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In a method for operating an internal combustion engine using exhaust gas purification system, and internal combustion engine, the method for operating an internal combustion engine with exhaust gas purification system, in which a rich mode of the internal combustion engine with a rich exhaust gas c

In a method for operating an internal combustion engine using exhaust gas purification system, and internal combustion engine, the method for operating an internal combustion engine with exhaust gas purification system, in which a rich mode of the internal combustion engine with a rich exhaust gas composition and a lean mode of the internal combustion engine with a lean exhaust gas composition are set alternately, and by the exhaust gas purification system with a rich exhaust gas composition ammonia is synthesized and stored and with a lean exhaust gas composition nitrogen oxides are reduced to form nitrogen by means of the stored ammonia. The quantity of fuel which is introduced by a combustion cycle of the internal combustion engine is introduced by at least one preinjection, at least one main injection and at least one afterinjection, the at least one preinjection and the at least one main injection are burnt under excess oxygen in order to generate a quantity of nitrogen oxides which is sufficient for the ammonia synthesis, and a rich or lean exhaust gas composition is set by the at least one afterinjection. The method may be used, for example, for exhaust gas purification in motor vehicle diesel engines.

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1. A method for operating an internal combustion engine including an exhaust gas purification system, comprising:alternately setting a rich mode of the internal combustion engine with a rich exhaust gas composition and a lean mode of the internal combustion engine with a lean exhaust gas composition

1. A method for operating an internal combustion engine including an exhaust gas purification system, comprising:alternately setting a rich mode of the internal combustion engine with a rich exhaust gas composition and a lean mode of the internal combustion engine with a lean exhaust gas composition;synthesizing and storing ammonia by the exhaust gas purification system with the rich exhaust gas composition;reducing nitrogen oxides to form nitrogen by the stored ammonia by the exhaust gas purification system with the lean exhaust gas composition;introducing a quantity of fuel during a combustion cycle of the internal combustion engine by at least one preinjection, at least one main injection and at least one afterinjection; andburning the at least one preinjection and the at least one main injection under excess oxygen to generate a quantity of nitrogen oxides sufficient for ammonia synthesis;wherein the rich exhaust gas composition and the lean exhaust gas composition are set in the setting step in accordance with the at least one afterinjection. 2. The method according to claim 1, further comprising at least partially burning the at least one afterinjection in a combustion chamber, the at least partial burning of the at least one afterinjection contributing to engine load. 3. The method according to claim 1, further comprising combusting in rich mode the quantity of fuel introduced during a combustion cycle of the internal combustion engine without gas recirculation. 4. The method according to claim 1, wherein the lean exhaust gas composition and the rich exhaust gas composition are set in the setting step in accordance with at least one first afterinjection that burns in a combustion chamber and at least one further, offset afterinjection. 5. The method according to claim 1, wherein starts of injection of the preinjection in the rich mode substantially correspond to starts of injection of the preinjection in the lean mode. 6. The method according to claim 1, wherein starts of injection of the main injection in the rich mode substantially correspond to starts of injection of the main injection in the lean mode. 7. The method of claim 1, wherein the quantity of nitrogen oxides are generated even during a rich mode. 8. The method of claim 1, wherein the quantity of nitrogen oxides are generated even during a rich mode to shorten a duration of the rich mode. 9. The method of claim 1, wherein the quantity of nitrogen oxides are generated even during a rich mode so that nitrogen oxide storage during a lean mode and nitrogen oxide release during the rich mode are not required. 10. The method of claim 1, wherein the quantity of nitrogen oxides are generated even during a rich mode to shorten a duration of the rich mode, and so that nitrogen oxide storage during a lean mode and nitrogen oxide release during the rich mode are not required. 11. An internal combustion engine having an exhaust gas purification system, comprising:a first catalytic converter unit configured to generate ammonia with a rich exhaust gas composition from corresponding exhaust gas constituents;a second catalytic converter unit arranged downstream of the first catalytic converter unit and configured to temporarily store ammonia generated by the first catalytic converter unit with a rich exhaust gas composition and to subject nitrogen oxides present in exhaust gas to a reduction reaction using the temporarily stored ammonia as a reagent with a lean exhaust gas composition; andan injection system including:an arrangement configured to introduce a quantity of fuel in accordance with at least one preinjection, at least one main injection and at least one afterinjection;an arrangement configured to set an excess of oxygen in rich mode during combustion of the at least one preinjection and at least one main injection in a combustion chamber; andan arrangement configured to alter a time, a quantity and a duration of the at least one afterinjection to set one of the r ich exhaust gas composition and the lean exhaust gas composition;wherein the at least one preinjection and the at least one main injection are burned under the excess oxygen to generate a quantity of nitrogen oxides sufficient for ammonia synthesis. 12. The internal combustion engine of claim 11, wherein the quantity of nitrogen oxides are generated even during a rich mode. 13. The internal combustion engine of claim 11, wherein the quantity of nitrogen oxides are generated even during a rich mode to shorten a duration of the rich mode. 14. The internal combustion engine of claim 11, wherein the quantity of nitrogen oxides are generated even during a rich mode so that nitrogen oxide storage during a lean mode and nitrogen oxide release during the rich mode are not required. 15. The internal combustion engine of claim 11, wherein the quantity of nitrogen oxides are generated even during a rich mode to shorten a duration of the rich mode, and so that nitrogen oxide storage during a lean mode and nitrogen oxide release during the rich mode are not required. 16. The internal combustion engine of claim 11, wherein the at least one afterinjection is at least partially burned in a combustion chamber, the at least partial burning of the at least one afterinjection contributing to engine load. 17. The internal combustion engine of claim 11, further comprising combusting in rich mode the quantity of fuel introduced during a combustion cycle of the internal combustion engine without gas recirculation. 18. The internal combustion engine of claim 11, wherein the lean exhaust gas composition and the rich exhaust gas composition are set in accordance with at least one first afterinjection that burns in a combustion chamber and at least one further, offset afterinjection. 19. The internal combustion engine of claim 11, wherein starts of injection of the preinjection in a rich mode substantially correspond to starts of injection of the preinjection in a lean mode. 20. The internal combustion engine of claim 11, wherein starts of injection of the main injection in a rich mode substantially correspond to starts of injection of the main injection in a lean mode. 21. An internal combustion engine having an exhaust gas purification system, comprising:a first catalytic converter unit configured to generate ammonia with a rich exhaust gas composition from corresponding exhaust gas constituents;a second catalytic converter unit arranged downstream of the first catalytic converter unit and configured to temporarily store ammonia generated by the first catalytic converter unit with a rich exhaust gas composition and to subject nitrogen oxides present in exhaust gas to a reduction reaction using the temporarily stored ammonia as a reagent with a lean exhaust gas composition; andan injection system including:means for introducing a quantity of fuel in accordance with at least one preinjection, at least one main injection and at least one afterinjection;means for setting an excess of oxygen in rich mode during combustion of the at least one preinjection and at least one main injection in a combustion chamber; andmeans for altering a time, a quantity and a duration of the at least one afterinjection to set one of the rich exhaust gas composition and the lean exhaust gas composition;wherein the at least one preinjection and the at least one main injection are burned under the excess oxygen to generate a quantity of nitrogen oxides sufficient for ammonia synthesis. 22. The internal combustion engine of claim 21, wherein the quantity of nitrogen oxides are generated even during a rich mode. 23. The internal combustion engine of claim 21, wherein the quantity of nitrogen oxides are generated even during a rich mode to shorten a duration of the rich mode. 24. The internal combustion engine of claim 21, wherein the quantity of nitrogen oxides are generated even during a rich mode so that nitrogen oxide storage during a lean mode and nitrogen oxide release during the rich mode are not required. 25. The internal combustion engine of claim 21, wherein the quantity of nitrogen oxides are generated even during a rich mode to shorten a duration of the rich mode, and so that nitrogen oxide storage during a lean mode and nitrogen oxide release during the rich mode are not required. 26. The internal combustion engine of claim 21, wherein the at least one afterinjection is at least partially burned in a combustion chamber, the at least partial burning of the at least one afterinjection contributing to engine load. 27. The internal combustion engine of claim 21, further comprising combusting in rich mode the quantity of fuel introduced during a combustion cycle of the internal combustion engine without gas recirculation. 28. The internal combustion engine of claim 21, wherein the lean exhaust gas composition and the rich exhaust gas composition are set in accordance with at least one first afterinjection that burns in a combustion chamber and at least one further, offset afterinjection. 29. The internal combustion engine of claim 21, wherein starts of injection of the preinjection in a rich mode substantially correspond to starts of injection of the preinjection in a lean mode. 30. The internal combustion engine of claim 21, wherein starts of injection of the main injection in a rich mode substantially correspond to starts of injection of the main injection in a lean mode.