IPC분류정보
국가/구분 |
United States(US) Patent
등록
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국제특허분류(IPC7판) |
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출원번호 |
US-0021767
(2001-12-12)
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발명자
/ 주소 |
- Zhang, Zhiqiang
- Lockwood, Frances E.
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출원인 / 주소 |
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대리인 / 주소 |
Carrithers Law Office, PLLC
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인용정보 |
피인용 횟수 :
47 인용 특허 :
10 |
초록
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The introduction of nanotubes in a liquid provides a means for changing the physical and/or chemical properties of the liquid. Improvements in heat transfer, electrical properties, viscosity, and lubricity can be realized upon dispersion of nanotubes in liquids; however, nanotubes behave like hydrop
The introduction of nanotubes in a liquid provides a means for changing the physical and/or chemical properties of the liquid. Improvements in heat transfer, electrical properties, viscosity, and lubricity can be realized upon dispersion of nanotubes in liquids; however, nanotubes behave like hydrophobic particles and tend to clump together in liquids. Methods of preparing stable dispersions of nanotubes are described and surfactants/dispersants are identified which can disperse carbon nanotubes in aqueous and petroleum liquid medium. The appropriate dispersant is chosen for the carbon nanotube and the water or oil based medium and the dispersant is dissolved into the liquid medium to form a solution. The carbon nanotube is added to the dispersant containing the solution with agitation, ultrasonication, and/or combinations thereof.
대표청구항
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1. A method of preparing a stable dispersion of carbon nano particles in a liquid, comprising the steps of:dissolving a dispersant comprising a surfactant having a low hydrophile-lipophile balance (HLB) value of 8 or less in an amount of from 0.001 to 30.0 percent, into a major amount of a liquid me
1. A method of preparing a stable dispersion of carbon nano particles in a liquid, comprising the steps of:dissolving a dispersant comprising a surfactant having a low hydrophile-lipophile balance (HLB) value of 8 or less in an amount of from 0.001 to 30.0 percent, into a major amount of a liquid medium selected from the group consisting of a mineral oil, a hydrogenated oil, a vegetable oil, a synthetic oil, and combinations thereof forming a dispersant liquid medium;adding carbon nano material having an aspect ratio of from 500 to 5,000 in an amount of from 0.01 to 10.0 percent by weight into said dispersant liquid medium with mechanical agitation; andforming a uniform suspension of colloidal size solid particles. 2. A method of preparing a stable dispersion of carbon nano particles in a liquid, comprising the steps of:dissolving a dispersant in an amount of from 0.001 to 30.0 percent comprising a surfactant having a low hydrophile-lipophile balance (HLB) value of 8 or less into a major amount of a liquid medium selected from the group consisting of a mineral oil, a hydrogenated oil, a vegetable oil, a synthetic oil, and combinations thereof forming a dispersant liquid medium;adding carbon nano material having an aspect ratio of from 500 to 5000 in an amount of from 0.01 to 10.0 percent by weight into said dispersant liquid medium with ultrasonification; andforming a uniform suspension of colloidal size solid particles. 3. The method according to claim 1, wherein said dispersant comprises an ashless polymeric dispersant. 4. The method according to claim 3, wherein said ashless polymeric dispersant comprises a lipophilic hydrocarbon group and a polar hydrophilic functional group. 5. The method according to claim 4, wherein said polar hydrophilic functional group is selected from the group consisting of a carboxylate, ester, amine, amide, imine, imide, hydroxyl, ether, epoxide, phosphorus, ester carboxyl, anhydride, nitrile, and combinations thereof. 6. The method according to claim 4, wherein said lipophilic hydrocarbon group comprises from 70 to 200 carbon atoms to ensure oil solubility. 7. The method according to claim 1, including the step of adding electrolytes to aid in electrostatic stabilization. 8. The method according to claim 1, wherein said mechanical agitation is comprises the step of mixing said carbon nano particles using a high shear mixer selected from the group consisting of a high speed mixer, homogenizer, microfluidizer, a Kady mill, a colloid mill, a high impact mixer, a attritor, a ball and pebble mill, and combinations thereof. 9. The method according to claim 1, including the step of adding a viscosity improver. 10. The method according to claim 9, wherein said viscosity improver is selected from the group consisting of an olefin copolymer, a polymethacrylate, a hydrogenated styrene-diene, a styrene-polyester polymer, and combinations thereof. 11. The method according to claim 9, including a thickening agent selected from the group consisting of a polyacrylic acid and sodium polyacrylate, a high-molecular-weight polymer of ethylene oxide, a carboxymethylcellulose, a polyvinyl alcohol, a polyvinyl pyrrolidone, and combinations thereof. 12. The method according to claim 1, including the step of adding a plasticizer. 13. The method according to claim 12, wherein said plasticizer is selected from the group consisting of a phthalate, an adipate, a sebacate ester, a glyceryl tri(acetoxystearate), an epoxidized soybean oil, an epoxidized linseed oil, a N, n-butyl benzene sulfonamide, an aliphatic polyurethane, a polyester glutarate, a triethylene glycol, a caprate/caprylate, a long chain alkyl ether, a dialkyl diester glutarate, a monomeric polymer, a polyester based on adipic acid, a hydrogenated dimer acid, a distilled dimer acid, a polymerized fatty acid trimer, an ethyl ester of hydrolyzed collagen, an isostearic acid, a sorbian oleate, a cocoyl hydrolyzed keratin, a lanolin oil, a dialkyl adipate, an alky laryl phosphate, an alkyl diaryl phosphate, a modified triaryl phosphate, triaryl phosphate, a butyl benzyl phthalate, an octyl benzyl phthalate, an alkyl benzyl phthalate, a dibutoxy ethoxy ethyl adipate, a 2-ethylhexyldiphenyl phosphate, a dibutoxy ethoxy ethyl formyl, a diisopropyl adipate, a diisopropyl sebacate, an isodecyl oleate, a neopentyl glycol dicaprate, a neopenty glycol diotanoate, an isohexyl neopentanoate, an ethoxylated lanolin, a polyoxyethylene cholesterol, a propoxylated (2 moles) lanolin alcohol, a propoxylated lanoline alcohol, an acetylated polyoxyethylene derivative of lanoline, a dimethylpolysiloxane, a glycerine, a polyethylene glycol, a dibutyl phthalate, a 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate, a diisononyl phthalate, and combinations thereof. 14. The method according to claim 1, wherein said dispersant is selected from the group comprising a zinc dithiophosphate, a zinc alkyldithiophosphate, and combinations thereof. 15. The method according to claim 1, wherein said dispersant comprises a surfactant added to said liquid medium promoting uniform suspension of extremely fine solid particles of colloidal size. 16. The method according to claim 1, wherein said dispersant comprises a long chain oil soluble or dispersible compound which functions to disperse the “cold sludge” formed in engines. 17. The method according to claim 1, wherein said mineral oil comprises a solvent refined neutral oil, a white mineral oil, a paraffinic oil, a MVI naphthenic oil, and combinations thereof. 18. The method according to claim 1, wherein said mineral oil further comprises a hydrocracked mineral oil. 19. The method according to claim 1, wherein said hydrogenated oil comprises a severely hydrocracked mineral oil. 20. The method according to claim 1, wherein said synthetic oil is selected from the group consisting of a polyalphaolefin, an ester , a naphthene, a polyalkylglycol, a hydrocarbon oil, a halo-substituted hydrocarbon oil such as polymerized and interpolymerized olefins, a polybutylene, a polypropylene, a propylene-isobutylene copolymer, a chlorinated polybutylene, a poly(1-octenes), a poly(1-decenes), an alkylbenzene, a dodecylbenzene, a tetradecylbenzene, a dinonylbenzene, a di-(2ethylhexyl) benzene, a polypheny, a biphenyl, a terphenyl, an alkylated polyphenyl, an alkylated diphenyl ether, an alkylated diphenyl sulfide, an alkylene oxide polymer and interpolymer and derivatives thereof where the terminal hydroxyl groups have been modified by esterification, an ester of a dicarboxylic acids, a phtalic acid, a succinic acid, an alkyl succinic acid and an alkenyl succinic acid, a maleic acid, an azelaic acid, a suberic acid, a sebacic acid, a fumaric acid, an adipic acid, an alkenyl malonic acid, a butyl alcohol, a hexyl alcohol, a dodecyl alcohol, a 2-ethylhexyl alcohol, an ethylene glycol diethylene glycol monoether, a propylene glycol, a dibutyl adipate, a di(2-ethylhexyl) sebacate, a di-hexyl fumarate, a dioctyl sebacate, a diisooctyl azelate, a diisodecyl azealate, a dioctyl phthalate, a didecyl phthalate, a dicicosyl sebacate, a 2-ethylhexyl diester of linoleic acid dimer, a polyol ether, a neopentyl glycol, trimethylolpropane, a pentaerythritol, a dipentaerythritol, a tripentaerythritol, a polyolester, a diester, a di-aliphatic diester of alkyl carboxylic acids such as di-2-ethylhexylazelate, di-isodecyladipate, and di-tridecyladipate, an aliphatic diester of a dicarboxylic acid, a dialkyl aliphatic diester of an alkyl dicarboxylic acid, such as di-2-ethyl hexyl azelate, di-isodecyl azelate, di-tridecyl azelate, di-isodecyl adipate, di-tridecyl adipate. 21. The method according to claim 1, wherein said synthetic oil is selected from the group having varying viscosity from about 2 to about 460 centistokes. 22. The method according to claim 1, wherein said carbon nanoparticles are selected from the group consisting of an amorphous carbon particles nanotubes, carbon fibers, short nan otubes, and combinations thereof. 23. The method according to claim 1, wherein said carbon nanoparticles are surface treated chemically to achieve certain level of hydrophilicity by an activated carbon treatment. 24. The method according to claim 1, further comprising the step of varying the amount of said carbon nanoparticles, said dispersant, and said liquid medium and maintaining an HBL value of 8 or less producing compounds having a gel, grease, or wax type consistency. 25. The method according to claim 1, wherein said dispersant is selected form the group consisting of a nonionic surfactant, an ionic surfactant, and mixtures thereof.
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