Method of storing, uptaking, releasing of gases by novel framework materials
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
H01M-008/04
F17C-011/00
B01D-053/02
출원번호
US-0061147
(2002-02-01)
§371/§102 date
20030619
(20030619)
발명자
/ 주소
M?ller, Ulrich
Harth, Klaus
H?lzle, Markus
Hesse, Michael
Lobree, Lisa
Harder, Wolfgang
Yaghi, Omar M.
Eddaoudi, Mohamed
출원인 / 주소
BASF Aktiengesellschaft
The Regents of the University of Michigan
대리인 / 주소
Oblon, Spivak, McClelland, Maier &
인용정보
피인용 횟수 :
61인용 특허 :
5
초록▼
The present invention relates to the technical field of storing gas including methane and hydrogen, in particular to the fuel cell technology. In particulars it relates to a method of using a metallo-organic framework material comprising pores and at least one metal ion and at least one at least bid
The present invention relates to the technical field of storing gas including methane and hydrogen, in particular to the fuel cell technology. In particulars it relates to a method of using a metallo-organic framework material comprising pores and at least one metal ion and at least one at least bidentate organic compound.
대표청구항▼
1. Method of uptaking, or storing, or releasing, or uptaking and storing, or uptaking and releasing, or storing and releasing or uptaking, storing and releasing at least one gas wherein the gas is uptaken, or stored, or released, or uptaken and stored, or uptaken and released, or stored and released
1. Method of uptaking, or storing, or releasing, or uptaking and storing, or uptaking and releasing, or storing and releasing or uptaking, storing and releasing at least one gas wherein the gas is uptaken, or stored, or released, or uptaken and stored, or uptaken and released, or stored and released or uptaken, stored and released by an agent comprising a metallo-organic framework material comprising pores and at least one metal ion and at least one at least bidentate organic compound, which is bound to said metal ion;wherein the metallo organic framework material comprising pores exhibits a specific surface area, as determined via adsorption (BET according to DIN 66131) of larger than 2000 m2/g. 2. Method according to claim 1, wherein the gas comprises at least one of the gases among the group consisting of hydrogen, nitrogen, a noble gas, CO, CO2, and compounds generating and/or delivering these gases.3. Method according to claim 2, wherein the gas is selected from the group consisting of hydrogen, a gas mixture comprising hydrogen, a hydrogen generating or delivering substance, a gas mixture comprising at least one hydrogen generating and/or delivering substance, and combinations thereof.4. Method according to claim 1, wherein the metal ion is selected among ions of elements of groups Ia, IIa, IIIa, IVa to VIIIa and Ib to VIb of the periodic table of the elements.5. Method according to claim 1, further comprising contacting the metallo-organic framework material with at least one capacity-enhancing agent selected from the group consisting of a solvent, a complex, a metal, a metal hydride, a metal alloy, and mixtures of two or more thereof.6. Method according to claim 1, wherein the bidentate organic compound is selected among substituted or unsubstituted aromatic polycarboxylic acids, which may comprise one or more nuclei; and substituted or unsubstituted aromatic polycarboxylic acids, which comprise at least one hetero-atom and which may have one or more nuclei.7. Device for uptaking, or storing, or releasing, or uptaking and storing, or uptaking and releasing, or storing and releasing, or uptaking, storing and releasing at least one gas, comprising a metallo-organic framework material, as claimed in claim 1.8. Device according to claim 7, further comprising a container comprising the metallo-organic framework material; an entrance/exit opening for allowing the at least one gas to enter or exit the device; a gas-tight maintaining mechanism capable of maintaining the gas under pressure inside the container.9. Fuel cell comprising the agent according to claim 1.10. Method of using an agent comprising a metallo-organic framework material comprising pores and at least one metal ion and at least one at least bidentate organic compound, which is bound to said metal ions;wherein said using comprises uptaking, or storing, or releasing, or uptaking and storing, or uptaking and releasing, or storing and releasing or uptaking, storing and releasing at least one gas in at least one of a stationary application, a mobile application, or a mobile portable application; and wherein the metallo organic framework material comprising pores exhibits a specific surface area, as determined via adsorption (BET according to DIN 66131) of larger than 2000 m2/g. 11. Method of using according to claim 10, wherein at least one application is selected from the group consisting of a power plant, a car, a truck, a bus, a cell phone, a laptop, and combinations thereof.12. Method of using a device according to claim 7, wherein said using comprises:supplying power to an application selected from the group consisting of a power plant, a car, a truck, a bus, a cell phone, a laptop, and combinations thereof. 13. Method of using the fuel cell according to claim 9, wherein said using comprises:supplying power to an application selected from the group consisting of a power plant, a car, a truck, a bus, a cell phone, a laptop, and combinations thereof. 14. The method according to claim 1, wherein at least one at least bidentate organic compound is coordinately bound to said metal ion.15. The method of using according to claim 10,wherein at least one at least bidentate organic compound is coordinately bound to said metal ion.
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이 특허에 인용된 특허 (5)
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Muller, Ulrich; Lobree, Lisa; Hesse, Michael; Yaghi, Omar M.; Eddaoudi, Mohamed, Process for the epoxidation of an organic compound with oxygen or an oxygen-delivering compounds using catalysts containing metal-organic frame-work materials.
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Long, Jeffrey R.; Kapelewski, Matthew T.; Geier, Stephen J., Metal-organic frameworks with a high density of highly charged exposed metal cation sites.
McGrail, B. Peter; Thallapally, Praveen K.; Xu, Wu, Methods for associating or dissociating guest materials with a metal organic framework, systems for associating or dissociating guest materials within a series of metal organic frameworks, and gas separation assemblies.
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Masel, Richard I.; Radadia, Adarsh D., Micromachined gas chromatography columns for fast separation of Organophosphonate and Organosulfur compounds and methods for deactivating same.
Yaghi, Omar M.; Kim, Jaheon; Ko, Nakeun; Choi, Sang Beom; Furukawa, Hiroyasu, Open metal organic frameworks with exceptional surface area and high gas storage capacity.
Yaghi, Omar M.; Czaja, Alexander U.; Wang, Bo; Lu, Zheng, Oxidative homo-coupling reactions of aryl boronic acids using a porous copper metal-organic framework as a highly efficient heterogeneous catalyst.
Reyes, Sebastian C.; Santiesteban, legal representative, Jose G.; Ni, Zheng; Paur, Charanjit S.; Kortunov, Pavel; Zengel, John; Deckman, Harry W., Separation of methane from higher carbon number hydrocarbons utilizing zeolitic imidazolate framework materials.
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