Oxygen barrier copolymers and methods of making the same are disclosed. The oxygen barrier copolymers comprise repeating units derived from vinylidene chloride and oxygen scavenging repeating units. The oxygen scavenging repeating units can comprise oxygen scavenging moieties that are cycloalkenyl.
Oxygen barrier copolymers and methods of making the same are disclosed. The oxygen barrier copolymers comprise repeating units derived from vinylidene chloride and oxygen scavenging repeating units. The oxygen scavenging repeating units can comprise oxygen scavenging moieties that are cycloalkenyl. Oxygen barrier compositions, methods of preparing oxygen barrier compositions, and packaging articles comprising oxygen barrier copolymer are also disclosed.
대표청구항▼
1. An oxygen barrier composition, comprising:an oxygen barrier copolymer comprising repeating units having the formula (I), and repeating units having formula (II),wherein R is hydrogen or methyl; X is —(C═O)—O—, —O—(C═O)—, —(C═O)
1. An oxygen barrier composition, comprising:an oxygen barrier copolymer comprising repeating units having the formula (I), and repeating units having formula (II),wherein R is hydrogen or methyl; X is —(C═O)—O—, —O—(C═O)—, —(C═O)—NH—, —O—; t is 0 or 1; s is an integer between 0 and 12, inclusive; J is a cycloalkenyl group; andwherein the composition comprises at least about 50 mole % of repeating units having formula (I) and at least about 2 mole % of repeating units having formula (II). 2. The composition of claim 1, wherein the oxygen barrier copolymer comprises 50 mole % of repeating units having formula (I) and at least about 5 mole % of repeating units having formula (II). 3. The composition of claim 1, wherein J is selected from substituted cyclohexenyls, unsubstituted cyclohexenyl, substituted norbornenyl, and unsubstituted norbornenyl. 4. The composition of claim 1, wherein J is selected from chemical groups having the formula (VI) or the formula (VII)wherein Q is —(CR 2 R 3 ) n —; n is an integer from 0 to 3, inclusive; Z is —(CR 4 R 5 ) e —; e is an integer from 0 to 3, inclusive; n+e≦3; q 0 , q1, q 2 , q 3 , q 4 , r, each R 2 , each R 3 , each R 4 , and each R 5 are independently selected from hydrogen, linear C 1 -C 20 alkyls, branched C 1 -C 20 alkyls, Cyclic C 1 -C 20 alkyls, polycyclic C 1 -C 20 alkyls, aromatic groups, halogens, and sulfur-containing substituents; in formula (VI) when r is hydrogen at least one of q 1 , q 2 , q 3 , and q 4 is hydrogen; and in formula (VII) when r is hydrogen at least one of q 1 and q 2 is hydrogen. 5. The composition of claim 1, wherein the copolymer further comprises a plurality of units having formula (IV)wherein R 6 is hydrogen or methyl, and R 7 is —CN or —COOR″, and wherein R″ is H or a C 1 -C 6 alkyl. 6. The composition of claim 5, wherein R 7 is —COOH or —COOCH 3 . 7. The composition of claim 1, wherein the composition further comprises an oxidation catalyst. 8. The composition of claim 7, wherein the oxidation catalyst comprises a transition metal selected from cobalt, copper, nickel, iron, manganese, rhodium, or ruthenium. 9. The composition of claim 1, further comprising at least one material selected from photoinitiators and antioxidants. 10. The composition of claim 1, wherein the composition comprises a polymer blend comprising a polyvinylidene chloride polymer. 11. A method of preparing an oxygen barrier composition, comprising:blending a mixture comprising a polyvinylidene chloride polymer, an oxidation catalyst, and an oxygen barrier copolymer to produce an oxygen barrier composition, wherein the oxygen barrier copolymer comprisesrepeating units having the formula (I), and repeating units having formula (II)wherein R is hydrogen or methyl; X is —(C═O)—O—, —O—(C═O)—, —(C═O)—NH—, —O—; t is 0 or 1; s is an integer between 0 and 12, inclusive; J is a cycloalkenyl group; andwherein the oxygen barrier copolymer comprises at least about at least about 50 mole % of repeating units having the formula (I) and at least about 5 mole % of repeating units having formula (II). 12. The method of claim 11, wherein J is selected from substituted cyclohexenyls, unsubstituted cyclohexenyl, substituted norbornenyl, and unsubstituted norbornenyl. 13. The method of claim 11, wherein J is selected from chemical groups having the formula (VI) or the formula (VII)wherein Q is —(CR 2 R 3 ) n —; n is an integer from 0 to 3, inclusive; Z is —(CR 4 R 5 ) e —; e is an integer from 0 to 3, inclusive; n+e≦3; q 0 , q 1 , q 2 , q 3 , q 4 , r, each R 2 , each R 3 , each R 4 , and each R 5 are independently selected from hydrogen, linear C 1 -C 20 alkyls, branched C 1 -C 20 alkyls, cyclic C 1 -C 20 alkyls, polycyclic C 1 -C 20 alkyls, aromatic groups, halogens, and sulfur-containing substituents; in formula (VI) when r is hydrogen at least one of q 1 , q 2 , q 3 , and q 4 is hydrogen; and in formula (VII) when r is hydrogen at least one of q 1 and q 2 is hydrogen. 14. The method of claim 11, wherein the copolymer further comprises a plurality of units having formula (IV)wherein R 6 is hydrogen or methyl, and R 7 is —CN or —COOR″, and wherein R″ is H or a C 1 -C 6 alkyl. 15. The method of claim 14, wherein R 7 is —COOH or —COOCH 3 . 16. The method of claim 11, wherein the oxidation catalyst comprises a transition metal selected from cobalt, copper, nickel, iron, manganese, rhodium, or ruthenium. 17. The method of claim 11, wherein the mixture further comprises at least one material selected from photoinitiators and antioxidants.
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