IPC분류정보
국가/구분 |
United States(US) Patent
등록
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국제특허분류(IPC7판) |
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출원번호 |
US-0301455
(2002-11-21)
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발명자
/ 주소 |
- Kupe, Joachim
- Zizelman, James
- Botti, Jean J.
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출원인 / 주소 |
- Delphi Technologies, Inc.
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대리인 / 주소 |
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인용정보 |
피인용 횟수 :
63 인용 특허 :
42 |
초록
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An active system for regenerating a NO x adsorber and a particulate filter, the system comprising a fuel source, a reformer for generating hydrogen and carbon monoxide in fluid communication with the fuel source, a first valve, a second valve, and a third valve in fluid communication with the refor
An active system for regenerating a NO x adsorber and a particulate filter, the system comprising a fuel source, a reformer for generating hydrogen and carbon monoxide in fluid communication with the fuel source, a first valve, a second valve, and a third valve in fluid communication with the reformer, an oxidation catalyst, a NO x adsorber located downstream from the oxidation catalyst, a particulate filter located downstream from the NO x adsorber; and wherein the first valve, the second valve, and the third valve control fluid flow from the reformer to the oxidation catalyst, the NO x adsorber, and the particulate filter.
대표청구항
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1. A process for regenerating at least one of a NO x adsorber and a particulate filter disposed in an exhaust conduit, the process comprising;periodically supplying a fuel to a reformer;converting said fuel to a hydrogen and carbon monoxide containing fluid;periodically and selectively pulsing the
1. A process for regenerating at least one of a NO x adsorber and a particulate filter disposed in an exhaust conduit, the process comprising;periodically supplying a fuel to a reformer;converting said fuel to a hydrogen and carbon monoxide containing fluid;periodically and selectively pulsing the hydrogen and carbon monoxide containing fluid into a selected one of an oxidation catalyst, a NOx adsorber, or a particulate filter; andgenerating an exotherm in the oxidation catalyst and heating an exhaust fluid passing therethrough to a temperature effective to regenerate a particulate filter disposed downstream from the oxidation catalyst, or regenerating the NOx adsorber by reacting the fluid containing the hydrogen and carbon monoxide with the nitrogen oxides trapped by the NOx adsorber, or generating an exotherm in the oxidation catalyst and heating an exhaust fluid passing therethrough to a temperature effective to desulfate the NOx adsorber, or a combination thereof. 2. The process of claim 1, wherein said reformer is a partial oxidation reformer. 3. The process of claim 1, wherein the exhaust fluid as it flows through the particulate filter is at a temperature less than or equal to about 550° C. 4. The process of claim 1, wherein the exhaust fluid as it flows through the NOx adsorber is at a temperature of about 200° C. to about 600° C. 5. The process of claim 1, wherein the exhaust fluid as it flows through the NOx adsorber is at a temperature of about 300° C. to about 500° C. 6. A process for regenerating a NOx adsorber, comprising;supplying a fuel to a reformer;converting the fuel to a hydrogen and carbon monoxide containing fluid;introducing the hydrogen and carbon monoxide containing fluid to into the NOx adsorber; andregenerating the NOx adsorber by reacting the fluid containing the hydrogen and carbon monoxide with the nitrogen oxides trapped by the NOx adsorber. 7. A process for desulfating a NOx adsorber, comprising;supplying a fuel to a reformer;converting the fuel to a hydrogen and carbon monoxide containing fluid;introducing the hydrogen and carbon monoxide containing fluid to into an oxidation catalyst;generating an exotherm in a oxidation catalyst and heating an exhaust fluid passing therethrough to a temperature effective to desulfate the NOx adsorber;introducing the heated exhaust fluid to the NOx adsorber; anddesulfating the NOx adsorber. 8. A process for regenerating a particulate filter, comprising:supplying a fuel to a reformer;converting the fuel to a hydrogen and carbon monoxide containing fluid;introducing the hydrogen and carbon monoxide containing fluid to an oxidation catalyst;generating an exotherm in a oxidation catalyst and heating an exhaust fluid passing therethrough to a temperature effective to regenerate a particulate filter;introducing the heated exhaust fluid to the particulate filter; andregenerating the particulate filter. 9. A regeneration and desulfating system comprising:an exhaust conduit in fluid communication with an exhaust fluid from an engine, wherein the exhaust conduit comprises a first oxidation catalyst, a NO x adsorber, and a second oxidation catalyst coupled to a particulate filter;a fuel source in fluid communication with a reformer, wherein the reformer is adapted to generate a hydrogen and carbon monoxide containing fluid from a fuel supplied by the fuel source;a regeneration conduit in fluid communication with the exhaust conduit and the reformer; andvalve means disposed in the regeneration conduit for selectively controlling and directing the hydrogen and carbon monoxide containing fluid from the reformer to the first oxidation catalyst, the coupled second oxidation catalyst and particulate filter, and the NOx adsorber, wherein the first oxidation catalyst, the NOx adsorber, and the coupled second oxidation catalyst and particulate filter are serially disposed in the exhaust conduit, wherein the exhaust fluid from the engine first flows th rough the oxidation catalyst, then the NOx adsorber, and then the particulate filter. 10. A process for regenerating at least one of a NO x adsorber and a particulate filter disposed in an exhaust conduit, the process comprising;periodically supplying a fuel to a reformer;converting said fuel to a hydrogen and carbon monoxide containing fluid;directing the hydrogen and carbon monoxide containing fluid to the NOx adsorber and reducing nitrogen oxides trapped by the NOx adsorber; andgenerating an exotherm in an oxidation catalyst, heating an exhaust fluid passing therethrough, and regenerating the particulate filter disposed downstream from the oxidation catalyst. 11. The process of claim 10, further comprising: generating an exotherm in the oxidation catalyst, heating an exhaust fluid passing therethrough, and desulfating the NOx adsorber disposed downstream from the oxidation catalyst. 12. A regeneration and desulfating system comprising:an exhaust conduit in fluid communication with an exhaust fluid from an engine, wherein the exhaust conduit comprises a first oxidation catalyst, a NOx adsorber, and a second oxidation catalyst coupled to a particulate filter;a fuel source in fluid communication with a reformer, wherein the reformer is adapted to generate a hydrogen and carbon monoxide containing fluid from a fuel supplied by the fuel source;a regeneration conduit in fluid communication with the exhaust conduit and the reformer; andvalve means disposed in the regeneration conduit for selectively controlling and directing the hydrogen and carbon monoxide containing fluid from the reformer to the first oxidation catalyst, the coupled second oxidation catalyst and particulate filter, the NOx adsorber, or a combination thereof. 13. The system of claim 12, wherein said reformer is a partial oxidation reformer. 14. The system of claim 12, wherein said particulate filter comprises a catalyst selected from the group consisting of platinum, palladium, rhodium, nickel, iron, cobalt, molybdenum, tungsten, vanadium, niobium, tantalum, their oxides and sulfides, and mixtures thereof. 15. The system of claim 12, wherein said fuel source is selected from the group consisting gasoline, diesel, ethanol, methanol, kerosene, natural gas, propane, butane, biofuels, dimethyl ether, and mixtures thereof. 16. The system of claim 12, wherein the valve means comprises a first valve for providing a selected fluid flow from the reformer to the oxidation catalyst, a second valve for providing a selected fluid flow from the reformer to the NOx adsorber, and a third valve for providing a selected fluid flow from the reformer to the second oxidation catalyst coupled to the particulate filter. 17. The system of claim 12, wherein the first oxidation catalyst, the NOx adsorber, and the coupled second oxidation catalyst and particulate filter are serially disposed in the exhaust conduit, wherein the exhaust fluid from the engine first flows through the oxidation catalyst, then the NOx adsorber, and then the coupled second oxidation catalyst and particulate filter. 18. The system of claim 12, wherein the oxidation catalyst, the NOx adsorber, and the coupled second oxidation catalyst and particulate filter are serially disposed in the exhaust conduit, wherein the exhaust fluid from the engine first flows through the coupled second oxidation catalyst and particulate filter, then the oxidation catalyst, and then the NOx adsorber. 19. The system of claim 12, wherein said NO x adsorber comprises a porous support, a catalytic metal component, and a NO x trapping material. 20. The system of claim 19, wherein said catalytic metal is selected from the group consisting of platinum, palladium, rhodium, iridium, osmium, ruthenium, tantalum, zirconium, yttrium, cerium, aluminum, nickel, copper, and mixtures thereof. 21. The system of claim 19, wherein said porous support is selected from the group consisting of alumina, gamma-alumina, zirconia, alpha-alumina, magnesium ox ide cerium oxide, zirconium oxide, lanthanum oxide, yttrium oxide, neodymium oxide, and mixtures thereof.
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