초록 ▼

An improved system for treating the aftertreatment of exhaust gases, especially from diesel engines, comprises a first catalyst (20) effective to oxidise hydrocarbons, a second catalyst (22) effective to convert NO to NO2, a trap (24) for particulates, on which particulates may combust with the NO2,

An improved system for treating the aftertreatment of exhaust gases, especially from diesel engines, comprises a first catalyst (20) effective to oxidise hydrocarbons, a second catalyst (22) effective to convert NO to NO2, a trap (24) for particulates, on which particulates may combust with the NO2, and optionally a NOx absorption material (26).

대표청구항 ▼

1. A process of treating internal combustion engine exhaust gas containing O2, NOx, unburnt hydrocarbon (“HC”), CO and soot, comprising the steps of:i. contacting the engine exhaust gas with a first catalyst adapted to be fed with the engine exhaust gas and effective to promote oxidation of HC, to o

1. A process of treating internal combustion engine exhaust gas containing O2, NOx, unburnt hydrocarbon (“HC”), CO and soot, comprising the steps of:i. contacting the engine exhaust gas with a first catalyst adapted to be fed with the engine exhaust gas and effective to promote oxidation of HC, to oxidize a substantial part of the HC; ii. contacting the engine exhaust gas that has passed over the first catalyst with a second catalyst effective to promote the catalytic oxidation of NO to NO2, to oxidize NO to NO2; iii. collecting soot on a filter adapted to be fed with the engine exhaust gas that has passed over the first and second catalysts; and iv. combusting the collected soot by reaction with the catalytically oxidized NO2 and O2. 2. A process according to claim 1, wherein the first and second catalysts are honeycomb-supported.3. A process according to claim 2, wherein the honeycomb defines cells having a cell density in the range of 100-900 per square inch.4. A process according to claim 1, further comprising the step of cooling the engine exhaust gas leaving the first catalyst and before the engine exhaust gas contacts the second catalyst.5. A process according to claim 1, wherein the step of contacting the exhaust gas with a first catalyst to oxidize a substantial part of the HC is carried out close to the source of the engine exhaust gas, whereby a maximum convenient operating temperature and reaction rate is obtained.6. A process according to claim 4, further comprising the step of providing an increased amount of a combustible upstream of the first catalyst to increase the temperature at which step i operates.7. A process according to claim 6, wherein the combustible is provided by modifying engine settings to pass more HC and/or generate more CO.8. A process according to claim 1, wherein the first catalyst has a very low light-off temperature for HC and CO oxidation.9. A process according to claim 1, wherein the HC is absorbed on the soot.10. A process according to claim 1, further comprising the step of removing NOx downstream of the step of combusting the collected soot.11. A process according to claim 10, wherein the step of removing NOx is through a regenerable NOx absorber.12. A process according to claim 11, further comprising the step of catalytically removing NOx downstream from the NOx absorber.13. A system for treating internal combustion engine exhaust gas containing O2 NOx, unburnt hydrocarbon (“HC”), CO, and soot, comprising:i. a first catalyst adapted to receive the engine exhaust gas and effective to promote oxidation of HC therein for oxidizing a substantial part of the HC; ii. a second catalyst adapted to receive the engine exhaust gases that have passed over the first catalyst and disposed downstream of the first catalyst, the second catalyst effective to promote oxidation of NO to NO2; and iii. a filter adapted to receive the engine exhaust gases that have passed over the first and second catalysts, the filter effective to collect and retain soot for combustion by reaction with the NO2 and the O2. 14. The system according to claim 13, wherein the first and second catalysts are honeycomb-supported.15. The system according to claim 14, wherein the honeycomb defines cells having a density in the range of 100-900 per square inch.16. The system according to claim 13, wherein the internal combustion engine is a diesel engine.17. The system according to claim 16, wherein the diesel engine is designed for light duty applications.18. The system according to claim 17, wherein the diesel engine is a turbo-charged direct injection type.19. The system according to claim 16, wherein the diesel engine is a heavy duty engine.20. The system according to claim 13, wherein the first catalyst is positioned close to the second catalyst.21. The system according to claim 13, wherein the first catalyst and the second catalyst are at opposite ends of a single catalyst monolith.22. A process according to claim 1, wherein the step of oxidizing a substantial part of the HC over a first catalyst further comprises oxidizing some NO to NO2.23. A process according to claim 1, wherein the first catalyst comprises at least one supported platinum group metal (PGM).24. A process according to claim 23, wherein the at least one supported PGM is selected from the group consisting of platinum, palladium and rhodium.25. A process according to claim 24, wherein the at least one PGM is platinum and palladium.26. A process according to claim 24, wherein the support is selected from the group consisting of alumina, ceria and alumina and ceria.27. A process according to claim 25, wherein the support is selected from the group consisting of alumina, ceria and alumina and ceria.28. A process according to claim 1, wherein the first catalyst comprises a first layer comprising platinum-catalyzed alumina and a second layer comprising ceria overlying the first layer.29. A process according to claim 23, wherein the at least one supported PGM comprises from 10-150 g/ft3 platinum.30. A process according to claim 1, wherein the second catalyst comprises at least one supported platinum group metal (PGM).31. A process according to claim 30, wherein the at least one supported PGM is selected from the group consisting of platinum, palladium and rhodium.32. A process according to claim 31, wherein the at least one PGM is platinum.33. A process according to claim 30, wherein the support is alumina.34. A process according to claim 32, wherein the at least one PGM comprises from 10-150 g/ft3 platinum.35. The system according to claim 13, wherein the first catalyst comprises at least one supported platinum group metal (PGM).36. The system according to claim 35, wherein the at least one supported PGM is selected from the group consisting of platinum, palladium and rhodium.37. The system according to claim 36, wherein the at least one PGM is platinum and palladium.38. The system according to claim 36, wherein the support is selected from the group consisting of alumina, ceria and alumina and ceria.39. The system according to claim 37, wherein the support is selected from the group consisting of alumina, ceria and alumina and ceria.40. The system according to claim 36, comprising a first layer comprising platinum-catalyzed alumina and a second layer comprising ceria overlying the first layer.41. The system according to claim 36, comprising from 10-150 g/ft3 platinum.42. The system according to claim 13, wherein the second catalyst comprises at least one supported platinum group metal (PGM).43. The system according to claim 42, wherein the at least one supported PGM is selected from the group consisting of platinum, palladium and rhodium.44. The system according to claim 43, wherein the at least one PGM is platinum.45. The system according to claim 42, wherein the support is alumina.46. The system according to claim 44 comprising from 10-150 g/ft3 platinum.