초록 ▼

The invention is to provide polyhydroxyalkanoate of a novel structure enabling application to wider fields, and a producing method therefor. The invention also provides a biodegradable charge control agent having excellent charging characteristics, excellent dispersibility in the toner resin and imp

The invention is to provide polyhydroxyalkanoate of a novel structure enabling application to wider fields, and a producing method therefor. The invention also provides a biodegradable charge control agent having excellent charging characteristics, excellent dispersibility in the toner resin and improved spent property. The polyhydroxyalkanoate of the present invention is featured by including, in the polymer molecule, a units represented by the general formulas (1) and (2) and at least one of the units represented by the general formulas (3) to (6).

대표청구항 ▼

1. Polyhydroxyalkanoate comprising, in the polymer molecule, a unit represented by the following general formula (1): (wherein x stands for an integer selected within a range of 0-8 indicated in the chemical formula, and such unit may be present at least one in the polymer);a unit represented by the

1. Polyhydroxyalkanoate comprising, in the polymer molecule, a unit represented by the following general formula (1): (wherein x stands for an integer selected within a range of 0-8 indicated in the chemical formula, and such unit may be present at least one in the polymer);a unit represented by the following general formula (2): (wherein x stands for an integer selected within a range of 0-8 indicated in the chemical formula, and such unit may be present at least one in the polymer); and at least one of the units represented by the following general formulas (3) to (6), namely:a unit represented by the following general formula (3): (wherein x stands for an integer selected within a range of 0-8 indicated in the chemical formula, and such unit may be present at least one in the polymer);a unit represented by the following general formula (4): (wherein x stands for an integer selected within a range of 0-8 indicated in the chemical formula, and such unit may be present at least one in the polymer);a unit represented by the following general formula (5): (wherein x stands for an integer selected within a range of 0-8 indicated in the chemical formula, and such unit may be present at least one in the polymer); anda unit represented by the following general formula (6): (wherein x stands for an integer selected within a range of 0-8 indicated in the chemical formula, and such unit may be present at least one in the polymer).2. Polyhydroxyalkanoate according to claim 1, further comprising, in addition to the unit represented by said general formula (1), the unit represented by said general formula (2) and at least one of the units represented by said general formulas (3) to (6), at least one of:a unit represented by the following general formula (7): (wherein y stands for an integer selected within a range of 0-8 indicated in the chemical formula, and such unit may be present at least one in the polymer); anda unit represented by the following general formula (8): (wherein z stands for an integer selected from 3 and 5).3. Polyhydroxyalkanoate according to claim 1, having a number average molecular weight within a range of 1000 to 500000.4. A method for producing polyhydroxyalkanoate according to claim 1, comprising:(step 1) a step of culturing microorganisms in a culture medium containing at least one of ω-(2-thienylsulfanyl)alkanoic acids represented by the following general formula (27) (wherein x stands for an integer selected from a range of 0 to 8); and(step 2) a step of processing polyhydroxyalkanoate, produced by the microorganisms cultured in the step 1, with sodium hypochlorite. 5. A producing method according to claim 4, further comprising, between said steps 1 and 2:a step of separating polyhydroxyalkanoate produced by said microorganisms cultured in the step 1 from the cells of said microorganisms. 6. A producing method according to claim 5, wherein said step of separating polyhydroxyalkanoate produced by said microorganisms includes a step of pulverizing the microorganism cells.7. A producing method according to claim 5, wherein said step of separating polyhydroxyalkanoate produced by the microorganisms from said cells thereof includes a step of extracting said polyhydroxyalkanoate from the microorganism cells with a solvent capable dissolving polyhydroxyalkanoate produced by the microorganisms.8. A producing method according to claim 4, wherein the culture medium employed in the step 1 contains polypeptone.9. A producing method according to claim 4, wherein the culture medium employed in the step 1 contains yeast extract.10. A producing method according to claim 4, wherein the culture medium employed in the step 1 contains saccharide.11. A producing method according to claim 10, wherein said saccharide is at least one compound selected from a group consisting of glyceraldehyde, erythrose, arabinose, xylose, glucose, galactose, mannose, fructose, glycerol, erythritol, xylitol, gluconic acid, glucuronic acid, galacturonic acid, maltose, sucrose and lactose.12. A producing method according to claim 4, wherein the culture medium employed in the step 1 contains an organic acid or a salt thereof.13. A producing method according to claim 12, wherein said organic acid or salt thereof is at least a compound selected from a group consisting of pyruvic acid, malic acid, lactic acid, citric acid, succinic acid and salts thereof.14. A producing method according to claim 4, wherein the culture medium employed in the step 1 contains an amino acid or a salt thereof.15. A producing method according to claim 14, wherein said amino acid or salt thereof is at least a compound selected from a group consisting of glutamic acid, aspartic acid and salts thereof.16. A producing method according to claim 4, wherein the culture medium employed in the step 1 contains a straight-chain alkanoic acid with 4 to 12 carbon atoms or a salt thereof.17. A producing method according to claim 4, wherein the culture of microorganisms in said step 1 includes:(step 1-1) a step of culturing microorganisms in a culture medium containing at least one of ω-(2-thienylsulfanyl)alkanoic acids represented by the following general formula (27) (wherein x stands for an integer selected from a range of 0 to 8) and polypeptone; and(step 1-2) a step of further culturing the microorganisms, cultured in said step 1-1, in a culture medium containing at least one of ω-(2-thienylsulfanyl)alkanoic acids represented by said general formula (27) and an organic acid or a salt thereof. 18. A producing method according to claim 4, wherein the culture of microorganisms in said step 1 includes:(step 1-3) a step of culturing microorganisms in a culture medium containing at least one of ω-(2-thienylsulfanyl)alkanoic acids represented by the following general formula (27) (wherein x stands for an integer selected from a range of 0-8) and saccharide; and(step 1-4) a step of further culturing the microorganisms, cultured in the step 1-3, in a culture medium containing at least one of ω-(2-thienylsulfanyl)alkanoic acids represented by said general formula (27) and saccharide. 19. A producing method according to claim 4, wherein the microorganisms employed in the step 1 are those belonging to Pseudomonas genus.20. A producing method according to claim 19, wherein said microorganisms employed in the step 1 are those of at least a strain selected from Pseudomonas cichorii YN2 (FERM BP-7375), Pseudomonas cichorii H45 (FERM BP-7374) and Pseudomonas jessenii P161 (FERM BP-7376).21. In a charge control agent, the improvement wherein the charge control agent comprises a polyhydroxyalkanoate including, in the polymer molecule, a unit represented by the following general formula (1): (wherein x stands for an integer selected within a range of 0-8 indicated in the chemical formula, and such unit may be present at least one in the polymer); a unit represented by the following general formula (2): (wherein x stands for an integer selected within a range of 0-8 indicated in the chemical formula, and such unit may be present at least one in the polymer); and at least one of the units represented by the following general formulas (3) to (6), namely:a unit represented by the following general formula (3): (wherein x stands for an integer selected within a range of 0-8 indicated in the chemical formula, and such unit may be present at least one in the polymer);a unit represented by the following general formula (4): (wherein x stands for an integer selected within a range of 0-8 indicated in the chemical formula, and such unit may be present at least one in the polymer);a unit represented by the following general formula (5): (wherein x stands for an integer selected within a range of 0-8 indicated in the chemical formula, and such unit may be present at least one in the polymer); anda unit represented by the following general formula (6): (wherein x stands for an integer selected within a range of 0-8 indicated in the chemical formula, and such unit may be present at least one in the polymer).22. A charge control agent according to claim 21 wherein said polyhydroxyalkanoate further includes, in addition to the unit represented by said general formula (1), the unit represented by said general formula (2) and at least one of the units represented by said general formulas (3) to (6), at least one of:a unit represented by the following general formula (7): (wherein y stands for an integer selected within a range of 0-8 indicated in the chemical formula, and such unit may be present at least one in the polymer); anda unit represented by the following general formula (8): (wherein z stands for an integer selected from 3 and 5) (wherein y and z may assume arbitrary integral values at least equal to 1 within the ranges shown in the chemical formulas, independently from the units represented by (1), (2), (3), (4), (5) and (6)).23. A charge control agent according to claim 21, wherein said polyhydroxyalkanoate has a number average molecular weight within a range of 1000 to 500000.24. A toner binder comprising the charge control agent according to claim 21.25. An electrostatic latent image developing toner comprising, at least, binder resin, a coloring agent, and the charge control agent according to claim 21.26. An image forming method comprising at least a step of externally applying a voltage to a charging member thereby charging an electrostatic latent image bearing member, a step of forming an electrostatic latent image on the charged electrostatic latent image bearing member, a development step of developing the electrostatic latent image with electrostatic latent image developing toner thereby forming a toner image on the electrostatic latent image bearing member, a transfer step of transferring the toner image on the electrostatic latent image bearing member onto a recording material, and a fixation step of heat fixing the toner image on the recording material;the method comprising the use of electrostatic latent image developing toner comprising at least a binder resin, a coloring agent, and a charge control agent according to claim 21. 27. An image forming method at least comprising a step of externally applying a voltage to a charging member thereby charging an electrostatic latent image bearing member, a step of forming an electrostatic latent image on the charged electrostatic latent image bearing member, a development step of developing the electrostatic latent image with electrostatic latent image developing toner thereby forming a toner image on the electrostatic latent image bearing member, a first transfer step of transferring the toner image on the electrostatic latent image bearing member onto an intermediate transfer member, a second transfer step of transferring the toner image on the intermediate transfer member onto a recording material, and a fixation step of heat fixing the toner image on the recording material;the method comprising the use of electrostatic latent image developing toner comprising at least a binder resin, a coloring agent, and a charge control agent according to claim 21. 28. An image forming apparatus comprising formation of an image on a recording material with electrostatic latent image developing toner according to claim 25.29. An image forming apparatus at least comprising means for externally applying a voltage to a charging member thereby charging an electrostatic latent image bearing member, means for forming an electrostatic latent image on the charged electrostatic latent image bearing member, development means for developing the electrostatic latent image with electrostatic latent image developing toner thereby forming a toner image on the electrostatic latent image bearing member, transfer means for transferring the toner image on the electrostatic latent image bearing member onto a recording material, and fixation means for heat fixing the toner image on the recording material;the apparatus comprising the use of electrostatic latent image developing toner according to claim 25. 30. An image forming apparatus according to claim 29, comprising at least means for externally applying a voltage to a charging member thereby charging an electrostatic latent image bearing member, means for forming an electrostatic latent image on the charged electrostatic latent image bearing member, development means for developing the electrostatic latent image with electrostatic latent image developing toner thereby forming a toner image on the electrostatic latent image bearing member, first transfer means for transferring the toner image on the electrostatic latent image bearing member onto an intermediate transfer member, second transfer means for transferring the toner image on the intermediate transfer member onto a recording material, and fixation means for heat fixing the toner image on the recording material;the apparatus comprising the use of electrostatic latent image developing toner.