Hydrogenation of tetrahydroxybutane to tetrahydrofuran
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
C07D-307/02
C07D-307/00
출원번호
US-0292881
(2002-11-12)
발명자
/ 주소
Manzer,Leo Ernest
출원인 / 주소
Invista North America S.A.R.L.
인용정보
피인용 횟수 :
21인용 특허 :
5
초록
Disclosed is a method for the hydrogenation of tetrahydroxybutane in the presence of supported rhenium catalysts and an acid to form tetrahydrofuran and its precursors.
대표청구항▼
What is claimed is: 1. A process for preparing tetrahydrofuran or a mixture of tetrahydrofuran and unsaturated compounds having either one of Formulae II or III, wherein R is independently hydrogen or--OH, the process comprising: contacting 1,2,3,4-tetrahydroxybutane in the presence of at least o
What is claimed is: 1. A process for preparing tetrahydrofuran or a mixture of tetrahydrofuran and unsaturated compounds having either one of Formulae II or III, wherein R is independently hydrogen or--OH, the process comprising: contacting 1,2,3,4-tetrahydroxybutane in the presence of at least one acid with a catalytic amount of rhenium, the rhenium being supported on a carbon support. 2. The process according to claim 1 wherein the 1,2,3,4-tetrahydroxybutane is erythritol. 3. The process according to claim 1 further comprising converting said unsaturated compounds of formula (II) or (III) to tetrahydrofuran. 4. The process of claim 3 wherein the unsaturated compounds of formula (II) or (III) are recycled back into said process. 5. The process according to claim 1 wherein the rhenium supported on the carbon support further comprises a metal promoter. 6. The process according to claim 5 wherein the metal promoter is selected from Group 8 metals of the Periodic Table of Elements. 7. The process according to claim 3 wherein the metal promoter is Ni or Pd. 8. The process according to claim 1 wherein the acid is selected from the group consisting of a) an acid having a pKa less than about 4, or a metal salt thereof, b) an acidic zeolite, and c) a mixture of one or more compounds from a) with one or more compounds from b). 9. The process of claim 1 wherein the acid comprises at least one compound selected from the group consisting of inorganic acids, organic sulfonic acids, heteropolyacids, perfluoroalkyl sulfonic acids, and metal salts thereof. 10. The process according to claim 1 wherein the acid comprises at least one compound selected from the group consisting of sulfuric acid, sulfonic acid, and fluorinated sulfonic acid polymer. 11. The process according to claim 1 wherein the acid comprises at least one compound selected from the group consisting of sulfuric acid, methanesulfonic acid, p-toluicsulfonic acid, benzenesulfonic acid, fluorinated sulfonic acid polymer ion-exchanged with a metal from Group 8 of the Periodic Table of Elements, a zeolite with labile H+ groups on its surface, and a zeolite with Lewis acid sites on its surface. 12. The process according to claim 1 wherein the acid is supported on a solid support. 13. The process according to claim 12 wherein the solid support is selected from the group consisting of SiO2 (silica), Al2O3 (alumina), TiO2 (titania), MgO (magnesia) or ZrO2 (zirconia), zeolites, carbon, clays, and mixtures thereof. 14. The process according to claim 1 wherein the process is performed at a temperature of 100째 C. to 300째 C. and a pressure of 1.0 MPa to 10.0 MPa. 15. The process according to claim 1 wherein the process is performed at a temperature of 150째 C. to 250째 C. and a pressure of 3.0 MPa to 4.0 MPa. 16. The process according to claim 1, wherein the process is performed in the presence of a solvent, and wherein further the solvent is a dioxane solvent. 17. The process according to claim 1 wherein the mixture of tetrahydrofuran and one or more unsaturated compounds of formula (II) or (III) is prepared. 18. A process for preparing a compound having any one of Formulae I, II or III: wherein R is independently hydrogen or hydroxyl group, the process comprising: contacting 1,2,3,4-tetrahydroxybutane in the presence of at least one acid with a catalytic amount of rhenium, the rhenium being supported on a carbon support. 19. The process of claim 1 wherein the process is performed in the presence of a solvent. 20. The process of claim 1 wherein the acid has a pKa less than about 2. 21. The process of claim 1 wherein the catalyst comprises about 1% to about 50% by weight of rhenium. 22. The process of claim 21 wherein the catalyst comprises about 5% to about 20% by weight of rhenium. 23. The process of claim 1 further comprising contacting the tetrahydroxybutane with a catalytic amount of rhenium in the presence of hydrogen. 24. The process according to claim 19, wherein the solvent is a dioxane solvent. 25. A process for producing a composition comprising tetrahydrofuran, furan, and 1,4-dihydrofuran, the process comprising: contacting 1,2,3,4-recrahydroxybutane in the presence of at least one acid with a catalytic amount of rhenium, the rhenium being supported on a carbon support.
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이 특허에 인용된 특허 (5)
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de Silva, Wathudura Indika Namal; Korovessi, Ekaterini; Menning, Carl Andrew; Murphy, Joseph E; Ritter, Joachim C; Sengupta, Sourav Kumar, Process for the production of hexanediols.
Allgeier, Alan Martin; Carlson, Torren Ryan; Corbin, David Richard; De Silva, Wathudura Indika Namal; Korovessi, Ekaterini; Menning, Carl Andrew; Ritter, Joachim C; Rosenfeld, H David; Sengupta, Sourav Kumar, Production of alpha, omega-diols.
Allgeier, Alan Martin; Carlson, Torren Ryan; Corbin, David Richard; De Silva, Wathudura Indika Namal; Korovessi, Ekaterini; Menning, Carl Andrew; Ritter, Joachim C; Sengupta, Sourav Kumar, Production of alpha, omega-diols.
Allgeier, Alan Martin; Carlson, Torren Ryan; Corbin, David Richard; De Silva, Wathudura Indika Namal; Menning, Carl Andrew; Ritter, Joachim C; Sengupta, Sourav Kumar, Production of alpha, omega-diols.
Allgeier, Alan Martin; De Silva, Wathudura Indika Namal; Menning, Carl Andrew; Ritter, Joachim C; Sengupta, Sourav Kumar, Production of alpha, omega-diols.
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de Silva, Wathudura Indika Namal; Korovessi, Ekaterini; Menning, Carl Andrew; Murphy, Joseph E; Ritter, Joachim C; Sengupta, Sourav Kumar; Stauffer, Christina S, Production of tetrahydrofuran-2, 5-dimethanol from isosorbide.
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