초록 ▼

CMS adsorbents having suitable indexes are used to improve greatly the performance of nitrogen-producing apparatuses where nitrogen is obtained from the air with a PSA method, so as to improve the efficiency of nitrogen production. A nitrogen PSA apparatus is formed with two adsorbing columns where

CMS adsorbents having suitable indexes are used to improve greatly the performance of nitrogen-producing apparatuses where nitrogen is obtained from the air with a PSA method, so as to improve the efficiency of nitrogen production. A nitrogen PSA apparatus is formed with two adsorbing columns where an adsorption step and a regeneration step are performed alternatively and periodically. The adsorption step is for adsorbing oxygen and conducting nitrogen to a product tank with the supply of compressed air from an air compressor, and the regeneration step for releasing the adsorbed gas after the adsorption step. The adsorbing columns are filled with a carbon molecular sieve (CMS) that selectively adsorbs oxygen as an adsorbent. The CMS adsorbs an oxygen/nitrogen amount of 50% of the saturated adsorption amount with a period TO/TN starting from oxygen/nitrogen supply, wherein TO is 5˜10 seconds and TN is larger than TO by more than 41 times.

대표청구항 ▼

1. A method for producing nitrogen using a pressure swing adsorption (PSA) method with air as a raw material, comprising:having the air contact with an adsorbent that comprises a carbon molecular sieve selectively adsorbing oxygen to produce nitrogen with a purity ranging from 99% to 99.999% by usin

1. A method for producing nitrogen using a pressure swing adsorption (PSA) method with air as a raw material, comprising:having the air contact with an adsorbent that comprises a carbon molecular sieve selectively adsorbing oxygen to produce nitrogen with a purity ranging from 99% to 99.999% by using the pressure swing adsorption (PSA) method that conducts regeneration of the adsorbent under atmospheric pressure, whereina period “TO” needed for the carbon molecular sieve to adsorb an oxygen amount of 50% of a saturated oxygen adsorption amount starting from the beginning of oxygen supply is 5˜10 seconds, and a period “TN” needed for the carbon molecular sieve to adsorb a nitrogen amount of 50% of a saturated nitrogen adsorption amount starting from the beginning of nitrogen supply is larger than “TO” by more than 41 times. 2. The method of claim 1, wherein a production rate of the nitrogen product with one ton of adsorbent is higher than 100 Nm 3 /h as an oxygen concentration in the nitrogen product is 100 ppm, higher than 150 Nm 3 /h as the oxygen concentration is 1000 ppm, or higher than 250 Nm 3 /h as the oxygen concentration is 10000 ppm, wherein the oxygen concentration serves as a purity indicator of the nitrogen product. 3. The method of claim 1, wherein a processing rate of the air with one ton of adsorbent is less than 500 Nm 3 /h as an oxygen concentration in the nitrogen product is 100 ppm, less than 570 Nm 3 /h as the oxygen concentration is 1000 ppm, or less than 690 Nm 3 /h as the oxygen concentration is 10000 ppm, wherein the oxygen concentration serves as a purity indicator of the nitrogen product. 4. An apparatus for producing nitrogen with a purity ranging from 99% to 99,999% using air as a raw material, comprising:an air compressor for compressing the air;a dryer for removing water from the compressed air;at least one adsorbing column into which the dried and compressed air is conducted, the adsorbing column being filled with an adsorbent that selectively adsorbs oxygen; anda product tank for temporarily storing a nitrogen product conduct out of the adsorbing column after oxygen is removed in the adsorbing column, whereinin said at least one adsorbing column, an adsorption step and a depressurization regeneration step are switched alternatively and periodically to implement a pressure swing adsorption (PSA) process, wherein the adsorption step comprises conducting a raw air compressively into the adsorbing column, and the depressurization regeneration step comprises releasing a compressed gas under atmospheric pressure after the adsorption step; andthe adsorbent is a carbon molecular sieve that selectively adsorbs oxygen, which adsorbs an oxygen amount of 50% of a saturated oxygen adsorption amount with a period “TO” of 5˜10 seconds starting from the beginning of oxygen supply, and adsorbs a nitrogen amount of 50% of a saturated nitrogen adsorption amount with a period “TN” starting from the beginning of nitrogen supply, wherein TN is larger than TO by more than 41 times.