초록 ▼

The vessel assembly includes a polymeric cylinder and a circular polymeric cap for the cylinder, the cylinder being closed at one end and open at the other end to receive the cap. The open end of the cylinder has a lip that is beveled inwardly from the open end, and the circular polymeric cap has a

The vessel assembly includes a polymeric cylinder and a circular polymeric cap for the cylinder, the cylinder being closed at one end and open at the other end to receive the cap. The open end of the cylinder has a lip that is beveled inwardly from the open end, and the circular polymeric cap has a beveled lower edge that engages the beveled lip when the cap is place upon the polymeric cylinder. For high pressure applications, a choke cylinder depends from the beveled lower edge of the cap, and has an outer diameter substantially the same as the inner diameter of the polymeric cylinder so that the choke provides a self sealing mechanism for the cylinder as pressure from a chemical reaction increases within the cylinder. A composite sleeve surrounds the polymeric cylinder, and includes at least one wound fabric layer in which the winding can be a filament or a yarn.

대표청구항 ▼

1. A self scaling vessel assembly for high pressure microwave assisted chemistry, said vessel assembly comprising:a polymeric cylinder and a circular polymeric cap for said cylinder;said cylinder being closed at one end and open at the other end to receive said cap;said open end of said cylinder com

1. A self scaling vessel assembly for high pressure microwave assisted chemistry, said vessel assembly comprising:a polymeric cylinder and a circular polymeric cap for said cylinder;said cylinder being closed at one end and open at the other end to receive said cap;said open end of said cylinder comprising a lip that is beveled inwardly from said open end;said circular polymeric cap having a beveled lower edge that engages said beveled lip when said cap is place upon said polymeric cylinder;a composite sleeve surrounding said polymeric cylinder, said composite sleeve being formed of a microwave transparent inner cylindrical tetrafluoroethylene polymeric layer, a first microwave transparent wound layer adjacent to and concentric with said inner polymeric layer in which said winding is selected from the group consisting of filaments and yarns, a structural polymer layer on said wound layer, and a microwave transparent outer tetrafluoroethylene polymeric layer on said structural polymer layer;a supporting frame that extends along said cylinder and across said lid and across said closed end of said cylinder for preventing said lid from being displaced from said cylinder when pressure is generated inside of said vessel; anda choke cylinder depending from said beveled lower edge of said cap, said choke cylinder having an outer diameter substantially the same as the inner diameter of said polymeric cylinder so that said choke provides a self sealing mechanism for said cylinder as pressure from a chemical reaction increases within said cylinder.2. A vessel assembly according to claim 1 wherein said frame comprises:a threaded opening in said frame adjacent said cap; anda bolt in said threaded opening that bears on said cap when tightened in said threaded opening.3. A vessel assembly according to claim 1 wherein said cap and said cylinder both comprise fluorinated hydrocarbons.4. A composite sleeve according to claim 1 comprising a plurality of pairs of adjacent concentric layers of structural polymer and textiles between said first wound layer and said outer polymeric layer.5. A composite sleeve according to claim 4 wherein said textile layers in said pairs are selected from the group consisting of woven fabrics, braided fabrics, nonwoven fabrics, and knitted fabrics.6. A composite sleeve according to claim 4 wherein said textile layers in said pairs comprise a winding selected from the group consisting of filaments and yarns.7. A vessel assembly according to claim 1 wherein said supporting frame is flexible under a predetermined force exerted by pressure inside said cylinder and against said cap, so that the flexing of said frame at said pressure allows said cap to disengage from said cylinder and release the pressure inside.8. A system for microwave assisted chemistry comprising:a source of microwave radiation;a cavity in microwave communication with said source; anda plurality of vessels according to claim 1 in said cavity.9. A system according to claim 8 wherein said source is selected from the group consisting of magnetrons, klystrons, solid state devices, and switching power supplies.10. A system according to claim 8 and further comprising a waveguide between said source and said cavity.