IPC분류정보
| 국가/구분 |
United States(US) Patent
등록
|
| 국제특허분류(IPC7판) |
|
| 출원번호 |
US-0481772
(2002-06-10)
|
| 우선권정보 |
JP-0195080 (2001-06-27) |
| 국제출원번호 |
PCT//JP02/05713
(2003-12-23)
|
| §371/§102 date |
20031223
(20031223)
|
| 국제공개번호 |
WO03//00262
(2003-01-09)
|
|
발명자
/ 주소 |
- Hanazawa, Makoto
- Itami, Yasuo
|
| 출원인 / 주소 |
|
| 대리인 / 주소 |
|
| 인용정보 |
피인용 횟수 :
35 인용 특허 :
0 |
초록
▼
A perfluoropolyether-containing composition, which can easily conform to a fluorine-free substrate and can form a film on a surface of the substrate to fix the composition to the substrate surface, wherein the composition is a carbon-carbon double bond-containing composition comprising (A) a triisoc
A perfluoropolyether-containing composition, which can easily conform to a fluorine-free substrate and can form a film on a surface of the substrate to fix the composition to the substrate surface, wherein the composition is a carbon-carbon double bond-containing composition comprising (A) a triisocyanate prepared by trimerizing a diisocyanate, and (B) a combination of at least two active hydrogen-containing compounds, and the component (B) comprises (B-1) a perfluoropolyether having at least one active hydrogen, and (B-2) a monomer having active hydrogen and a carbon-carbon double bond.
대표청구항
▼
1. A composition containing a carbon-carbon double bond, which comprises:(A) a triisocyanate prepared by trimerizing a diisocyanate, and (B) active hydrogen-containing compounds wherein the component (B) is a combination of at least two active hydrogen-containing compounds, and essentially consists
1. A composition containing a carbon-carbon double bond, which comprises:(A) a triisocyanate prepared by trimerizing a diisocyanate, and (B) active hydrogen-containing compounds wherein the component (B) is a combination of at least two active hydrogen-containing compounds, and essentially consists of: (B-1) a perfluoropolyether having at least one active hydrogen, and (B-2) a monomer having active hydrogen and a carbon-carbon double bond. 2. The composition according to claim 1, wherein the perfluoropolyether (B-1) has a compound which has one hydroxyl group at one molecular end, or one hydroxyl group at each of both molecular ends.3. The composition according to claim 1, wherein the perfluoropolyether (B-1) is of the general formula: wherein X is a fluorine atom or a ?CH2OH group, Y and Z are a fluorine atom or a trifluoromethyl group, a is an integer of 1 to 16, c is an integer of 0 to 5, b, d, e, f and g are an integer of 0 to 200, and h is an integer of 0 to 16. 4. The composition according to claim 1, wherein the component (B-1) is reacted with the NCO group present in the triisocyanate (A), and remaining NCO group is reacted with the component (B-2).5. The composition according to claim 4, wherein the total amount of the active hydrogen possessed by the component (B-1) and the active hydrogen possessed by the component (B-2) is 3 mol, relative to 1 mol of the triisocyanate (A), and the molar ratio of active hydrogen of the monomer (B-1)/active hydrogen of the PFPE (B-2) is at most 1/2.6. A composition containing a carbon-carbon double bond, which comprises:(A) a triisocyanate prepared by trimerizing a diisocyanate, and (B) active hydrogen-containing compounds wherein the component (B) is a combination of at least two active hydrogen-containing compounds, and essentially consists of: (B-1) a perfluoropolyether having at least one active hydrogen, (B-2) a monomer having active hydrogen and a carbon-carbon double bond and (B-3) a compound having active hydrogen, and the compound (B-3) is selected from the group consisting of a monohydric alcohol comprising a linear or branched hydrocarbon having 1 to 16 carbon atoms, a secondary amine comprising a linear or branched hydrocarbon having 1 to 16 carbon atoms, a secondary amine containing an aromatic group, an Rf alcohol; Q(CF2)l(CH?CH)m(CHI)n(CH2)oOH (wherein Q is a hydrogen atom, a fluorine atom or a (CF3)2CF? group, l is an integer of 1 to 10, m and n is an integer of 0 to 1, and o is an integer of 1 to 10), R(OCH2CH2CH2)qOH (R is a linear or branched hydrocarbon, an acetyl group, or an alkylphenoxy group having 1 to 16 carbon atoms, and p and q are an integer of 1 to 20), an aromatic alcohol, a silane compound having active hydrogen, (CH3)3Si(CH2)sOH (wherein s is an integer of 1 to 20), [(CH3)3]2NH, 7. The composition according to claim 6, wherein the component (B-1) is reacted with the NCO group present in the triisocyanate (A), and the remaining NCO group is reacted with the component (B-2) and the component (B-3).8. The composition according to claim 7, wherein the total amount of the active hydrogen possessed by the component (B-1), the active hydrogen possessed by the component (B-2) and the active hydrogen possessed by the component (B-3) is 3 mol, relative to 1 mol of the triisocyanate (A).9. A polymer containing perfluoropolyether which is prepared by polymerizing the carbon-carbon double bond-containing composition according to claim 1.10. A polymer containing perfluoropolyether prepared by polymerizing the carbon-carbon double bond-containing composition according to claim 1 and a monomer having a carbon-carbon double bond.11. An article which is coated with the polymer according to claim 9.12. A coating liquid comprising the carbon-carbon double bond-containing composition according to claim 1.13. A coating liquid comprising:(1) the carbon-carbon double bond-containing composition according to claim 1, and (2) a fluoroalcohol, a fluoroether or ditrifluoromethylbenzene. 14. An article having a perfluoropolyether film on a surface of the article, which is prepared by coating the coating liquid according to claim 11 on the surface of the article, and then polymerizing the coating liquid.15. An optical material surface-coated with a film formed so that the content of perfluoropolyether in the carbon-carbon double bond-containing composition according to claim 1 is from 0.01% by weight to 10% by weight based on the film.16. A method of purifying a compound having a carbon-carbon double bond and a perfluoropolyether group, which comprises:precipitating the composition according to claim 1 with a nonpolar solvent, separating a high-boiling point reaction solvent from the precipitate, adding acetone and a polymerization inhibitor to the precipitate, and then removing a solution of the compound containing the carbon-carbon double bond and perfluoropolyether group from a reactor. 17. A polymer containing perfluoropolyether which is prepared by polymerizing the carbon-carbon double bond-containing composition according to claim 6.18. A polymer containing perfluoropolyether prepared by polymerizing the carbon-carbon double bond-containing composition according to claim 6 and a monomer having a carbon-carbon double bond.19. A coating liquid comprising the carbon-carbon double bond-containing composition according to claim 6.20. A coating liquid comprising:(1) the carbon-carbon double bond-containing composition according to claim 6, and (2) a fluoroalcohol, a fluoroether or ditrifluoromethylbenzene. 21. A coating liquid comprising:(1) the polymer according to claim 9, and (2) a fluoroalcohol, a fluoroether or ditrifluoromethylbenzene. 22. A coating liquid comprising:(1) the polymer according to claim 10, and (2) a fluoroalcohol, a fluoroether or ditrifluoromethylbenzene. 23. An optical material surface-coated with a film formed so that the content of perfluoropolyether in the carbon-carbon double bond-containing composition according to claim 6 is from 0.01% by weight to 10% by weight based on the film.24. An optical material surface-coated with a film formed so that the content of perfluoropolyether in the polymer according to claim 9 is from 0.01% by weight to 10% by weight based on the film.25. An optical material surface-coated with a film formed so that the content of perfluoropolyether in the polymer according to claim 10 is from 0.01% by weight to 10% by weight based on the film.
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