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A method for processing polycrystalline silicon workpieces to form size distributions of polycrystalline silicon pieces suitable for use in a Czochralski-type process includes: (1) preparing a polycrystalline silicon workpiece by a chemical vapor deposition process; (2) fracturing the polycrystallin

A method for processing polycrystalline silicon workpieces to form size distributions of polycrystalline silicon pieces suitable for use in a Czochralski-type process includes: (1) preparing a polycrystalline silicon workpiece by a chemical vapor deposition process; (2) fracturing the polycrystalline silicon workpiece into a mixture of polycrystalline silicon pieces, where the polycrystalline silicon pieces have varying sizes; and (3) sorting the mixture of polycrystalline silicon pieces into at least two size distributions. Step (2) may be carried out by a thermal shock process. Step (3) may be carried out using a rotary indent classifier. A rotary indent classifier for performing the method includes: (i) a rotating cylinder having a circumferential edge with indents arrayed in increasing size from a first end of the cylinder to a second end of the cylinder, and (ii) a conveyor running longitudinally adjacent the cylinder, for conveying silicon pieces from the first end of the cylinder to the second end of the cylinder.

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1. A method comprising:feeding a mixture of silicon piece to a rotary indent classifier comprising a rotating disk having a circumferential edge with one or more indents sized to capture silicon pieces of a predetermined size or smaller and to reject silicon pieces of a size larger than the predeter

1. A method comprising:feeding a mixture of silicon piece to a rotary indent classifier comprising a rotating disk having a circumferential edge with one or more indents sized to capture silicon pieces of a predetermined size or smaller and to reject silicon pieces of a size larger than the predetermined size, thereby separating the mixture of silicon pieces into at least two size distributions. 2. The method of claim 1, where the rotary indent classifier comprises more than one rotating disk, and where each rotating disk has one or more indents.3. The method of claim 2, where the rotating disks are arrayed such that the first rotating disk has the smallest sized indents and the last rotating disk has the largest sized indents.4. The method of claim 1, where more than one rotary indent classifier is used in series, and where each rotating disk has indents of different sizes.5. A method comprising:(A) feeding a mixture of silicon pieces to a rotary indent classifier, where the rotary indent classifier comprises a rotating cylinder having a circumferential edge with indents arrayed in increasing size from a first end of the cylinder to a second end of the cylinder, where the silicon pieces have varying sizes, where the indents are sized to capture silicon pieces of a predetermined size or smaller and to reject silicon pieces of a size larger than the predetermined size, where the mixture of silicon pieces is fed to the first end of the cylinder, and (B) conveying the mixture of silicon pieces along the length of the cylinder, thereby effecting separation of the mixture into a plurality of size distributions. 6. The method of claim 5, where step (A) is carried out using a conveyor selected from a vibratory conveyor, a bucket conveyor, a belt conveyor, or a hopper.7. The method of claim 5, where step (B) is carried out using a conveyor selected from a vibratory conveyor, a bucket conveyor, a belt conveyor, or a hopper.8. The method of claim 5, where each indent has a shape selected from cubic, cylindrical, half-cylindrical, ellipsoidal, half-ellipsoidal, or wedge.9. A method comprising:(1) fracturing a polycrystalline silicon workpiece into a mixture of polycrystalline silicon pieces, where the polycrystalline silicon pieces have varying sizes; and (2) sorting the mixture of polycrystalline silicon pieces into at least two size distributions using a rotary indent classifier. 10. The method of claim 9, where step (1) is carried out by the steps of:(i) heating the polycrystalline silicon workpiece to a temperature of 600 to 1400° F., (ii) spraying the product of step (i) with a fluid from a nozzle, and (iii) extending cracks in the product of step (ii) with a separator. 11. The method of claim 10, where step (i) is carried out with laser, infra-red, or microwave energy.12. The method of claim 10, where the fluid used step (ii) is selected from purified water, a solution of HF in water, or a solution of ammonium hydroxide in water.13. The method of claim 10, where the separator used in step (iii) is selected from a mechanical, sonic, or vibrational separator.14. The method of claim 9, further comprising (3) a washing step comprising washing the silicon either before or after fracturing in step (1), either before or after sorting into size distributions in step (2), or combinations thereof.15. The method of claim 9, where the rotary indent classifier comprises a rotating disk having a circumferential edge with one or more indents sized to capture polycrystalline silicon pieces of a predetermined size or smaller and to reject polycrystalline silicon pieces of a size larger than the predetermined size.16. The method of claim 9, where the rotary indent classifier comprises a rotating cylinder having a circumferential edge with indents arrayed in increasing size from a first end of the cylinder to a second end of the cylinder, where the indents are sized to capture silicon pieces of a predetermined size or smaller and to reject silicon pieces of a size larger than the predetermined size.17. The method of claim 16, where the mixture of polycrystalline silicon pieces is fed to the first end of the cylinder and conveyed along the length of the cylinder, thereby effecting separation of the mixture into a plurality of size distributions.18. A method comprising:(1) fracturing a polycrystalline silicon workpiece into a mixture of polycrystalline silicon pieces, where the polycrystalline silicon pieces have varying sizes; and (2) separating the mixture of polycrystalline silicon pieces into at least two size distributions; wherein step (1) is carried out by a process comprising: (i) heating the polycrystalline silicon workpiece to a temperature of 600 to 1400° F., (ii) spraying the product of step (i) with a fluid from a plurality of nozzles, and (iii) extending cracks in the product of step (ii) with a separator. 19. The method of claim 18, where step (i) is carried out with laser, infra-red, or microwave energy.20. The method of claim 18, where the polycrystalline silicon workpiece is heated to a temperature of 600 to 750° F.21. The method of claim 18, where the fluid used step (ii) is selected from purified water, solutions of HF in water, or ammonium hydroxide in water.22. The method of claim 18, where the nozzles are oriented to produce irregular shaped polycrystalline silicon pieces.23. The method of claim 18, where the nozzles are oriented to produce wedge or pie shaped pieces.24. The method of claim 18, where a type of nozzle is selected to produce a cone spray pattern.25. The method of claim 18, where a type of nozzle is selected to produce a flat fan spray pattern.26. The method of claim 18, where the separator used in step (iii) is selected from a mechanical, sonic, or vibrational separator.27. The method of claim 18, where step (2) is carried out using a rotary indent classifier.28. The method of claim 18, further comprising (3) a washing step comprising washing the silicon either before or after fracturing in step (1), either before or after sorting into mixtures with different size distributions in step (2), or combinations thereof.29. The method of claim 18 where the mixture of polycrystalline silicon pieces is sorted into more than two size distribution and further comprising (3) mixing two or more of the size distributions to form a new size distribution to meet customer requirements.30. A method comprising:(1) preparing a polycrystalline silicon workpiece by a chemical vapor deposition process, (2) fracturing the product of step (1) into a mixture of polycrystalline silicon pieces of varying sizes, and (3) sorting the product of step (2) into at least two size distributions; with the proviso that (A) step (2) is carried out by a process comprising (i) heating the product of step (1) to a temperature of 600 to 1400° F., (ii) spraying the product of step (i) with a fluid from a plurality of nozzles, and (iii) extending cracks in the product of step (ii) with a separator; or (B) step (3) is carried out by using a rotary indent classifier; or (C) both (A) and (B). 31. A method comprising:(1) preparing a polycrystalline silicon workpiece by a fluidized bed reactor process, (2) sorting the product of step (1) into at least two size distributions using a rotary indent classifier.