초록 ▼

This invention relates to rapid drying lacquers that are particularly useful for automotive OEM refinish applications. The lacquer includes a novel highly branched copolyester polyol. This invention is also directed to a process for producing coatings from the rapid drying lacquers. These lacquers a

This invention relates to rapid drying lacquers that are particularly useful for automotive OEM refinish applications. The lacquer includes a novel highly branched copolyester polyol. This invention is also directed to a process for producing coatings from the rapid drying lacquers. These lacquers are especially useful in providing for chip and humidity resistant coatings having improved adhesion.

대표청구항 ▼

1. A lacquer comprising a highly branched copolyester polyol having a number average molecular weight ranging from 1000 to 30,000, hydroxyl groups ranging from 5 to 200 per polymer chain and carboxyl groups ranging from 0 to 40 per polymer chain, said copolyester polyol being polymerized from a mono

1. A lacquer comprising a highly branched copolyester polyol having a number average molecular weight ranging from 1000 to 30,000, hydroxyl groups ranging from 5 to 200 per polymer chain and carboxyl groups ranging from 0 to 40 per polymer chain, said copolyester polyol being polymerized from a monomer mixture containing a chain extender selected from the group consisting of a hydroxy carboxylic acid, a lactone of a hydroxy carboxylic acid and a combination thereof; and one or more hyper branching monomers, said hyper branching monomer having one carboxyl group and two hydroxyl groups, two carboxyl groups and one hydroxyl group, one carboxyl group and three hydroxyl groups, or three carboxyl groups and one hydroxyl group, and wherein the weight ratio of the hyper branching monomer to the chain extender in said monomer mixture ranges from 1/0.3 to 1/20.2. The lacquer of claim 1 wherein said monomer mixture further comprises a molecular weight controlling agent having in the range of 1 to 6 functionalities selected from the group consisting of hydroxyl, amine, epoxide, carboxyl and a combination thereof.3. The lacquer of claim 1 wherein when said monomer mixture contains hyper branching monomer having two carboxyl groups and one hydroxyl group or three carboxyl groups and one hydroxyl group, said highly branched copolyester polyol is further reacted with monoepoxy or diol to provide said highly branched copolyester polyol with said range of hydroxyl groups.4. The lacquer of claim 1 wherein said hyper branching monomer is dialkylol propionic acid and said lactone is caprolactone.5. The lacquer of claim 2 wherein said hyper branching monomer is dialkylol propionic acid, said lactone is caprolactone and said molecular weight controlling agent is pentaerythritol or trimethylol propane.6. The lacquer of claim 2 wherein said hyper branching monomer is dimethylol propionic acid, said lactone is caprolactone and said molecular weight controlling agent is pentaerythritol.7. The lacquer of claim 1 or 2 wherein said lacquer comprises an acrylic polymer, polyester, alkyd resin, acrylic alkyd resin, cellulose acetate butyrate, an iminated acrylic polymer, ethylene-vinyl acetate co-polymer, nitrocellulose, plasticizer or a combination thereof.8. The lacquer of claim 1 or 2 wherein said lacquer further comprises metallic driers, chelating agents, or a combination thereof.9. The lacquer of claim 1 or 2 comprising in the range 2 weight percent to 100 weight percent of said highly branched copolyester polyol.10. The lacquer of claim 1 or 2 comprising in the range 5 weight percent to 50 weight percent of said highly branched copolyester polyol.11. The lacquer of claim 1 or 2 comprising a pigment, flake or a combination thereof.12. The lacquer of claim 1 wherein said highly branched copolyester polyol is produced by polymerizing said chain extender and highly branched monomers in one step.13. The lacquer of claim 2 wherein said highly branched copolyester polyol is produced by polymerizing said chain extender, molecular weight controlling agent and highly branched monomers in one step.14. The lacquer of claim 1 wherein said highly branched copolyester polyol is produced in stages by first polymerizing said highly branched monomers followed by polymerizing said chain extender.15. The lacquer of claim 2 wherein said highly branched copolyester polyol is produced in stages by first polymerizing said molecular weight controlling agent and said highly branched monomers followed by polymerizing said chain extender.16. The lacquer of claim 1 wherein said highly branched copolyester polyol is produced in stages by first polymerizing said highly branched monomers and a portion of said chain extender followed by polymerizing the remainder of said chain extender.17. The lacquer of claim 2 wherein said highly branched copolyester polyol is produced in stages by first polymerizing said molecular weight controlling agent and said highly branched monomers and a portion of said chain extender followed by polymerizing the remainder of said chain extender.18. The lacquer of claim 2 wherein said highly branched copolyester polyol is produced in stages by first polymerizing said molecular weight controlling agent and a portion of said highly branched monomers and a portion of said chain extender followed by polymerizing the remainder of said highly branched monomers and chain extender.19. The lacquer of claim 2 wherein said highly branched copolyester polyol is produced in stages by first polymerizing portions of said molecular weight controlling agent, highly branched monomers and said chain extender followed by polymerizing the remainder of said molecular weight controlling agent, highly branched monomers and chain extender.20. A lacquer comprising a highly branched copolyester polyol polymerized from a monomer mixture comprising:one or more hyper branching monomers having the structural formula: (R2O)n?R4?[C(CO)O R3]m; and a chain extender selected from the group consisting of a hydroxy carboxylic acid, an ester of a hydroxy carboxylic acid and a combination thereof, said hydroxy carboxylic acid having the structural formula: R5O?R6?C(O)O R7, wherein:R2 and R5 are H or (O)C R8, R3 and R7 are H, C1-12 hydrocarbyl radical or hydroxyl substituted C1-12 hydrocarbyl radical, R4 is C1-12 hydrocarbyl radical having m+n free valencies, R6 is C1-12 hydrocarbyl radical with two free valencies, R8 is H or C1-200 hydrocarbyl radical and n+m ranges from 3 to 6, and provided n or m is 1. 21. The lacquer of claim 20 wherein said monomer mixture further comprises a molecular weight controlling agent having the formula:R1-Zk, wherein:R1 is C1-200 hydrocarbyl radical with free valencies ranging from 1 to 6, Z is a hydroxyl, carboxyl, amine or epoxy group, and k ranges from 1 to 6. 22. A lacquer comprising a highly branched copolyester polyol having a number average molecular weight ranging from 1000 to 30,000, hydroxyl groups ranging from 5 to 200 per polymer chain and carboxyl groups ranging from 0 to 40 per polymer chain, said copolyester polyol being polymerized from a monomer mixture containing a chain extender selected from the group consisting of a hydroxy carboxylic acid, a lactone of a hydroxy carboxylic acid and a combination thereof; one or more hyper branching monomers, said hyper branching monomer having one carboxyl group and two hydroxyl groups, two carboxyl groups and one hydroxyl group, one carboxyl group and three hydroxyl groups, or three carboxyl groups and one hydroxyl group; and a molecular weight controlling agent having in the range of 1 to 6 functionalities selected from the group consisting of hydroxyl, amine, epoxide, carboxyl and a combination thereof; wherein the weight ratio of the hyper branching monomer to the chain extender in said monomer mixture ranges from 1/0.3 to 1/20.23. A lacquer comprising a highly branched copolyester polyol polymerized from a monomer mixture comprising:(a) a molecular weight controlling agent having the formula: R1-Zk, wherein:R1 is C1-200 hydrocarbyl radical with free valencies ranging from 1 to 6, Z is a hydroxyl, carboxyl, amine or epoxy group, and k ranges from 1 to 6; (b) one or more hyper branching monomers having the structural formula: (R2O)n?R4?[C(CO)O R3]m; and (c) a chain extender selected from the group consisting of a hydroxy carboxylic acid, an ester of a hydroxy carboxylic acid and a combination thereof, said hydroxy carboxylic acid having the structural formula: R5O?R6?C(O)O R7, wherein:R2 and R5 are H or (O)C R8, R3 and R7 are H, C1-12 hydrocarbyl radical or hydroxyl substituted C1-12 hydrocarbyl radical, R4 is C1-12 hydrocarbyl radical having m+n free valencies, R6 is C1-12 hydrocarbyl radical with two free valencies, R8 is H or C1-200 hydrocarbyl radical and n m ranges from 3 to 6, and provided n or m is 1.