초록 ▼

A fuel cell contains an electrolyte sheet sandwiched between two electrodes. One or both electrode/electrolyte interfaces includes mesoscopic three-dimensional features in a prescribed pattern. The features increase the surface area-to-volume ratio of the device and can be used as integral channels

A fuel cell contains an electrolyte sheet sandwiched between two electrodes. One or both electrode/electrolyte interfaces includes mesoscopic three-dimensional features in a prescribed pattern. The features increase the surface area-to-volume ratio of the device and can be used as integral channels for directing the flow of reactant gases to the reaction surface area, eliminating the need for channels in sealing plates surrounding the electrodes. The electrolyte can be made by micromachining techniques that allow very precise feature definition. Both selective removal and mold-filling techniques can be used. The fuel cell provides significantly enhanced volumetric power density when compared with conventional fuel cells.

대표청구항 ▼

1. A fuel cell comprising:a) two electrodes; andb) an electrolyte sheet sandwiched between said electrodes to form an electrode/electrolyte structure, thereby defining first and second interfaces between said electrolyte sheet and said electrodes, at least one of said interfaces having three-dimensi

1. A fuel cell comprising:a) two electrodes; andb) an electrolyte sheet sandwiched between said electrodes to form an electrode/electrolyte structure, thereby defining first and second interfaces between said electrolyte sheet and said electrodes, at least one of said interfaces having three-dimensional features in a prescribed pattern, wherein said prescribed pattern is selected to direct a flow of a reactant from an inlet region of said fuel cell to an outlet region of said fuel cell and wherein said prescribed pattern comprises a plurality of discrete channels for directing said reactant flow therethrough, and wherein said electrode/electrolyte structure has a substantially planar peripheral portion surrounding said three-dimensional features of said at least one of said interfaces, said fuel cell further comprising a sealing plate for contacting said substantially planar peripheral portion of said electrode/electrolyte structure to seal said channels. 2. The fuel cell of claim 1, wherein a ratio of a surface area of said at least one interface to a projected surface area of said at least one interface is greater than approximately 2. 3. The fuel cell of claim 1, wherein said first interface has three-dimensional structure in a first prescribed pattern and said second interface has three-dimensional structure in a second prescribed pattern. 4. The fuel cell of claim 3, wherein said first and second prescribed patterns are complementary such that a thickness of said electrolyte sheet is substantially constant between said first and second prescribed patterns. 5. The fuel cell according to claim 3, wherein said first prescribed pattern is different from said second prescribed pattern. 6. The fuel cell of claim 5, wherein said first and second patterns are selected in dependence on the type of reactants contacting said first and second interfaces, respectively. 7. The fuel cell of claim 1, wherein said prescribed pattern is selected in dependence on the type of reactant contacting said at least one interface. 8. The fuel cell of claim 1, wherein said electrolyte is a polymer. 9. The fuel cell of claim 8, wherein said polymer is a proton-exchange membrane. 10. The fuel cell of claim 8, wherein said polymer is shaped by a method selected from the group consisting of direct casting, injection molding, embossing, laser machining, laminated layer assembly, selective plasma etching, blow molding, and autoclaving. 11. The fuel cell of claim 1, wherein said electrolyte is a solid oxide. 12. The fuel cell of claim 11, wherein said solid oxide is an ion-exchange membrane. 13. The fuel cell of claim 11, wherein said solid oxide is shaped by a method selected from the group consisting of chemical vapor deposition, gel casting, powder sintering, and sol-gel processing. 14. The fuel cell of claim 1, wherein said three-dimensional features further comprise an additional pattern superimposed on said prescribed pattern, said additional pattern and said prescribed pattern having different length scales. 15. The fuel cell of claim 1, wherein said three-dimensional features have widths of between approximately 5 and 500 μm. 16. The fuel cell of claim 1, wherein said three-dimensional features have depth-to-width aspect ratios greater than approximately 1:2. 17. The fuel cell of claim 1, wherein said electrodes comprise a porous conductive material. 18. The fuel cell according to claim 1, wherein said inlet region and said outlet region communicate with only a portion of said plurality of channels. 19. The fuel cell of claim 1, wherein said plurality of channels comprise continuous serpentine channels and said inlet and outlet regions each communicate with only one channel. 20. A fuel cell comprising:a) two electrodes; andb) an electrolyte sheet sandwiched between said electrodes to form an electrode/electrolyte structure, thereby defining first and second interfaces between said electrolyte sheet and said electrodes, at least one of said i nterfaces having three-dimensional features in a prescribed pattern, wherein said prescribed pattern is selected to direct a flow of a reactant from an inlet region of said fuel cell to an outlet region of said fuel cell, and wherein said prescribed pattern defines a discrete serpentine path for directing said reactant flow therethrough such that said inlet region and said outlet region communicate with respective end portions of said serpentine path, and wherein said electrode/electrolyte structure has a substantially planar peripheral portion surrounding said three-dimensional features of said at least one of said interfaces, said fuel cell further comprising a sealing plate for contacting said substantially planar peripheral portion of said electrode/electrolyte structure to seal said serpentine path. 21. A fuel cell comprising:a) two electrodes; andb) an electrolyte sheet sandwiched between said electrodes, thereby defining first and second interfaces between said electrolyte sheet and said electrodes, at least one of said interfaces having three dimensional features in a prescribed pattern, wherein said prescribed pattern is selected to direct flow of reactant from an inlet region of said fuel cell to an outlet region of said fuel cell such that said inlet region and said output region communicate with only a portion of said three-dimensional features, wherein said electrodes each consist of a conductive grid and wherein at least one of said conductive grids associated with said at least one of said interfaces is conformal to said three-dimensional features of said at least one of said interfaces. 22. The fuel cell of claim 15, wherein said at least one of said conductive grids is formed by physical vapor deposition.