초록 ▼

A process for preparing maleic anhydride by heterogeneously catalyzed gas-phase oxidation of an n-butene-containing hydrocarbon stream by means of oxygen-containing gases in a shell-and-tube reactor having two successive reaction zones, where the first, feed-side reaction zone contains at least one

A process for preparing maleic anhydride by heterogeneously catalyzed gas-phase oxidation of an n-butene-containing hydrocarbon stream by means of oxygen-containing gases in a shell-and-tube reactor having two successive reaction zones, where the first, feed-side reaction zone contains at least one catalyst which is suitable for the oxydehydrogenation of n-butenes to 1,3-butadiene and the second, product-side reaction zone contains at least one catalyst which is suitable for the oxidation of 1,3-butadiene to maleic anhydride, is carried out using a shell-and-tube reactor which has at least one heat transfer medium circuit in the region of the first, feed-side reaction zone and at least one further heat transfer medium circuit in the region of the second, product-side reaction zone.

대표청구항 ▼

We claim: 1. A process for preparing maleic anhydride by heterogeneously catalyzed gas-phase oxidation of an n-butene-containing hydrocarbon stream by means of oxygen-containing gases in a shell-and-tube reactor, which comprises conducting the gas-phase oxidation of the n-butene-containing hydrocar

We claim: 1. A process for preparing maleic anhydride by heterogeneously catalyzed gas-phase oxidation of an n-butene-containing hydrocarbon stream by means of oxygen-containing gases in a shell-and-tube reactor, which comprises conducting the gas-phase oxidation of the n-butene-containing hydrocarbon stream in a shell-and-tube reactor which has two successive reaction zones (a) and (b), (a) being the first, feed-side reaction zone and containing at least one catalyst which is suitable for oxydehydrogenating n-butenes to obtain 1,3-butadiene, and (b) being the second, product-side reaction zone and containing at least one catalyst which is suitable for oxidizing 1,3-butadiene to obtain maleic anhydride, and wherein the shell-and-tube reactor has, in the region of each of the reactions zones (a) and (b), at least one heat transfer medium circuit which is separate and independent from the heat transfer medium circuit of the other reaction zone. 2. A process as claimed in claim 1, wherein the reaction gas from the first, feedside reaction zone is passed through an inert intermediate bed before it enters the second, product-side reaction zone. 3. A process as claimed in claim 2, wherein the inert intermediate bed used is a bed of inert material having an empty volume fraction of from 40 to 99.5%. 4. A process as claimed in claim 1, wherein the active composition of the catalyst suitable for the oxydehydrogenation of n-butenes to 1,3-butadiene is a multimetal oxide of the formula (I) Mo 12BiaFebCo cNidCreX 1fKgOx (I), where the variables have the following meanings: X1=W, Sn, Mn, La, Ce, Ge, Ti, Zr, Hf, Nb, P, Si, Sb, Al, Cd and/or Mg; a=0.5 to 5; b=0 to 5; c=0 to 10; d=0 to 10; e=0 to 10; f=0 to 5; g=0 to 2; and x=a number determined by the valence and abundance of the elements other than oxygen in (I). 5. A process as claimed in claim 1, wherein the active composition of the catalyst suitable for the oxidation of 1,3-butadiene to maleic anhydride is a multimetal oxide of the formula (II) SbMo aSnbX2 cOx (II), where the variables have the following meanings: X2=V, Fe, Ni, Li, Ce, Nb, Ta, W, Ti, Zr, B, P, Al and/or Mg; a=1 to 10; b=0 to 5; c=0 to 3; and x=a number determined by the valence and abundance of the elements other than oxygen in (II). 6. A process as claimed in claim 1, wherein the active composition of the catalyst suitable for the oxidation of 1,3-butadiene to maleic anhydride is a multimetal oxide of the formula (III) Mo 12VaWbX3 cOx (III), where the variables have the following meanings: X3=La, Mn, Fe, Cu, Al, Co, Ni, Bi, Ag, P, Zn, Cd, As, Cr, Sn, U, Ti, Nb, Ge, an alkali metal and/or an alkaline earth metal; a=0.1 to 12; b=0 to 5; c=0 to 12; and x=a number determined by the valence and abundance of the elements other than oxygen in (III). 7. A process as claimed in claim 1, wherein the oxydehydrogenation of n-butenes to 1,3-butadiene in the first, feed-side reaction zone is carried out at from 220 to 490째C. and the oxidation of 1, 3-butadiene to maleic anhydride in the second, product-side reaction zone is carried out at from 190 to 500째C. 8. A process as claimed in claim 1, wherein the pressure at the reactor inlet is from 0.005 to 1 MPa gauge pressure. 9. A process as claimed in claim 1, wherein the n-butene-containing hydrocarbon stream used is a raffinate II stream.