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Volatile organic compound or other materials are produced in the thermoplastic manufacture of thermoplastic polyester beverage containers. Such materials can be eluted into beverages such as carbonated beverages, sparkling or still water from the polyester. Such thermoplastic polyester resins can be

Volatile organic compound or other materials are produced in the thermoplastic manufacture of thermoplastic polyester beverage containers. Such materials can be eluted into beverages such as carbonated beverages, sparkling or still water from the polyester. Such thermoplastic polyester resins can be manufactured with a substituted cyclodextrin material that can prevent the formation of, or react with, and absorb volatile by-products during the formation of thermoplastic preforms or containers from the thermoplastic pellet or chip. Further, as the preform is blown into a polyester container, the active materials of the invention prevent the generation of additional undesirable volatile materials. Lastly, the scavenger material can act as a barrier that prevents transport of materials from the exterior of the container into the container contents.

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1. A method of making a shaped polyester member comprising the steps of:(a) forming a coating of a substituted cyclodextrin material on the surface of a polyester pellet or chip in an amount effective to obtain scavenging and barrier properties and to complex catalyst residue, the substituted cyclod

1. A method of making a shaped polyester member comprising the steps of:(a) forming a coating of a substituted cyclodextrin material on the surface of a polyester pellet or chip in an amount effective to obtain scavenging and barrier properties and to complex catalyst residue, the substituted cyclodextrin having a degree of substitution of about 0.3 to 1.8; wherein the substituted cyclodextrin is substantially free of any compound in the central pore of the cyclodextrin ring; and (b) melt extruding the coated chip in an extruder to form a polymer melt into a shaped polymer comprising 100 to 2000 parts by weight of the substituted cyclodextrin per each one million parts of polyester. 2. The method of claim 1 wherein the shaped polymer member comprises a parison, perform or container and the member comprises 100 to 1400 parts by weight of a substituted cyclodextrin per each one million parts of polyester.3. The method of claim 1 wherein the shaped polymer member comprises a polymer preform and further comprises the steps of inflating the polymer preform at an appropriate temperature and pressure to form a thermoplastic beverage container.4. The method of claim 1 wherein the polyester comprises at least 60% by weight polyethylene terephthalate units and up to 40% by weight other polymers.5. The method of claim 1 wherein the polyester comprises at least 60% by weight polyethylene terephthalate units and up to 40% by weight other polymers.6. The chip of claim 1 wherein the polyester comprises at least 60% by weight polyethylene naphthalate units and up to 40% by weight other polymers.7. The chip of claim 1 wherein the polyester comprises a copolymer of polyethylene terephthalate/isophthalate and the cyclodextrin is a non-reducing carbohydrate.8. The chip of claim 1 wherein the cyclodextrin compound has a substituent substantially on at least one ?OH group on the ?6 position of the glucose moiety in the cyclodextrin.9. The chip of claim 8 wherein the cyclodextrin compound comprises a 6-O-Methyl ether.10. The chip of claim 8 wherein the cyclodextrin compound comprises a 6-O-Acetyl ester.11. The chip of claim 1 wherein the cyclodextrin compound comprises a degree of substitution of about 0.5 to 1.2 in an amount of about 350 parts by weight to about 900 parts by weight of the cyclodextrin compound per each one million parts of polyester resin.12. A method of making a polyester chip comprising the steps of:(a) forming an aqueous solution of a substituted cyclodextrin compound, the solution comprising about 1.0 to 50 weight percent of the substituted cyclodextrin compound; (b) contacting the aqueous solution with an activated carbon absorbent, an ion exchange resin, a reverse osmosis membrane or a nanofiltration membrane to reduce the concentration of impurities in the aqueous solution to form a purified aqueous solution; (c) contacting a polyester chip with the purified aqueous solution to form a coating of a cyclodextrin material on the surface of a polyester chip in an amount of about 100 parts by weight to 1400 parts by weight of the cyclodextrin compound, per each one million parts by weight of the polymer chip to form a coated chip; and, (d) drying the coated chip. 13. The method of claim 12 wherein the coating is formed from a solution comprising about 3.0 to 40 wt.-% cyclodextrin in an aqueous medium.14. The method of claim 12 wherein the polyester comprises at least 60% by weight polyethylene terephthalate units and up to 40% by weight other polymers.15. The method of claim 12 wherein the polyester comprises at least 60% by weight polyethylene naphthalate units and up to 40% by weight other polymers.16. The chip of claim 12 wherein the polyester comprises a copolymer of polyethylene terephthalate/isophthalate and the cyclodextrin is a non-reducing carbohydrate.17. The method of claim 12 wherein the cyclodextrin compound has a substituent substantially on at least one ?OH group on the ?6 position of the glucose moiety in the cyclodextrin.18. The method of claim 17 wherein the cyclodextrin compound comprises a 6-O-Methyl ether.19. The method of claim 17 wherein the cyclodextrin compound comprises a 6-O-Acetyl ester.20. The method of claim 17 wherein the cyclodextrin compound comprises a degree of substitution of about 0.5 to 1.2 in an amount of about 350 parts by weight to about 900 parts by weight of the cyclodextrin compound per each one million parts of polyester resin.21. A method of making a polyester beverage container comprising the steps of:(a) forming an aqueous solution of a substituted cyclodextrin compound, the solution comprising about 1.0 to 50 weight percent of the substituted second action compound; (b) contacting the aqueous solution with an activated carbon absorbent, an ion exchange resin or a reverse osmosis membrane, to reduce the concentration of impurities in the aqueous solution to form a purified aqueous solution; (c) contacting a polyester chip with the purified aqueous solution to form a coating of a cyclodextrin material on the surface of the polyester chip in an amount of about 100 parts by weight to 1400 parts by weight of the cyclodextrin compound, per each one million parts by weight of the polymer chip to form a coated chip; (d) drying the chip to form a coated chip; and (e) melt extruding the coated chip in an extruder to form a shaped beverage container. 22. The method of claim 21 wherein the shaped polymer comprises a polyester container having a volume of about 250 mL to 5 Liters.23. The method of claim 21 wherein the polyester comprises at least 60% by weight polyethylene terephthalate units and up to 40% by weight other polymers.24. The method of claim 21 wherein the polyester comprises at least 60% by weight polyethylene naphthalate units and up to 40% by weight other polymers.25. The chip of claim 21 wherein the polyester comprises a copolymer of polyethylene terephthalate/isophthalate and the cyclodextrin is a non-reducing carbohydrate.26. The method of claim 23 wherein a preform is melt formed prior to forming a shaped container.27. The method of claim 21 wherein the cyclodextrin compound has a substituent substantially on at least one ?OH group on the ?6 position of the glucose moiety in the cyclodextrin.28. The method of claim 27 wherein the cyclodextrin compound comprises a 6-O-Methyl ether.29. The method of claim 27 wherein the cyclodextrin compound comprises a 6-O-Acetyl ester.30. The method of claim 21 wherein the cyclodextrin compound comprises a degree of substitution of about 0.5 to 1.2 in an amount of about 350 parts by weight to about 900 parts by weight of the cyclodextrin compound per each one million parts of polyester resin.