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A process to facilitate mercury extraction from high temperature flue/fuel gas via the use of metal sorbents which capture mercury at ambient and high temperatures. The spent sorbents can be regenerated after exposure to mercury. The metal sorbents can be used as pure metals (or combinations of meta

A process to facilitate mercury extraction from high temperature flue/fuel gas via the use of metal sorbents which capture mercury at ambient and high temperatures. The spent sorbents can be regenerated after exposure to mercury. The metal sorbents can be used as pure metals (or combinations of metals) or dispersed on an inert support to increase surface area per gram of metal sorbent. Iridium and ruthenium are effective for mercury removal from flue and smelter gases. Palladium and platinum are effective for mercury removal from fuel gas (syngas). An iridium-platinum alloy is suitable for metal capture in many industrial effluent gas streams including highly corrosive gas streams.

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We claim: 1. A process for removing metal from fluid, the process comprising: a) supplying an active metal sorbent; and b) contacting the fluid with the sorbent for a time sufficient for the metal to absorb to predetermined regions of the sorbent, wherein the active metal sorbent is selected from t

We claim: 1. A process for removing metal from fluid, the process comprising: a) supplying an active metal sorbent; and b) contacting the fluid with the sorbent for a time sufficient for the metal to absorb to predetermined regions of the sorbent, wherein the active metal sorbent is selected from the group consisting of iridium, palladium, ruthenium and iridium-platinum alloy and the fluid is selected from the group consisting of flue gases and combustion gases. 2. The process as recited in claim 1 wherein the contacting step further comprises: a) relegating metal adsorption to an exterior surface of the sorbent; and b) allowing the relegated metal to diffuse into the interior of the sorbent. 3. The process as recited in claim 2 wherein the metal diffuses into the sorbent when the sorbent is heated to more than 150째 C. (300째 F.). 4. The process as recited in claim 1 wherein the metal to be adsorbed is a Group IIB metal selected from the group comprising of mercury, cadmium or a combination thereof. 5. The process as recited in claim 4 wherein the Group IIB metal forms an amalgam with the metal in the sorbent. 6. The process as recited in claim 4 wherein the Group IIB metal is desorbed from the sorbent. 7. The process as recited in claim 1 wherein the temperature of the fluid ranges from approximately 170째 C. to 370째 C. (700째 F.). 8. The process as recited in claim 1 wherein the metal sorbent is a solid mass. 9. The process as recited in claim 8 wherein the active metal is dispersed throughout the solid mass. 10. The process as recited in claim 9 wherein the surface area of the solid mass is between approximately 1 m2/gram to 1000 m2/gram. 11. The process as recited in claim 1 wherein the metal sorbent is regenerated by heating to a temperature above 500째 C. (930째 F.) . 12. A process for increasing the surface area of an active metal sorbent, the process comprising: a) supplying a support with a surface area of between 1 m 2/g to 1000 m2/g; and b) depositing active metal sorbent on the support, wherein the active metal sorbent is selected from the group consisting of iridium, palladium, ruthenium and iridium-platinum alloy and the active metal is deposited on a support in a controlled atmosphere selected from the group consisting of argon (Ar), nitrogen (N2), or a combination thereof. 13. The process as recited in claim 12 wherein the support is a high temperature tolerant material selected from a group consisting of activated carbon, alumina, aluminosilicates, silica, titania, zirconia, zeolite, or combinations thereof. 14. The process as recited in claim 12 wherein the support can withstand temperatures above 925째 C. (1700째 F.). 15. The process as recited in claim 12 wherein the deposited metal sorbent is a solid phase selected from the group consisting of extrudates, powders, pellets, or monoliths. 16. The process of claim 14 further comprising increasing the resistance of metal sorbents to chemical reaction, the process comprising alloying active metals, wherein the active metal sorbent is selected from the group consisting of iridium, palladium, ruthenium and iridium-platinum alloy. 17. A process for increasing the surface area of an active metal sorbent, the process comprising: a) supplying a support with a surface area of between 1 m 2/g to 1000 m2/g; and b) depositing active metal sorbent on the support, wherein the active metal sorbent is selected from the group consisting of iridium and ruthenium. 18. The process as recited in claim 17 wherein the active metal is deposited on a support in a controlled atmosphere selected from the group consisting of argon (Ar), nitrogen (N2), or a combination thereof.