초록 ▼

A method for removing nitrogen oxides and particulate matter from the lean exhaust gas of a combustion engine that also contains low concentrations of sulfur oxides. The exhaust gas stream is passed over a nitrogen oxide storage catalyst and a particulate filter, where nitrogen oxides and sulfur oxi

A method for removing nitrogen oxides and particulate matter from the lean exhaust gas of a combustion engine that also contains low concentrations of sulfur oxides. The exhaust gas stream is passed over a nitrogen oxide storage catalyst and a particulate filter, where nitrogen oxides and sulfur oxides are adsorbed by the storage catalyst under lean exhaust gas conditions and the particulate matter is deposited on the particulate filter. The storage catalyst is in a first cycle is periodically denitrated by enriching the exhaust gas regeneration of the particulate filter. Desulfurization of the nitrogen oxide storage catalyst is carried out in a second cycle by raising the temperature of the lean exhaust gas to a value at which the particulate matter combustion on the particulate filter is initiated and then the storage catalyst can be desulfurized by enriching the exhaust gas.

대표청구항 ▼

1. A method for removing nitrogen oxides and particulate matter from the lean exhaust gas of a combustion engine that also contains low concentrations of sulfur oxides, comprising in a first cycle, passing the exhaust gas stream over a nitrogen oxide storage catalyst and a particulate filter arrange

1. A method for removing nitrogen oxides and particulate matter from the lean exhaust gas of a combustion engine that also contains low concentrations of sulfur oxides, comprising in a first cycle, passing the exhaust gas stream over a nitrogen oxide storage catalyst and a particulate filter arranged in succession, where nitrogen oxides and sulfur oxides are adsorbed by the storage catalyst under lean exhaust gas conditions and the particulate matter is deposited on the particulate filter, and periodically denitrating the storage catalyst by enriching the exhaust gasand in a second cycle at first regenerating the particulate filter by increasing the temperature of the lean exhaust gas to a value at which the particulate combustion on the particulate filter is ignited and thereafter desulfurizing the nitrogen oxide storage catalysts by enriching the exhaust gas; wherein the temperature of the lean exhaust gas is increased by burning hydrocarbons on the nitrogen oxide storage catalyst. 2. The method according to claim 1, wherein the hydrocarbons are supplied to the nitrogen oxide storage catalyst by the addition of the hydrocarbons to the exhaust gas stream.3. The method of claim 1, further comprising passing the exhaust gas stream over an oxidation catalyst after passing the exhaust gas stream over the nitrogen oxide storage catalyst.4. The method according to claim 1, further comprising arranging the nitrogen oxide storage catalyst in the exhaust gas stream in front of the particulate filter and wherein increasing the exhaust gas temperature, is by adding hydrocarbons to the exhaust gas stream by after-injection of fuel into the combustion chambers of the internal combustion engine or by injection into the exhaust gas stream in front of the storage catalyst with the aid of an injection nozzle, while maintaining a net oxidizing gas composition, and after ignition of particulate combustion operating the combustion engine with a rich air/fuel mixture to generate a reducing exhaust gas composition for the desulfurization of the storage catalyst.5. The method according to claim 4, wherein the desulfurization of the storage catalyst is carried out at an exhaust gas air/fuel ratio of 0.7 to 0.98.6. The method according to claim 1, wherein the nitrogen oxide storage catalyst is applied in the form of a coating onto the inlet side and onto the outlet side of the particulate filter.7. The method according to claim 1, further comprising passing the exhaust gas stream successively over a nitrogen storage catalyst and particulate filter and in a third cycle carrying out only the regeneration of the particulate filter at a lean exhaust gas composition by increasing the exhaust gas temperature in front of the particular filter beyond the particulate ignition temperature.8. The method according to claim 7, wherein an oxidation catalyst is arranged in the exhaust gas stream in front of the particulate filter and in a third cycle injecting hydrocarbons into the exhaust gas stream to increase gas temperature in front of the particulate filter while maintaining a net oxidizing exhaust gas composition in front of the oxidation catalyst and burning the hydrocarbons on the oxidation catalyst.9. A method according to claim 8, wherein an oxidation catalyst is arranged in the exhaust gas stream in front of the particulate filter and in a third cycle adding hydrocarbons to the exhaust gas stream by after-injection of fuel into the combustion chambers of the diesel engine in order to increase the exhaust gas temperature in front of the particulate filter, while maintaining a net oxidizing exhaust gas composition, and the exhaust gas composed in this is diverted at the storage catalyst and sent to the oxidation catalyst.