IPC분류정보
국가/구분 |
United States(US) Patent
등록
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국제특허분류(IPC7판) |
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출원번호 |
US-0435208
(2003-05-09)
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발명자
/ 주소 |
- Cortright, Randy D.
- Dumesic, James A.
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출원인 / 주소 |
- Wisconsin Alumni Research Foundation
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대리인 / 주소 |
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인용정보 |
피인용 횟수 :
106 인용 특허 :
26 |
초록
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Disclosed is a method of producing hydrocarbons from oxygenated hydrocarbon reactants, such as glycerol, glucose, or sorbitol. The method can take place in the vapor phase or in the condensed liquid phase (preferably in the condensed liquid phase). The method includes the steps of reacting water and
Disclosed is a method of producing hydrocarbons from oxygenated hydrocarbon reactants, such as glycerol, glucose, or sorbitol. The method can take place in the vapor phase or in the condensed liquid phase (preferably in the condensed liquid phase). The method includes the steps of reacting water and a water-soluble oxygenated hydrocarbon having at least two carbon atoms, in the presence of a metal-containing catalyst. The catalyst contains a metal selected from the group consisting of Group VIIIB transitional metals, alloys thereof, and mixtures thereof. These metals are supported on supports that exhibit acidity or the reaction is conducted under liquid-phase conditions at acidic pHs. The disclosed method allows the production of hydrocarbon by the liquid-phase reaction of water with biomass-derived oxygenated compounds.
대표청구항
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1. A method of producing hydrocarbons comprising: reacting water and a water-soluble oxygenated hydrocarbon having at least two carbon atoms, in the presence of a metal-containing catalyst, wherein the catalyst comprises a metal selected from the group consisting of Group VIIIB transitional metals,
1. A method of producing hydrocarbons comprising: reacting water and a water-soluble oxygenated hydrocarbon having at least two carbon atoms, in the presence of a metal-containing catalyst, wherein the catalyst comprises a metal selected from the group consisting of Group VIIIB transitional metals, alloys thereof, and mixtures thereof, wherein hydrocarbons are produced.2. The method of claim 1, wherein the water and the oxygenated hydrocarbon are reacted at a temperature of from about 100° C. to about 450° C., and at a pressure where the water and the oxygenated hydrocarbon are gaseous.3. The method of claim 1, wherein the water and the oxygenated hydrocarbon are reacted at a temperature of from about 100° C. to about 300° C., and at a pressure where the water and the oxygenated hydrocarbon are gaseous.4. The method of claim 1, wherein the water and the oxygenated hydrocarbon are reacted at a temperature not greater than about 400° C., at a pressure where the water and the oxygenated hydrocarbon remain condensed liquids.5. The method of claim 1, wherein the water and the oxygenated hydrocarbon are reacted at a pH of from about 1.0 to about 10.0.6. The method of claim 1, wherein the catalyst comprises a metal selected from the group consisting of nickel, palladium, platinum, ruthenium, rhodium, iridium, cobalt, iron, osmium, alloys thereof, and mixtures thereof.7. The method of claim 1, wherein the catalyst is further alloyed or mixed with a metal selected from the group consisting of Group IB metals, Group IIB metals, Group VIb, and Group VIIb metals.8. The method of claim 1, wherein the catalyst is further alloyed or mixed with a metal selected from the group consisting of copper, tin, manganese, chromium, molybdenum, zinc, and rhenium.9. The method of claim 1, wherein the catalyst is adhered to a support.10. The method of claim 9, wherein the support is selected from the group consisting of silica, alumina, zirconia, titania, vanadia, ceria, carbon, silica-alumina, silica nitride, boron nitride, heteropolyacids, and mixtures thereof.11. The method of claim 9, wherein the support is surface-modified to create Brønsted acid sites thereon, whereby acidity of the support is increased.12. The method of claim 9, wherein the support is modified by treating it with a modifier selected from the group consisting of silanes, sulfates, phosphates, tungstenates, oxides of molybdenum, and combinations thereof.13. The method of claim 9, wherein the support is silica modified with trimethylethoxysilane.14. The method of claim 9, wherein the support is a zeolite.15. The method of claim 9, wherein the support is a carbon nanotube or a carbon fullerene.16. The method of claim 9, wherein the support is a nanoporous support.17. The method of claim 1, wherein the water and the oxygenated hydrocarbon are reacted at a pressure less than the vapor pressure of water at the desired reaction temperature.18. The method of claim 1, wherein the water and the oxygenated hydrocarbon are reacted at a temperature not greater than about 400° C., at a pressure where the water and the oxygenated hydrocarbon remain condensed liquids, and further comprising reacting the water and the water-soluble oxygenated hydrocarbon in the presence of a water-soluble acid.19. The method of claim 18, wherein the water-soluble acid is selected from the group consisting of a nitrate, phosphate, sulfate, and chloride acid salts, and mixtures thereof.20. The method of claim 1, wherein the water-soluble oxygenated hydrocarbon has a carbon-to-oxygen ratio of 1:1.21. The method of claim 1, wherein the water-soluble oxygenated hydrocarbon has from 2 to 12 carbon atoms.22. The method of claim 1, wherein the water-soluble oxygenated hydrocarbon is selected from the group consisting of ethanediol, ethanedione, glycerol, glyceraldehyde, aldotetroses, aldopentoses, aldohexoses, ketotetroses, ketopentoses, ketohexoses, and alditols.23. The method of claim 1, wherein the water-soluble oxygenated hydrocarbon is selected from the group consisting of aldohexoses and corresponding alditols.24. The method of claim 1, wherein the water-soluble oxygenated hydrocarbon is selected from the group consisting of xylose, glucose and sorbitol.25. The method of claim 1, wherein the water-soluble oxygenated hydrocarbon is a disaccharide.26. A method of producing C1 to C6 hydrocarbons comprising: reacting water and a water-soluble oxygenated hydrocarbon having at least two carbon atoms, at a temperature not greater than about 400° C., at a pressure where the water and the oxygenated hydrocarbon remain condensed liquids, and in the presence of a metal-containing catalyst, wherein the catalyst comprises a metal selected from the group consisting of Group VIIIB transitional metals, alloys thereof, and mixtures thereof, wherein C1 to C6 hydrocarbons are produced.27. The method of claim 26, wherein the catalyst comprises a metal selected from the group consisting of nickel, palladium, platinum, ruthenium, rhodium, iridium, cobalt, iron, osmium, alloys thereof, and mixtures thereof.28. The method of claim 26, wherein the catalyst is further alloyed or mixed with a metal selected from the group consisting of Group IB metals, Group IIB metals, Group VIb, and Group VIIb metals.29. The method of claim 26, wherein the catalyst is further alloyed or mixed with a metal selected from the group consisting of copper, zinc, tin, manganese, chromium, molybdenum, and rhenium.30. The method of claim 26, wherein the catalyst is adhered to a support.31. The method of claim 30, wherein the support is selected from the group consisting of silica, alumina, zirconia, titania, ceria, carbon, silica-alumina, vanadia, heteropolyacids, silica nitride, boron nitride, and mixtures thereof.32. The method of claim 30, wherein the support is modified by treating it with a modifier selected from the group consisting of sulfates, phosphates, tungstenates, oxides of molybdenum, and silanes.33. The method of claim 30, wherein the support is silica modified with trimethylethoxysilane.34. The method of claim 30, wherein the support is a zeolite.35. The method of claim 30, wherein the support is a carbon nanotube or a carbon fullerene.36. The method of claim 30, wherein the support is a nanoporous support.37. The method of claim 26, further comprising reacting the water and the water-soluble oxygenated hydrocarbon in the presence of a water-soluble acid.38. The method of claim 37, wherein the water-soluble acid is selected from the group consisting of H2SO4, HNO3, H2PO4, and HCl.39. The method of claim 26, wherein the water-soluble oxygenated hydrocarbon has a carbon-to-oxygen ratio of 1:1.40. The method of claim 26, wherein the water-soluble oxygenated hydrocarbon has from 2 to 12 carbon atoms.41. The method of claim 26, wherein the water-soluble oxygenated hydrocarbon is selected from the group consisting of ethanediol, ethanedione, glycerol, glyceraldehyde, aldotetroses, aldopentoses, aldohexoses, ketotetroses, ketopentoses, ketohexoses, and alditols.42. The method of claim 26, wherein the water-soluble oxygenated hydrocarbon is selected from the group consisting of aldohexoses and corresponding alditols.43. The method of claim 26, wherein the water-soluble oxygenated hydrocarbon is selected from the group consisting of xylose, glucose and sorbitol.44. The method of claim 26, wherein the water-soluble oxygenated hydrocarbon is a disaccharide.45. A method of producing C1 to C6 alkanes comprising: reacting water and a water-soluble oxygenated hydrocarbon having at least two carbon atoms, at a temperature of from about 100° C. to about 450° C., and at a pressure where the water and the oxygenated hydrocarbon are condensed liquids, in the presence of a metal-containing catalyst, wherein the catalyst comprises a metal selected from the group consisting of Group VIII transitional metals, alloys thereof, and mixtures thereof, the catalyst being adhered to a support wherein C1 to C6 alkanes are produced.46. The method of claim 45, wherein the support is selected from the group consisting of silica, alumina, zirconia, titania, ceria, vanadia, heteropolyacids, carbon, silica-alumina, silica nitride, and boron nitride, wherein the support is surface-modified to create Brønsted acid sites thereon, whereby acidity of the support is increased.47. The method of claim 46, wherein the support wherein the support is modified by treating it with a modifier selected from the group consisting of silanes, sulfates, phosphates, tungstenates, oxides of molybdenum, and combinations thereof.48. The method of claim 45, wherein the support is silica modified with trimethylethoxysilane.49. The method of claim 45, wherein the water-soluble oxygenated hydrocarbon has a carbon-to-oxygen ratio of 1:1.50. The method of claim 45, wherein the water-soluble oxygenated hydrocarbon is selected from the group consisting of ethanediol, ethanedione, glycerol, glyceraldehyde, aldotetroses, aldopentoses, aldohexoses, ketotetroses, ketopentoses, ketohexoses, and alditols.
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