IPC분류정보
국가/구분 |
United States(US) Patent
등록
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국제특허분류(IPC7판) |
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출원번호 |
US-0265422
(2002-10-07)
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발명자
/ 주소 |
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출원인 / 주소 |
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대리인 / 주소 |
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인용정보 |
피인용 횟수 :
53 인용 특허 :
5 |
초록
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Epoxy resin compositions are disclosed which comprise (A) at least one silicone resin, (B) at least one epoxy resin, (C) at least one anhydride curing agent, (D) at least one siloxane surfactant, and (E) at least one ancillary curing catalyst. Also disclosed are a packaged solid state devices compri
Epoxy resin compositions are disclosed which comprise (A) at least one silicone resin, (B) at least one epoxy resin, (C) at least one anhydride curing agent, (D) at least one siloxane surfactant, and (E) at least one ancillary curing catalyst. Also disclosed are a packaged solid state devices comprising a package, a chip, and an encapsulant comprising a composition of the invention. A method of encapsulating a solid state device is also provided.
대표청구항
▼
1. A curable epoxy resin composition for encapsulation of a solid state device, which comprises (A) at least one silicone resin, (B) at least one epoxy resin, (C) at least one anhydride curing agent, (D) at least one siloxane surfactant, and (E) at least one ancillary curing catalyst; wherein the si
1. A curable epoxy resin composition for encapsulation of a solid state device, which comprises (A) at least one silicone resin, (B) at least one epoxy resin, (C) at least one anhydride curing agent, (D) at least one siloxane surfactant, and (E) at least one ancillary curing catalyst; wherein the silicone resin comprises a silicone resin of structure (I)wherein R is independently at each occurrence a hydroxyl group, C 1-22 alkyl, C 1-22 alkoxy, C 2-22 alkenyl, C 6-14 aryl, C 6-22 alkyl-substituted aryl, C 6-22 aralkyl, or OSiR 3 wherein R 3 is independently at each occurrence hydroxyl, C 1-22 alkyl, C 1-22 alkoxy, C 2-22 alkenyl, C 6-14 aryl, C 6-22 alkyl-substituted aryl, or C 6-22 aralkyl; and wherein z is in a range between about 1 and about 10. 2. The composition of claim 1, wherein the epoxy resin is selected from the group consisting of aliphatic epoxy resins, cycloaliphatic epoxy resins, bisphenol-A epoxy resins, bisphenol-F epoxy resins, phenol novolac epoxy resins, cresol-novolac epoxy resins, biphenyl epoxy resins, biphenyl epoxy resins, 4,4′-biphenyl epoxy resins, polyfunctional epoxy resins, divinylbenzene dioxide, 2-glycidylphenylglycidyl ether, and combinations thereof. 3. The composition of claim 1, wherein the epoxy resin is selected from the group consisting of epoxy resins in structures (II) to (V) 4. The composition of claim 1, wherein the anhydride curing agent is selected from the group consisting of bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride, methylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride, bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride, phthalic anhydride, pyromellitic dianhydride, hexahydrophthalic anhydride, hexahydro-4-methylphthalic anhydride, dodecenylsuccinic anhydride, dichloromaleic anhydride, chlorendic anhydride, tetrachlorophthalic anhydride, and combinations thereof. 5. The composition of claim 1, wherein the anhydride curing agent is a compound of structure (VI), (VII), or combination thereof 6. The composition of claim 1 wherein the siloxane surfactant is a compound of structure (VIII), (IX), or combination thereofwherein R 1 and R 2 are independently at each occurrence selected from ethylene oxide, propylene oxide and methylene in structure (VIII) and where x and y are in a range between 0 and about 20 in structure (VIII). 7. The composition of claim 1, wherein the anhydride curing agent (C) is hexahydro-4-methylphthalic anhydride. 8. The composition of claim 1 further comprising refractive index modifiers selected from the group consisting of magnesium oxide, yttria, zirconia, cerium oxides, alumina, lead oxides, zinc selenide, zinc sulphides, alloys made from Zn, Se, S, and Te, gallium nitride, silicon nitride, aluminum nitride, and combinations thereof. 9. The composition of claim 1, wherein the composition is cured in a range between about 100° C. and about 200° C. 10. The composition of claim 1, wherein the ancillary curing catalyst (E) is selected from the group consisting of an organometallic salt, a sulfonium salt, an iodonium salt, and combinations thereof. 11. The composition of claim 1, wherein the ancillary curing catalyst (E) is selected from the group consisting of a metal carboxylate, a metal acetylacetonate, zinc octoate, stannous octoate, triarylsulfonium hexafluorophosphate, triarylsulfonium hexafluoroantimonate, diaryliodonium hexafluoroantimonate, diaryliodoniun tetrakis(pentafluorophenyl)borate, and combinations thereof. 12. The composition of claim 11, wherein the ancillary curing catalyst (E) comprises zinc octoate. 13. The composition of claim 1, comprising at least one of a hindered phenol stabilizer, a phosphite stabilizer, or combinations thereof. 14. The composition of claim 1 wherein the refractive index of the composition is in a range between about 0.1 and about 10.0. 15. The composition of claim 1 wherein the composition is clear, transparent, polishable and crackfree. 16. A curable epoxy resin compos ition for encapsulation of a solid state device, which comprises (A) a silicone resin comprising a hydroxyfunctional silicone resin, (B) an epoxy resin comprising bisphenol A epoxy resin, (C) an anhydride curing agent comprising hexahydro-4-methylphthalic anhydride, (D) a siloxane surfactant comprising ethylene oxide functionalized siloxane, and (E) an ancillary curing catalyst zinc octoate, wherein component (A) is present at a level of greater than about 40% by weight; component (B) is present at a level in a range of between about 1% by weight and about 20% by weight; component (C) is present at a level of less than about 40% by weight; and component (D) and (E) are present at a level in a range between about 0.008% by weight and about 10% by weight based on the combined weight of silicone resin (A), epoxy resin (B), anhydride curing agent (C), siloxane surfactant (D) and ancillary curing catalyst (E). 17. The composition of claim 16 further comprising at least one of a thermal stabilizer, a UV stabilizer, or combinations thereof. 18. The composition of claim 16 wherein the composition has a glass transition temperature varying in a range between about 24° C. and about 150° C. 19. The composition of claim 16 wherein the composition has a refractive index in a range between about 0.1 and about 10.0. 20. A packaged solid state device comprising: (a) a package; a chip; and (c) an encapsulant comprising: (A) at least one silicone resin, (B) at least one epoxy resin, (C) at least one anhydride curing agent, (D) at least one siloxane surfactant, and (E) at least one ancillary curing catalyst, wherein the silicone resin comprises a silicone resin selected from the silicone resin in structure (I)wherein R is independently at each occurrence a hydroxyl group, C 1-22 alkyl, C 1-22 alkoxy, C 2-22 alkenyl, C 6-14 aryl, C 6-22 alkyl-substituted aryl, C 6-22 aralkyl, or OSiR 3 wherein R 3 is independently at each occurrence hydroxyl, C 1-22 alkyl, C 1-22 alkoxy, C 2-22 alkenyl, C 6-14 aryl, C 6-22 alkyl-substituted aryl, or C 6-22 aralkyl; and wherein z is in a range between about 1 and about 10. 21. The packaged solid state device of claim 20, wherein the solid state device is a semiconductor device. 22. A packaged solid state device, wherein the solid state device is an opto-electronic device, comprising: (a) a package; a chip; and (c) an encapsulant comprising: (A) at least one silicone resin, (B) at least one epoxy resin, (C) at least one anhydride curing agent, (D) at least one siloxane surfactant, and (E) at least one ancillary curing catalyst. 23. The packaged solid state device of claim 22, wherein the opto-electronic device is semiconductor device comprising: a LED, CCD, LSI, photodiode, phototransistor, or opto-electronic coupler. 24. The packaged solid state device of claim 20, wherein the package comprises a shell or lens. 25. The packaged solid state device of claim 20, wherein the epoxy resin is selected from the group consisting of aliphatic epoxy resins, cycloaliphatic epoxy resins, bisphenol-A epoxy resins, bisphenol-F epoxy resins, phenol novolac epoxy resins, cresol-novolac epoxy resins, biphenyl epoxy resins, biphenyl epoxy resins, 4,4′-biphenyl epoxy resins, polyfunctional epoxy resins, divinylbenzene dioxide, 2-glycidylphenylglycidyl ether, and combinations thereof. 26. The packaged solid state device of claim 20, wherein the epoxy resin is a resin selected from the structures (II) to (V) 27. The packaged solid state device of claim 20, wherein the anhydride curing agent is selected from the group consisting of bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride, methylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride, bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride, phthalic anhydride, pyromellitic dianhydride, hexahydrophthalic anhydride, hexahydro-4-methylphthalic anhydride, dodecenylsuccinic anhydride, dichloromaleic anhydride, chlorendic anhydride, tetrachlorophthalic anhydr ide, and combinations thereof. 28. The packaged solid state device of claim 20, wherein the anhydride curing agent (C) is a compound of structure (VI), (VII), or combination thereof 29. The packaged solid state device of claim 20 wherein the anhydride curing agent (C) comprises hexahydro-4-methylphthalic anhydride. 30. The packaged solid state device of claim 20 wherein the siloxane surfactant is a compound of structure (VIII), (IX), or combination thereofwherein R 1 and R 2 are independently at each occurrence selected from methylene, ethylene oxide and propylene oxide in structure (VIII) and wherein x and y are in a range between 0 and about 20 in structure (VIII). 31. The packaged solid state device of claim 20, wherein the ancillary curing catalyst (E) is selected from the group consisting of an organometallic salt, a sulfonium salt, an iodonium salt, and combinations thereof. 32. The packaged solid state device of claim 20, wherein the ancillary curing catalyst (E) comprises at least one member selected from the group consisting of a metal carboxylate, a metal acetylacetonate, zinc octoate, stannous octoate, triarylsulfonium hexafluorophosphate, triarylsulfonium hexafluoroantimonate, diaryliodonium hexafluoroantimonate, diaryliodonium tetrakis(pentafluorophenyl)borate, and combinations thereof. 33. The packaged solid state device of claim 20, wherein the ancillary curing catalyst (E) is zinc octoate. 34. The packaged solid state device of claim 20, further comprising at least one of thermal stabilizers, UV stabilizers, cure modifiers, coupling agents, refractive index modifiers, or combinations thereof. 35. The packaged solid state device of claim 20, comprising at least one of a thermal stabilizer, a UV stabilizer, or combinations thereof. 36. The packaged solid state device of claim 20 wherein the encapsulant is clear, transparent, crackfree and polishable. 37. The packaged solid state device of claim 20 wherein the encapsulant has a glass transition varying in a range between about 24° C. and about 150° C. 38. The packaged solid state device of claim 21 wherein the encapsulant has a refractive index in a range between about 0.1 and about 10.0. 39. A LED device comprising: (a) a package; a LED chip; and (c) an encapsulant comprising: (A) a silicone resin comprising a hydroxyfunctional silicone resin, (B) an epoxy resin comprising a bisphenol F resin, (C) an anhydride curing agent comprising hexahydro-4-methylphthalic anhydride, (D) a siloxane surfactant comprising propylene oxide modified siloxane, and (E) a ancillary curing catalyst comprising zinc octoate, wherein component (A) is present at a level of greater than about 40% by weight; component (B) is present at a level in a range of between about 1% by weight and about 20% by weight; component (C) is present at a level of less than about 40% by weight; and component (D) and (E) are present at a level in a range between about 0.008% by weight and about 10% by weight based on the combined weight of silicone resin (A), epoxy resin (B), a siloxane surfactant (D) anhydride curing agent (C), and ancillary curing catalyst (E). 40. The LED of claim 39, in which the encapsulant further comprises at least one of a thermal stabilizer, a UV stabilizer, or combination thereof. 41. The LED of claim 39, in which the encapsulant has a glass transition temperature varying in a range between about 24° C. and about 150° C. 42. The LED of claim 39 in which the encapsulant has a refractive index in a range between about 0.1 and about 10.0. 43. A method of encapsulating a solid state device comprising: placing a solid state device into a package; and providing an encapsulant comprising: (A) at least one silicone resin, (B) at least one epoxy resin (C) at least one anhydride curing agent (D) at least one siloxane surfactant, and (E) at least one ancillary curing catalyst, wherein the silicone resin (A) comprises a silicone resin of structure (I)wherein R is independe ntly at each occurrence a hydroxyl group, C 1-22 alkyl, C 1-22 alkoxy, C 2-22 alkenyl, C 6-14 aryl, C 6-22 alkyl-substituted aryl, C 6-22 aralkyl, or OSiR 3 wherein R 3 is independently at each occurrence hydroxyl, C 1-22 alkyl, C 1-22 alkoxy, C 2-22 alkenyl, C 6-14 aryl, C 6-22 alkyl-substituted aryl, or C 6-22 aralkyl; and wherein z is in a range between about 1 and about 10. 44. The method of claim 43, wherein the solid state device is a semiconductor device. 45. The method of claim 43, wherein the solid state device is an opto-electronic device. 46. The method of claim 45, wherein the opto-electronic device is semiconductor device comprising: a LED, CCD, LSI, photodiode, phototransistor, or opto-electronic coupler. 47. The method of claim 43, wherein the package comprises a shell or lens. 48. The method of claim 43, wherein the epoxy resin is selected from the group consisting of aliphatic epoxy resins, cycloaliphatic epoxy resins, bisphenol-A epoxy resins, bisphenol-F epoxy resins, phenol novolac epoxy resins, cresol-novolac epoxy resins, biphenyl epoxy resins, biphenyl epoxy resins, 4,4′-biphenyl epoxy resins, polyfunctional epoxy resins, divinylbenzene dioxide, 2-glycidylphenylglycidyl ether, and combinations thereof. 49. The method of claim 43, wherein the epoxy resin is a resin selected from structures (II) to (V) 50. The method of claim 43, wherein the anhydride curing agent (C) is selected from the group consisting of bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride, methylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride, bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride, phthalic anhydride, pyromellitic dianhydride, hexahydrophthalic anhydride, hexahydro-4-methylphthalic anhydride, dodecenylsuccinic anhydride, dichloromaleic anhydride, chlorendic anhydride, tetrachlorophthalic anhydride, and combinations thereof. 51. The method of claim 43, wherein the anhydride curing agent is a compound of structure (VI), (VII), or combination thereof 52. The method of claim 43, wherein the siloxane surfactant (D) is a compound of structure (VIII), (IX), or combination thereofwherein R 1 and R 2 are independently at each occurrence selected from methylene, ethylene oxide and propylene oxide and in structure (VIII) wherein x and y are in a range between 0 and about 20 in structure (VIII). 53. The method of claim 43, wherein siloxane surfactant (D) comprises an ethyleneoxide functionalized siloxane. 54. The method of claim 43, wherein the anhydride curing agent (C) comprises hexahydro-4-methylphthalic anhydride. 55. The method of claim 43, wherein the ancillary curing catalyst (E) is selected from the group consisting of an organometallic salt, a sulfonium salt, an iodonium salt, and combinations thereof. 56. The method of claim 43, wherein the ancillary curing catalyst (E) is selected from the group consisting of a metal carboxylate, a metal acetylacetonate, zinc octoate, stannous octoate, triarylsulfonium hexafluorophosphate, triarylsulfonium hexafluoroantimonate, diaryliodonium hexafluoroantimonate, diaryliodonium tetrakis(pentafluorophenyl)borate, and combinations thereof. 57. The method of claim 43, wherein the ancillary curing catalyst is zinc octoate. 58. The method of claim 43, further comprising at least one of thermal stabilizers, UV stabilizers, cure modifiers, coupling agents, refractive index modifiers, or combinations thereof. 59. The method of claim 43, comprising at least one of a thermal stabilizer, a UV stabilizer, or combination thereof. 60. The method of claim 43, wherein the encapsulant is clear, transparent, crackfree and polishable. 61. The method of claim 43, wherein the encapsulant has a glass transition temperature varying in a range between about 24° C. and about 150° C. 62. The method of claim 43, wherein the encapsulant has a refractive index in a range between about 0.1 and about 10.0. 63. A method of encapsulating a LED device comprising: placing a LED device i nto a package and providing an encapsulant comprising: (A) a silicone resin comprising hydroxyfunctionalized silicone, (B) an epoxy resin comprising bisphenol F, (C) an anhydride curing agent comprising hexahydro-4-methylphthalic anhydride, (D) a siloxane surfactant comprising ethylene oxide functionalized siloxane, and (E) an ancillary curing catalyst comprising zinc octoate, wherein component (A) is present at a level of greater than about 40% by weight; component (B) is present at a level in a range of between about 1% by weight and about 20% by weight; component (C) is present at a level of less than about 40% by weight; and component (D) and (E) are present at a level in a range between about 0.008% by weight and about 10% by weight based on the combined weight of the silicone resin (A), epoxy resin (B), siloxane surfactant (C), curing agent (D), and ancillary curing catalyst (E). 64. The method of claim 63, wherein the encapsulant further comprises at least one of a thermal stabilizer, a UV stabilizer, or combination thereof. 65. The method of claim 63, wherein the encapsulant is partially cured. 66. The method of claim 63, wherein the encapsulant is cured.
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