Catalyst for selectively oxidizing carbon monoxide
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
B01J-02108
C01B-03120
출원번호
US-0232823
(2002-09-03)
우선권정보
JP-0232481 (2002-08-09); JP-0265409 (2001-09-03)
발명자
/ 주소
Hoshino, Maki
Kaneko, Hiroaki
출원인 / 주소
Nissan Motor Co., Ltd.
대리인 / 주소
McDermott Will &
인용정보
피인용 횟수 :
4인용 특허 :
11
초록▼
A catalyst (5) for selectively oxidizing carbon monoxide, wherein a noble metal (3) and an active oxygen supply material (4) capable of oxidizing carbon monoxide are supported on a substrate (6). Favorable selective oxidation of carbon monoxide can be obtained by setting the distance between the nob
A catalyst (5) for selectively oxidizing carbon monoxide, wherein a noble metal (3) and an active oxygen supply material (4) capable of oxidizing carbon monoxide are supported on a substrate (6). Favorable selective oxidation of carbon monoxide can be obtained by setting the distance between the noble metal (3) and the active oxygen supply material (4) such that the noble metal (3) is close enough to accept active oxygen from the active oxygen supply material (4), and preferably within 0.1 mm. This catalyst (5) for selectively oxidizing carbon monoxide is effective at removing carbon monoxide from a reformate gas whose main component is hydrogen and which is supplied to a fuel cell.
대표청구항▼
1. A catalyst for selectively oxidizing carbon monoxide, comprising:a substrate; a noble metal comprising ruthenium and platinum supported on the substrate, the mass ratio between ruthenium and platinum being from 1:0.2 to 1:5; and a supply material supported on the substrate for supplying active ox
1. A catalyst for selectively oxidizing carbon monoxide, comprising:a substrate; a noble metal comprising ruthenium and platinum supported on the substrate, the mass ratio between ruthenium and platinum being from 1:0.2 to 1:5; and a supply material supported on the substrate for supplying active oxygen to the noble metal, the distance between the supply material and the noble metal being set to no more than 0.1 millimeter to cause the active oxygen to be transferred from the supply material to the noble metal. 2. The catalyst for selectively oxidizing carbon monoxide as defined in claim 1, wherein the supply material comprises one of an alkali metal compound, an alkaline earth metal compound, and a rare earth metal compound, and the amount in which the supply material is supported is, in terms of metal amount, from 0.1 to 20 mass percent with respect to an amount of the substrate.3. The catalyst for selectively oxidizing carbon monoxide as defined in claim 1, wherein the substrate comprises one of alumina, titania, silica, and zirconia.4. The catalyst for selectively oxidizing carbon monoxide as defined in claim 2, wherein the alkali metal compound comprises one of potassium, cesium, rubidium, sodium, and lithium.5. The catalyst for selectively oxidizing carbon monoxide as defined in claim 2, wherein the alkaline earth metal compound comprises one of barium, calcium, magnesium, and strontium.6. The catalyst for selectively oxidizing carbon monoxide as defined in claim 2, wherein the rare earth metal compound comprises one of lanthanum, cerium, praseodymium, neodymium, samarium, and gadolinium.7. A method for reducing the carbon monoxide concentration of a reformate gas using the catalyst for selectively oxidizing carbon monoxide as defined in claim 1, wherein the carbon monoxide contained in a reformate gas is selectively oxidized into carbon dioxide by bringing a mixed gas of the reformate gas and oxygen into contact with the catalyst for selectively oxidizing carbon monoxide.8. The carbon monoxide concentration reduction method as defined in claim 7, wherein the mixed gas is brought into contact with the catalyst for selectively oxidizing carbon monoxide at a temperature between 60° C. and 200° C.9. The carbon monoxide concentration reduction method as defined in claim 7, wherein the reformate gas contains, in terms of volumetric ratio, no more than 10 percent unreformed fuel.10. A method for manufacturing the catalyst for selectively oxidizing carbon monoxide as defined in claim 1, comprising:(a) forming an impregnated substrate, in which a substrate is impregnated with a precursor of an active oxygen supply material and a precursor of a noble metal at a water content that is no more than the saturated water absorption of the substrate; (b) drying the impregnated substrate; and (c) subjecting the dried impregnated substrate to a reduction treatment in a reductive gas. 11. The method for manufacturing a catalyst for selectively oxidizing carbon monoxide as defined in claim 10, wherein the impregnated substrate is dried at a temperature between 40° C. and 100° C.12. The method for manufacturing a catalyst for selectively oxidizing carbon monoxide as defined in claim 10, wherein the reductive gas is hydrogen gas.13. The method for manufacturing a catalyst for selectively oxidizing carbon monoxide as defined in claim 10, wherein the space velocity of the reductive gas is at least 1000 hour?1.14. The method for manufacturing a catalyst for selectively oxidizing carbon monoxide as defined in claim 10, wherein the active oxygen supply material comprises one of an alkali metal compound, an alkaline earth metal compound, and a rare earth metal compound.15. The method for manufacturing a catalyst for selectively oxidizing carbon monoxide as defined in claim 10, wherein the active oxygen supply material comprises a cesium-containing compound.16. The method for manufacturing a catalyst for selectively oxidizing carbon monoxide as defined in claim 15, wherein the precursor of the active oxygen supply material comprises cesium nitrate.17. The method for manufacturing a catalyst for selectively oxidizing carbon monoxide as defined in claim 10, wherein the substrate comprises an alumina substrate.
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이 특허에 인용된 특허 (11)
Satoshi Aoyama JP, Apparatus and method for reducing carbon monoxide concentration and catalyst for selectively oxidizing carbon monoxide.
Vasalos Iacovos A. (Downers Grove IL) Ford William D. (Downers Grove IL) Hsieh Chuan-Kang R. (San Rafael CA), Catalytic cracking with reduced emission of noxious gases.
Gunugunuri, Krishna Reddy; Peck, Torin C.; Ling, Chen; Jia, Hongfei, Catalyst for direct NOx decomposition and a method of forming and using the catalyst.
Gunugunuri, Krishna Reddy; Peck, Torin C.; Ling, Chen; Jia, Hongfei, Catalyst for direct NOx decomposition and a method of forming and using the catalyst.
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