composition formed by mixing an organosilane with an organic carbonate. Water-stabilized organosilane compounds. A water stable composition made from the organic carbonate and organosilane composition and water. A method of treating a substrate by mixing or contacting the substrate with the prod
The composition formed by mixing an organosilane with an organic carbonate. Water-stabilized organosilane compounds. A water stable composition made from the organic carbonate and organosilane composition and water. A method of treating a substrate by mixing or contacting the substrate with the product, compound, or composition of this invention for a period of time sufficient for treatment of the substrate. A treated substrate having adhered thereto the product, compound, or composition of this invention. A method of dyeing and treating a substrate. A method of antimicrobially treating a food article. A method of antimicrobially coating a fluid container. A method of antimicrobially coating a latex medical article.
대표청구항▼
1. A composition comprising a mixture of:a) an antimicrobial organosilane of the formula R n SiX 4−n , wherein n is an integer of from 0 to 3; and R is, independently, a nonhydrolizable organic group; and each X is, independently, a hydrolyzable group; withb) an organic carbonate. 2. The co
1. A composition comprising a mixture of:a) an antimicrobial organosilane of the formula R n SiX 4−n , wherein n is an integer of from 0 to 3; and R is, independently, a nonhydrolizable organic group; and each X is, independently, a hydrolyzable group; withb) an organic carbonate. 2. The composition of claim 1, wherein n is an integer from 0 to 2; each R of the organosilane formula is, independently, alkyl, alkyl alcohol, or aromatic; each X is, independently, hydroxy, alkoxy, halogen, acetyl, acetoxy, acyl, acyloxy, a hydroxylated solid or liquid polymeric moiety, polyglycol or polyalkylether; and said organic carbonate is of the formula:wherein R of the carbonate formula is, independently,alkyl, glycol, alkyl glycol, a cyclic molecule, or a heterocyclic molecule; alkyl alcohol, polyglycol, alkyl glycol, cyclic alcohol, heterocyclic alcohol, or polyalkyl ether; optionally said cyclic alcohol or heterocyclic alcohol is substituted with an alkyl or an alkyl alcohol. 3. The composition of claim 1, wherein the organosilane is of the formula II, III, IV, or V: 1 ) 3 SiR 2 N + (R 3 )(R 4 )(R 5 )Y − (II) 1 ) 3 SiR 2 N(R 3 )(R 4 ) (III) 1 ) 3 SiR 2 R 35 (IV) 1 ) 2 Si(R 36 )(R 37 ) (V)whereineach R 1 is, independently, halogen or R 6 O; where R 6 is selected from the group consisting of the following:H, alkyl, acetyl, acetoxy, acyl, acyloxy, glycol, polyglycol, alkyl glycol, alkyl polyglycol, a monoester formed by linking a carbonic acid of from 1 to 24 carbons with glycol or polyglycol, phenolics substituted with an alkyl of from about 1 to 24 carbons and their ethers and sorbitan esters and their ethers and polyalkyl ether;R 35 is R 6 , H, halogen, NH 2 (CH 2 ) 2 NHR 2 , NH 2 R 2 , C 3 H 5 O 2 R 2 , C 4 H 5 O 2 R 2 , NaO(CH 3 O)P(O)R 2 , or ClCH 2 C 6 H 4 R 2 ,R 36 and R 37 are, independently, R 35 , halogen, H, alkyl of from 1 to about 4 carbon atoms, isobutyl, phenyl, or n-octyl;R 2 is R 6 , benzyl, vinyl or alkyl;R 3 and R 4 are, independently, R 35 alkyl alcohol, alkoxy, alkyl or a cyclic molecule; orR 3 and R 4 can, together, form a morpholine, a cyclic molecule, or a heterocyclic molecule;R 5 is alkyl alcohol, R 35 , CH 2 C 6 H 5 , polyglycol, alkyl, alkoxy, perfluoroalkyl, pefluoroalkylsulfonate, or perfluoroalkylcarboxylate; andY − is a suitable anionic moiety to form the salt of the compound of formula I, II, III or IV. 4. A water stable composition, comprising the composition of claim 1 and water. 5. The composition of claim 1, wherein the organosilane is 3-(trimethoxysilyl)propyldimethyloctadecyl ammonium chloride. 6. A composition for treating a substrate, comprising a carrier and an effective amount of the composition of claim 1. 7. The composition of claim 6, wherein the carrier is other than water. 8. The composition of claim 1, wherein the organosilane is 3-(trimethoxysilyl)propyldimethyloctadecyl ammonium chloride, 3-(trimethoxysilyl)propylmethyldi(decyl)ammonium chloride, 3-chloropropyltrimethylsilane, 3-chloropropyltrimethoxysilane, octadecyltrimethoxysilane, or perfluorooctyltriethoxysilane. 9. The composition of claim 1, wherein the organosilane is(CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 C 18 H 37 Cl − , (CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 C 18 H 37 Br − ,(CH 3 O) 3 Si(CH 2 ) 3 N + (C 10 H 21 ) 2 CH 3 Cl − , (CH 3 O) 3 Si(CH 2 ) 3 N + (C 10 H 21 ) 2 CH 3 Br − ,(CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 3 Cl − , (CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 C 8 H 17 Cl − ,(CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 C 10 H 21 Cl − , (CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 C 12 H 25 Cl − ,(CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 C 14 H 29 Cl − , (CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 C 16 H 33 Cl − ,(CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 C 20 H 41 Cl − , (CH 3 O) 3 Si(CH 2 ) 3 N + (C 4 H 9 ) 3 Cl − ,(CH 3 O) 3 Si(CH 2 ) 3 N + (C 2 H 5 ) 3 C − , (CH 3 CH 2 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 C 18 H 27 Cl − ,(CH 3 O) 3 Si(CH 2 ) 3 NHC(O)(CF 2 ) 6 CF 3 , (CH 3 O) 3 Si(CH 2 ) 3 NHC(O)(CF 2 ) 8 CF 3 ,(CH 3 O) 3 Si(CH 2 ) 3 NHC(O)(CF 2 ) 10 CF 3 , (CH 3 O) 3 Si(CH 2 ) 3 NHC(O)(CF 2 ) 12 CF 3 ,(CH 3 O)Si(CH 2 ) 3 NHC(O)(CF 2 ) 14 CF 3 , (CH 3 O) 3 Si(CH 2 ) 3 NHC(O)(CF 2 ) 16 CF 3 ,(CH 3 O) 3 Si(CH 2 ) 3 NHSO 2 (CF 2 ) 7 CF 3 ,(CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 (CH 2 ) 3 NHC(O)(CH 2 ) 6 CH 3 ,(CH 3 O) 3 Si(CH 2 ) 3 N + , (CH 3 ) 2 (CH 2 ) 3 NHC(O)(CH 2 ) 8 CH 3 ,(CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 (CH 2 ) 3 NHC(O)(CH 2 ) 10 CH 3 ,(CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 (CH 2 ) 3 NHC(O)(CH 2 ) 12 CH 3 ,(CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 (CH 2 ) 3 NHC(O)(CH 2 ) 14 CH 3 ,(CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 (CH 2 ) 3 NHC(O)(CH 2 ) 16 CH 3 ,(CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 (CH 2 )(CH 2 ) 3 NHC(O)(CF 2 ) 6 C 3 ,(CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 (CH 2 ) 3 NHC(O)(CF 2 ) 8 CF 3 ,(CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 (CH 2 ) 3 NHC(O)(CF 2 ) 10 CF 3 ,(CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 (CH 2 ) 3 NHC(O)(CF 2 ) 12 CF 3 ,(CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 (CH 2 ) 3 NHS(O)(CF 2 ) 14 CF 3 ,(CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 (CH 2 ) 3 NHC(O)(CF 2 ) 16 CF 3 ,(CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 (CH 2 ) 3 NHSO 2 (CF 2 ) 7 CF 3 ,(CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 (CH 2 ) 3 NHSO 2 (CF 2 ) 9 CF 3 ,(CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 (CH 2 ) 3 NHSO 2 (CF 2 ) 11 CF 3 ,(CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 (CH 2 ) 3 NHSO 2 (CF 2 ) 13 CF 3 ,(CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 (CH 2 ) 3 NHSO 2 (CF 2 ) 15 CF 3 ,(CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 (CH 2 ) 3 NHSO 2 (CF 2 ) 16 CF 3 ,(CH 3 O) 3 Si(CH 2 ) 3 NHC 6 H 4 COOH,(CH 3 O) 3 Si(CH 2 ) 3 NHC 6 H 4 COOCH 3 ,(CH 3 O) 3 Si(CH 2 ) 3 NHC 6 H 4 COOC 2 H 5 ,(CH 3 O) 3 Si(CH 2 ) 3 NHC 6 H 4 COOC 3 H 7 ,(CH 3 O) 3 Si(CH 2 ) 3 NHC 6 H 4 COOC 4 H 9 ,(CH 3 O) 3 Si(CH 2 ) 3 NHC 6 H 4 COOCH 2 C 6 H 5 ,(CH 3 O) 3 Si(CH 2 ) 3 NHC 6 H 4 COOCH 2 C 6 H 4 NH 2 ,(CH 3 O) 3 Si(CH 2 ) 3 NHC 6 H 4 COOCH 2 C 6 H 4 N(CH 3 ) 2 ,(CH 3 O) 3 Si(CH 2 ) 3 NHC 6 H 4 COOCH 2 C 6 H 4 N(CH 2 CH 3 ) 2 ,(CH 3 O) 3 Si(CH 2 ) 3 NHC 6 H 4 COOCH 2 C 6 H 4 N + (CH 3 ) 3 Y − ,(CH 3 O) 3 Si(CH 2 ) 3 NHC 6 H 4 COOCH 2 C 6 H 4 N + (CH 2 CH 3 ) 3 Y − ,(CH 3 O) 3 Si(CH 2 ) 3 NCH 3 C 6 H 4 COOH,(CH 3 O) 3 Si(CH 2 ) 3 NCH 3 C 6 H 4 COOCH 3 ,(CH 3 O) 3 Si(CH 2 ) 3 NCH 3 C 6 H 4 COOC 2 H 5 ,(CH 3 O) 3 Si(CH 2 ) 3 NCH 3 C 6 H 4 COOC 3 H 7 ,(CH 3 O) 3 Si(CH 2 ) 3 NCH 3 C 6 H 4 COOC 4 H 9 ,(CH 3 O) 3 Si(CH 2 ) 3 NCH 3 C 6 H 4 COOCH 2 C 6 H 5 ,(CH 3 O) 3 Si(CH 2 ) 3 NCH 3 C 6 H 4 COOCH 2 C 6 H 4 NH 2 ,(CH 3 O) 3 Si(CH 2 ) 3 NCH 3 C 6 H 4 COOCH 2 C 6 H 4 N(CH 3 ) 2 ,(CH 3 O) 3 Si(CH 2 ) 3 NCH 3 C 6 H 4 COOCH 2 C 6 H 4 N(CH 2 CH 3 ) 2 ,(CH 3 O) 3 Si(CH 2 ) 3 NCH 3 C 6 H 4 COOCH 2 C 6 H 4 N + (CH 3 ) 3 Y − ,(CH 3 O) 3 Si(CH 2 ) 3 NCH 3 C 6 H 4 COOCH 2 C 6 H 4 N + (CH 2 CH 3 ) 3 Y − ,(CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 C 6 H 4 COOH Y − ,(CH 3 O) 3 SI(CH 2 ) 3 N + (CH 3 ) 2 C 6 H 4 COOCH 3 Y − ,(CH 3 O) 3 SI(CH 2 ) 3 N + (CH 3 ) 2 C 6 H 4 COOC 2 H 5 Y − ,(CH 3 O) 3 SI(CH 2 ) 3 N + (CH 3 ) 2 C 6 H 4 COOC 3 H 7 Y − ,(CH 3 O) 3 SI(CH 2 ) 3 N + (CH 3 ) 2 C 6 H 4 COOC 4 H 9 Y − ,(CH 3 O) 3 SI(CH 2 ) 3 N + (CH 3 ) 2 C 6 H 4 COOCH 2 C 6 H 5 Y − ,(CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 C 6 H 4 COOCH 2 C 6 H 4 NH 2 Y − ,(CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 C 6 H 4 COOCH 2 C 6 H 4 N(CH 3 ) 2 Y − ,(CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 C 6 H 4 COOCH 2 C 6 H 4 N(CH 2 CH 3 ) 2 Y − ,(CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 C 6 H 4 COOCH 2 C 6 H 4 N + (CH 3 ) 3 Y − Y − ,(CH 3 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 C 6 H 4 COOCH 2 C 6 H 4 N + (CH 2 CH 3 ) 3 Y − Y − ,(CH 3 O) 3 Si(CH 2 ) 3 NC 2 H 5 C 6 H 4 COOH,(CH 3 O) 3 Si(CH 2 ) 3 NC 2 H 5 C 6 H 4 COOCH 3 ,(CH 3 O) 3 Si(CH 2 ) 3 NC 2 H 5 C 6 H 4 COOC 4 H 9 ,(CH 3 O) 3 Si(CH 2 ) 3 NC 2 H 5 C 6 H 4 COOC 3 H 7 ,(CH 3 O) 3 Si(CH 2 ) 3 NC 2 H 5 C 6 H 4 COOC 4 H 9 ,(CH 3 O) 3 Si(CH 2 ) 3 NC 2 H 5 C 6 H 4 COOCH 2 C 6 H 5 ,(CH 3 O) 3 Si(CH 2 ) 3 NC 2 H 5 C 6 H 4 COOCH 2 C 6 H 4 NH 2 ,(CH 3 O) 3 Si(CH 2 ) 3 NC 2 H 5 C 6 H 4 COOCH 2 C 6 H 4 N(CH 3 ) 2 ,(CH 3 O) 3 Si(CH 2 ) 3 NC 2 H 5 C 6 H 4 COOCH 2 C 6 H 4 N(CH 2 CH 3 ) 2 ,(CH 3 O) 3 Si(CH 2 ) 3 NC 2 H 5 C 6 H 4 COOCH 2 C 6 H 4 N + (CH 3 ) 3 Y − ,(CH 3 O) 3 Si(CH 2 ) 3 NC 2 H 5 C 6 H 4 COOCH 2 C 6 H 4 N + (CH 2 CH 3 ) 3 Y − ,(CH 3 O) 3 Si(CH 2 ) 3 N + (C 2 H 5 ) 2 C 6 H 4 COOH Y − ,(CH 3 O) 3 Si(CH 2 ) 3 N + (C 2 H 5 ) 2 C 6 H 4 COOCH 3 Y − ,(CH 3 O) 3 Si(CH 2 ) 3 N + (C 2 H 5 ) 2 C 6 H 4 COOC 2 H 5 Y − ,(CH 3 O) 3 Si(CH 2 ) 3 N + (C 2 H 5 ) 2 C 6 H 4 COOC 3 H 7 Y − ,(CH 3 O) 3 Si(CH 2 ) 3 N + (C 2 H 5 ) 2 C 6 H 4 COOC 4 H 9 Y − ,(CH 3 O) 3 Si(CH 2 ) 3 N + (C 2 H 5 ) 2 C 6 H 4 COOCH 2 C 6 H 5 Y − ,(CH 3 O) 3 Si(CH 2 ) 3 N + (C 2 H 5 ) 2 C 6 H 4 COOCH 2 C 6 H 4 N 2 Y − ,(CH 3 O) 3 Si(CH 2 ) 3 N + (C 2 H 5 ) 2 C 6 H 4 COOCH 2 C 6 H 4 N(CH 3 ) 2 Y − ,(CH 3 O) 3 Si(CH 2 ) 3 N + (C 2 H 5 ) 2 C 6 H 4 COOCH 2 C 6 H 4 N(CH 2 CH 3 ) 2 Y − ,(CH 3 O) 3 Si(CH 2 ) 3 N + (C 2 H 5 ) 2 C 6 H 4 COOCH 2 C 6 H 4 N + (CH 3 ) 3 Y − Y − ,(CH 3 O) 3 Si(CH 2 ) 3 N + (C 2 H 5 ) 2 C 6 H 4 COOCH 2 C 6 H 4 N + (CH 2 CH 3 ) 3 Y − Y − ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NHC 6 H 4 COOH,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NHC 6 H 4 COOCH 3 ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NHC 6 H 4 COOC 2 H 5 ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NHC 6 H 4 COOC 3 H 7 ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NHC 6 H 4 COOC 4 H 9 ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NHC 6 H 4 COOCH 2 C 6 H 5 ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NHC 6 H 4 COOCH 2 C 6 H 4 NH 2 ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NHC 6 H 4 COOCH 2 C 6 H 4 N(CH 3 ) 2 ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NHC 6 H 4 COOCH 2 C 6 H 4 N(CH 2 CH 3 ) 2 ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NHC 6 H 4 COOCH 2 C 6 H 4 N + (CH 3 ) 3 Y − ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NHC 6 H 4 COOCH 2 C 6 H 4 N + (CH 2 CH 3 ) 3 Y − ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NCH 3 C 6 H 4 COOH,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NCH 3 C 6 H 4 COOCH 3 ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NCH 3 C 6 H 4 COOC 2 H 5 ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NCH 3 C 6 H 4 COOC 3 H 7 ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NCH 3 C 6 H 4 COOC 4 H 9 ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NCH 3 C 6 H 4 COOCH 2 C 6 H 5 ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NCH 3 C 6 H 4 COOCH 2 C 6 H 4 NH 2 ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NCH 3 C 6 H 4 COOCH 2 C 6 H 4 N(CH 3 ) 2 ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NCH 3 C 6 H 4 COOCH 2 C 6 H 4 N(CH 2 CH 3 ) 2 ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NCH 3 C 6 H 4 COOCH 2 C 6 H 4 N + (CH 3 ) 3 Y − ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NCH 3 C 6 H 4 COOCH 2 C 6 H 4 N + (CH 2 CH 3 ) 3 Y − ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NCH 3 C 6 H 4 COOCH 2 C 6 H 4 N + (CH 2 CH 3 ) 3 Y − ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 C 6 H 4 COOH Y − ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 C 6 H 4 COOCH 3 Y − ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 C 6 H 4 COOC 2 H 5 Y − ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 C 6 H 4 COOC 3 H 7 Y − ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 C 6 H 4 COOC 4 H 9 Y − ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 C 6 H 4 COOCH 2 C 6 H 5 Y − ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 C 6 H 4 COOCH 2 C 6 H 4 NH 2 Y − ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 C 6 H 4 COOCH 2 C 6 H 4 N(CH 3 ) 2 Y − ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 C 6 H 4 COOCH 2 C 6 H 4 N(CH 2 CH 3 ) 2 Y − ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 C 6 H 4 COOCH 2 C 6 H 4 N + (CH 3 ) 3 Y − Y − ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 N + (CH 3 ) 2 C 6 H 4 COOCH 2 C 6 H 4 N + (CH 2 CH 3 ) 3 Y − Y − ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NC 2 H 5 C 6 H 4 COOH,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NC 2 H 5 C 6 H 4 COOCH 3 ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NC 2 H 5 C 6 H 4 COOC 2 H 5 ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NC 2 H 5 C 6 H 4 COOC 3 H 7 ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NC 2 H 5 C 6 H 4 COOC 4 H 9 ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NC 2 H 5 C 6 H 4 COOCH 2 C 6 H 5 ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NC 2 H 5 C 6 H 4 COOCH 2 C 6 H 4 NH 2 ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NC 2 H 5 C 6 H 4 COOCH 2 C 6 H 4 N(CH 3 ) 2 ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NC 2 H 5 C 6 H 4 COOCH 2 C 6 H 4 N(CH 2 CH 3 ) 2 ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NC 2 H 5 C 6 H 4 COOCH 2 C 6 H 4 N + (CH 3 ) 3 Y − ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 NC 2 H 5 C 6 H 4 COOCH 2 C 6 H 4 N + (CH 2 CH 3 ) 3 Y − ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 N + (C 2 H 5 ) 2 C 6 H 4 COOH Y − ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 N + (C 2 H 5 ) 2 C 6 H 4 COOCH 3 Y − ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 N + (C 2 H 5 ) 2 C 6 H 4 COOC 2 H 5 Y − ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 N + (C 2 H 5 ) 2 C 6 H 4 COOC 3 H 7 Y − ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 N + (C 2 H 5 ) 2 C 6 H 4 COOC 4 H 9 Y − ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 N + (C 2 H 5 )H 2 C 6 H 5 Y − ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 N + (C 2 H 5 ) 2 C 6 H 4 COOCH 2 C 6 H 4 NH 2 Y − ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 N + (C 2 H 5 ) 2 C 6 H 4 COOCH 2 C 6 H 4 N(CH 3 ) 2 Y − ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 N + (C 2 H 5 ) 2 C 6 H 4 COOCH 2 C 6 H 4 N(CH 3 ) 2 Y − ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 N + (C 2 H 5 ) 2 C 6 H 4 COOCH 2 C 6 H 4 N(CH 2 CH 3 ) 2 Y − ,(CH 3 CH 2 O) 3 Si(CH 2 ) 3 N + (C 2 H 5 ) 2 C 6 H 4 COOCH 2 C 6 H 4 N + ((CH 3 ) 3 Y − Y − , or(CH 3 CH 2 O) 3 Si(CH 2 ) 3 N + (C 2 H 5 ) 2 C 6 H 4 COOCH 2 C 6 H 4 N + (CH 2 CH 3 ) 3 Y − Y − . 10. The composition of claim 1 formed from mixing an antimicrobial organosilane of the formula II, III, IV, or V: 1 ) 3 SiR 2 N + (R 3 )(R 4 )(R 5 )Y − (II) 1 ) 3 SiR 2 N(R 3 )(R 4 ) (III) 1 ) 3 SiR 2 R 35 (IV) 1 ) 2 Si(R 36 )(R 37 ) (V)whereineach R 1 is, independently, halogen or R 6 O, where R 6 is selected from the group consisting of the following:H, alkyl, acetyl, acetoxy, acyl, acyloxy, glycol, polyglycol, alkyl glycol, alkyl polyglycol, a monoester formed by linking a carbonic acid of from 1 to 24 carbons with glycol or polyglycol; phenolics substituted with an alkyl of from about 1 to 24 carbons and th eir ethers, and sorbitan esters and their ethers, and polyalkyl etherR 35 is R 6 , H, halogen, NH 2 (CH 2 ) 2 NHR 2 , NH 2 R 2 , C 3 H 5 O 2 R 2 , C 4 H 5 O 2 R 2 , NaO(CH 3 O)P(O)R 2 , or ClCH 2 C 6 H 4 R 2 ;R 36 and R 37 are, independently, R 35 , halogen, H, alkyl of from 1 to about 8 carbon atoms, acrylic, vinyl, acetylenic, benzyl, styryl, propinyl, isobutyl, phenyl, or n-octyl;R 2 is benzyl, vinyl or alkyl;R 3 and R 4 are, independently, lower alkyl alcohol, lower alkoxy of from 1 to 4 carbon atoms, alkyl of from 1 to about 24 carbon atoms; or R 3 and R 4 can, together, form a morpholine or cyclic molecule or heterocyclic molecule;R 5 is lower alkyl alcohol, CH 2 C 6 H 5 , polyglycol, alkyl, alkoxy, perfluoroalkyl, pefluoroalkylsulfonate, or perfluoroalkylcarboxylate; andY − is a suitable anionic moiety to form the salt of the compound of formula I, II, III or IV,with an organic carbonate. 11. The composition of claim 10 which is an aqueous composition. 12. A method for making an organosilane of the formula R n SiX 4−n where n is an integer of from 0-3, preferably 0-2; each R is, independently, a nonhydrolizable organic group; and each X is, independently, a hydrolyzable group; which comprises mixing the organosilane synthesis starting materials in an aqueous solution in the presence of an organic carbonate. 13. A water-stable composition comprising from about 0.001% to about 26% antimicrobial organosilane and from about 0.001% to about 26% ethylene carbonate and from about 99.9% to about 48% water. 14. A water-stable composition comprising from about 1.6% to about 56% of an antimicrobial organosilane solution and from about 44% to about 99% water, wherein said organosilane solution comprises about 49% silane concentrate, about 32% glycol ether DB, and about 37% propylene carbonate. 15. A water-stable composition comprising from about 1% to about 55% of an antimicrobial organosilane solution and from about 45% to about 99% water, wherein said organosilane solution comprises about 50% silane concentrate, about 12% glycol ether DB, and about 38% propylene carbonate. 16. A composition comprising from about 7% to about 55% of an antimicrobial organosilane solution and from about 45% to about 93% water, wherein said organosilane solution comprises about 0% to about 50% silane concentrate and about 0% to about 50% propylene carbonate. 17. A composition comprising antimicrobial organosilane, propylene carbonate, and water. 18. A composition comprising antimicrobial organosilane, ethylene carbonate, and water. 19. A method for making an organosilane of the formula R n SiX 4−n where n is an integer of from 0-3, preferably 0-2; each R is, independently, a nonhydrolizable organic group; and each X is, independantly, a hydrolyzable group; which comprises mixing the organosilane synthesis starting materials in the presence of an organic carbonate solvent. 20. The method according to claim 19 wherein the organosilane starting materials comprise a silane component and a amine. 21. The method according to claim 20 wherein the silane component is 3-chloropropyltrimethoxysilane and the amine dimethyl octadecyl amine. 22. The method according to claim 19 wherein didecyl-N-methyl-3-(trimethoxysilyl)propanaminium chloride is synthesized.
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Taylor Jeffrey L. (316 Wilmuth Ave. Cincinnati OH 45215) Smith John M. (2600 Weymouth Pl. Greensboro NC 27408) Goad C. Dean (2806 Rockwood Rd. Greensboro NC 27408), Synthetic fabrics and surgical/medical products made therefrom.
Chang Wen H. (Gibsonia PA) McKeough David T. (Gibsonia PA) Ambrose Ronald R. (Allison Park PA), Urethane resins containing hydrolyzable moieties from organosilane compounds.
Taylor, Matthew Lee; Chen, Haunn-Lin Tony; Spitzer, Donald P.; Heitner, Howard I., Compositions for preventing or reducing aluminosilicate scale in industrial processes.
Samain,Henri; Rollat,Isabelle; Rose,Val?rie Jeanne; Sanchez,Cl?ment, Cosmetic composition based on organic silicon compounds comprising at least a function with a cosmetic effect.
Heitner, Howard, Silane substituted polyalkylene oxide reagents and methods of using for preventing or reducin aluminosilicate scale in industrial processes.
Heitner, Howard, Silane substituted polyalkylene oxide reagents and methods of using for preventing or reducing aluminosilicate scale in industrial processes.
Heitner, Howard, Silane substituted polyethylene oxide reagents and method of using for preventing or reducing aluminosilicate scale in industrial processes.
Garfield, Kirk; Potter, John, System and method for photocatalytic oxidation air filtration using a substrate with photocatalyst particles powder coated thereon.
Garfield, Kirk; Potter, John, System and method for photocatalytic oxidation air filtration using a substrate with photocatalyst particles powder coated thereon.
Garfield, Kirk; Potter, John, System and method for photocatalytic oxidation air filtration using a substrate with photocatalyst particles powder coated thereon.
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