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Bimodal inorganic material that in a pore size distribution plot has distinct mesopore and micropore peaks. A process for producing a bimodal material or a material that contains essentially only mesopores involves heating an inorganic oxide in the presence of material that bonds to the inorganic ox

Bimodal inorganic material that in a pore size distribution plot has distinct mesopore and micropore peaks. A process for producing a bimodal material or a material that contains essentially only mesopores involves heating an inorganic oxide in the presence of material that bonds to the inorganic oxide by hydrogen bonding. The micropores may or may not include a crystalline structure.

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1. A process for producing an inorganic oxide that contains micro- and mesopores, comprising:heating a mixture comprising water, an inorganic oxide, a crystalline zeolite in finely divided form, and at least one compound that binds to the inorganic oxide by hydrogen bonding, said compound being sele

1. A process for producing an inorganic oxide that contains micro- and mesopores, comprising:heating a mixture comprising water, an inorganic oxide, a crystalline zeolite in finely divided form, and at least one compound that binds to the inorganic oxide by hydrogen bonding, said compound being selected from the group consisting of triethanolamine, sulfolane, tetraethylpentamine, diethylgycoldibenzoate, and a glycol, said heating being to a temperature and for a time to produce an inorganic oxide that contains both micropores and mesopores. 2. The process of claim 1 wherein said compound is triethanolamine. 3. The process of claim 1 wherein the mixture further includes a micropore forming agent. 4. The process of claim 3 wherein said micropore forming agent is a quaternary ammonium cation. 5. The process of claim 3 wherein the inorganic oxide is an amorphous silicate. 6. The process of claim 5 wherein the heating includes maintaining the mixture about the boiling point of water to evaporate water and volatile organics from the inorganic oxide, followed by calcining at a temperature of above 300° C. 7. The process of claim 1 wherein the inorganic oxide is a silicate material selected from the group consisting of tetraethyl orthosilicate, fumed silica, sodium silicate and silica sol. 8. The process of claim 1 wherein the glycol has a boiling point of at least 150° C. 9. The process of claim 8 wherein the glycol is selected from the group consisting of glycerol, diethylene glycol, triethylene glycol and tetraethylene glycol. 10. The process of claim 9 wherein the mixture additionally contains a source of ions selected from the group consisting of IVA, VB, VIB, VIIB, VIII, IB, IIB and IIIA elements. 11. The process of claim 9 wherein the mixture additionally contains a source of aluminium ions. 12. The process of claim 1 wherein the inorganic oxide comprises alumina. 13. The process of claim 1 wherein the average particle size of the zeolite is from 5 to 1500 nanometers. 14. A product comprising:an inorganic oxide and zeolite beta, said product including mesopores and micropores, said micropores being present in an amount of from 3% to 60%, by pore volume, based on micropores and mesopores, said mesopores having been generated by an organic pore-forming agent selected from the group consisting of triethanolamine, sulfolane, tetraethylpentamine, diethylglycoldibenzoate, and a glycol. 15. The product of claim 14 wherein the BET surface area is from 50 to 1250 m 2 /g. 16. The product of claim 14 wherein the combined micro- and mesopore volume is from 0.3 to 2.2 ml/g. 17. The product of claim 14 wherein the pore size distribution of the mesopores produces a pore size distribution plot in which the ratio of the width of the plot at half the height of the plot to the pore size at the maximum height of the plot is no greater than 0.75. 18. The product of claim 14 wherein a pore size distribution plot of mesopores and micropores includes distinct mesopore and micropore peaks. 19. The product of claim 14 wherein the inorganic oxide comprises alumina. 20. The product of claim 14 wherein the average particle size of the zeolite beta is from 5 to 1500 nanometers. 21. A process for producing an inorganic oxide that contains mesopores and a substantial amount of micropores, comprising:heating a mixture comprising water, an inorganic oxide, a crystalline zeolite, and at least one compound that binds to the inorganic oxide by hydrogen bonding, said compound being selected from the group consisting of triethanolamine, sulfolane, tetraethylpentamine, diethylglycoldibenzoate and a glycol, said heating being to a temperature below the temperature at which there is substantial formation of mesopores, and removing said at least one compound at a temperature below the temperature at which there is substantial formation of mesopores to produce an inorganic oxide that contains mesopores and a substantial amount of micropores. 22. The process o f claim 21 wherein said zeolite is zeolite beta. 23. The process of claim 21 wherein the mixture additionally contains a source of ions selected from the group consisting of IVA, VB, VIB, VIIB, VIII, IB, IIB, and IIIA elements. 24. The process of claim 21 wherein the mixture additionally contains a source of aluminum ions. 25. The process of claim 21 wherein the inorganic oxide comprises alumina. 26. The process of claim 21 wherein the average particle size of the zeolite is from 5 to 1500 nanometers.