초록 ▼

The disclosed invention relates to a composition comprising a partially dehydrated product made by: (I) reacting (A) a hydrocarbyl substituted succinic acid or anhydride with (B) a polyol, a polyamine, a hydroxyamine, or a mixture of two or more thereof, to form a first intermediate product compr

The disclosed invention relates to a composition comprising a partially dehydrated product made by: (I) reacting (A) a hydrocarbyl substituted succinic acid or anhydride with (B) a polyol, a polyamine, a hydroxyamine, or a mixture of two or more thereof, to form a first intermediate product comprising: an ester, partial ester or mixture thereof when (B) is a polyol; an amide, imide, salt, amide/salt, partial amide or mixture of two or more thereof when (B) is a polyamine; or an ester, partial ester, amide, partial amide, amide/salt, imide, ester/salt, salt or a mixture of two or more thereof when (B) is a hydroxyamine, a mixture of a polyol and a polyamine, a mixture of a polyol and a hydroxyamine, a mixture of a polyamine and a hydroxyamine, or a mixture of a polyol, a polyamine and a hydroxyamine; the hydrocarbyl substituent of said acid or anhydride having an average of about 8 to about 200 carbon atoms; and (II) heating said first intermediate product at an effective temperature to form a second intermediate product with water of reaction being formed, and separating a portion of said water of reaction from said second intermediate product, when (A) is said succinic anhydride the amount of water of reaction that is separated is from about 0.2 to about 0.9 equivalents of said water of reaction per equivalent of said succinic anhydride, when (A) is said succinic acid the amount of water of reaction that is separated is from about 1.2 to about 1.9 moles of said water of reaction per equivalent of said succinic acid, said partially dehydrated product having a total acid number in the range of about 20 to about 100 mg of KOH/g. A process for making the foregoing partially dehydrated product is also disclosed. Emulsions comprising an organic phase, an aqueous phase, and an emulsifying amount of the foregoing partially dehydrated product are disclosed.

대표청구항 ▼

The invention claimed is: 1. A composition comprising a partially dehydrated product made by: (I) reacting (A) a hydrocarbyl substituted succinic acid or anhydride with (B) a polyol, a polyamine, a hydroxyamine, or a mixture of two or more thereof, to form a first intermediate product comprising: a

The invention claimed is: 1. A composition comprising a partially dehydrated product made by: (I) reacting (A) a hydrocarbyl substituted succinic acid or anhydride with (B) a polyol, a polyamine, a hydroxyamine, or a mixture of two or more thereof, to form a first intermediate product comprising: an ester, partial ester or a mixture thereof when (B) is a polyol; an amide, imide, salt, amide/salt, partial amide or mixture two or more thereof when (B) is a polyamine; or an ester, partial ester, amide, partial amide, amide/salt, imide, ester/salt, salt or a mixture of two or more thereof when (B) is a hydroxyamine, a mixture of a polyol and a polyamine, a mixture of polyol and a hydroxyamine, a mixture of a polyamine and a hydroxyamine, or a mixture of a polyol, a polyamine and a hydroxyamine; the hydrocarbyl sustitutent of said acid or anhydride having an average of about 8 to about 200 carbon atoms; and (II) heating said first intermediate product at an effective temperature to form a second intermediate product with water of reaction being formed, and separating a portion of said water of reaction from said second intermediate product to form said partially dehydrated product, when (A) is said succinic anhydride the amount of water of reaction that is separated is from about 0.2 to about 0.9 moles of said water of reaction per equivalent of said succinic anhydride, when (A) is said succinic acid the amount of water of reaction that is separated is from about 1.2 to about 1.9 moles of said water of reacting per equivalent of said succinic acid, said partially dehydrated product having a total acid number in the range of about 20 to about 100 mg of KOH/g. 2. The composition of claim 1 wherein said hydrocarbyl substituent has an average of about 18 to about 30 carbon atoms. 3. The composition of claim 1 wherein a mixture of at least two hydrocarbyl substituted succinic acids or anhydrides is used, the hydrocarbyl substituent of one of said acids or anhydrides having an average of about 12 to about 24 carbon atoms, and the hydrocarbyl substituent of another of said acids or anhydrides having an average of about 60 to about 200 carbon atoms. 4. The composition of claim 1 wherein said hydrocarbyl substituted succinic acid or anhydride consists of hydrocarbyl substituent groups and succinic groups and is characterized by the presence within its structure of at least about 1.3 succinic groups for each equivalent weight of the hydrocarbyl substituent. 5. The composition of claim 1 wherein said polyol is a compound represented by the formula description="In-line Formulae" end="lead"R--(OH) m (I)description="In-line Formulae" end="tail" wherein in Formula (I), R is an organic group having a valency of m, R is joined to the OH groups through carbon-to-oxygen bonds, and m is an integer from 2 to about 10. 6. The composition of claim 1 wherein said polyol is a glycol, a polyoxyalkylene glycol, a carbohydrate, or a partially esterfied polyhydric alcohol. 7. The composition of claim 1 wherein said polyol is ethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol, dibutylene glycol, tributylene glycol, 1,2-butanediol, 2,3-dimethyl-2,3-butanediol, 2,3-hexanediol, 1,2-cyclohexanediol, pentaerythritol, dipentaerythritol, 1,7-heptanediol, 2,4-heptanediol, 1,2,3-hexanetriol, 1,2,4-hexanetriol, 1, 2,5-hexanetriol, 2,3,4-hexanetriol, 1,2,3-butanetriol, 1,2,4-butanetriol, 2,2,6,6-tetrakis-(hydroxymethyl)cyclohexanol, 1,10-decanediol, digitalose, 2-hydroxymethyl-2-methyl-1,3-propanediol-(tri-methylolethane), or 2-hydroxymethyl-2-ethyl-1,3-propanediol-(trimethylopropane). 8. The composition of claim 1 wherein said polyol is a sugar, a starch, or a mixture thereof. 9. The composition of claim 1 wherein said polyol is erythritol, threitol, adonitol, arabitol, xylitol, sorbitol, mannitol, erythrose, fucose, ribose, xylulose, arabinose, xylose, glycose, fructose, sorbose, mannose, sorbitan, glucosamine, sucrose, rhamnose, glyceraldehyde or galactose. 10. The composition of claim 1 wherein said polyol is a compound represented by the formula description="In-line Formulae" end="lead"HO(CH 2CH(OH)CH2O)nHdescription="In-line Formulae" end="tail" wherein n is a number in the range of 1 to about 5. 11. The composition of claim 1 wherein said polyol is a polyhydric alcohol having at least three hydroxyl groups, some of the hydroxyl groups being esterfied with an aliphatic monocarboxylic acid of about 8 to about 30 carbon atoms, at least two of the hydroxyl groups not being esterfied. 12. The composition of claim 1 wherein said polyol is monooleate of glycerol, monostearate of glycerol, monooleate of sorbitol, distearate of sorbitol, or di-dodecanoate of erythritol. 13. The composition of claim 1 wherein said polyamine is an aliphatic, cycloaliphatic, heterocyclic or aromatic compound. 14. The composition of claim 1 wherein said polyamine is a compound represented by the formula wherein n has an average value between 1 and about 10, the Alkylene group has from 1 to about 10 carbon atoms, and each R is independently hydrogen or an aliphatic or hydroxy-substituted aliphatic group of up to about 30 carbon atoms. 15. The composition of claim 1 wherein said polyamine is ethylene diamine, triethylene tetramine, tris-(2-aminoethyl)amine, propylene diamine, trimethylene diamine, tripropylene tetramine, tetraethylene pentamine, hexaethylene heptamine, pentaethylenehexamine, or a mixture of two or more thereof. 16. The composition of claim 1 wherein said polyamine is an ethylene polyamine. 17. The composition of claim 1 wherein said polyamine is a heterocyclic amine. 18. The composition of claim 1 wherein said hydroxyamine is (a) an N-(hydroxyl-substituted hydrocarbyl) amine, (b) a hydroxyl-substituted poly(hydrocarbyloxy) analog of (a), or a mixture of (a) and (b). 19. The composition of claim 1 wherein said hydroxyamine is an alkanolamine containing from 1 to about 40 carbon atoms. 20. The composition of claim 1 wherein said hydroxyamine is selected from the group consisting of (a) primary, secondary or tertiary alkanol amines represented respectively by the formulae (b) hydroxyl-substituted poly(hydrocarbyloxy) analogs of said primary, secondary or tertiary alkanolamines represented respectively by the formulae wherein each R independently is a hydrocarbyl group of one to about 8 carbon atoms or a hydroxyl-substituted hydrocarbyl group of 2 to about 8 carbon atoms, each R' independently is a divalent hydrocarbon group of 2 to about 18 carbon atoms, and each x independently is 2 to about 15, and (c) mixtures of two of more of any of the above. 21. The composition of claim 1 wherein (B) is glycerol, diethanolamine, triethanol amine, or a mixture of two or more thereof. 22. The composition of claim 1 wherein the ratio of equivalents of component (A) to component (B) is about 3:1 to about 1:2. 23. A composition comprising a partially dehydrated product made by: (I) reacting (A) a hydrocarbyl substituted succinic acid or anhydride with (B) a polyamine, a hydroxyamine, a mixture of a polyol and a polyamine, a mixture of a polyol and a hydroxyamine, a mixture of a polyamine and a hydroxyamine, or a mixture of a polyol, a polyamine and a hydroxyamine, to form a first intermediate product comprising: an amide, imide, salt, amide/salt, partial amide or mixture two or more thereof when (B) is a polyamine; or an ester, partial ester, amide, partial amide, amide/salt, amide, ester/salt, salt or a mixture of two or more thereof when (B) is a hydroxyamine, a mixture of a polyol and a polyamine, a mixture of a polyol and a hydroxyamine, a mixture of a polyamine and a hydroxyamine, or a mixture of a polyol, a polyamine and a hydroxyamine; the hydrocarbyl sustitutent of said acid or anhydride having an average of about 8 to about 200 carbon atoms; and (II) heating said first intermediate product at an effective temperature to form a second intermediate product with water of reaction being formed, and separating a portion of said water of reaction from said second intermediate product to form said partially dehydrated product, when (A) is said succinic anhydride the amount of water of reaction that is separated is from about 0.2 to about 0.9 moles of said water of reaction per equivalent of said succinic anhydride, when (A) is said succinic acid the amount of water of reaction that is separated is from about 1.2 to about 1.9 moles of said water of reaction per equivalent of said succinic acid, said partially dehydrated product having a total acid number in the range of about 20 to about 100 mg of KOH/g. 24. A process, comprising: (I) reacting (A) a hydrocarbyl substituted succinic acid or anhydride with (B) a polyol, a polyamine, a hydroxyamine, or a mixture of two or more thereof, to form a first intermediate product comprising: an ester, partial ester or mixture thereof when (B) is a polyol; an amide, imide, salt, amide/salt, partial amide or mixture of two or more thereof when (B) is a polyamine; or an ester, partial ester, amide, partial amide, amide/salt, imide, ester/salt, salt or a mixture of two or more thereof when (B) is a hydroxyamine, a mixture of a polyol and a polyamine, a mixture of a polyol and a hydroxyamine, a mixture of a polyamine and a hydroxyamine, or a mixture of a polyol, a polyamine and a hydroxyamine; the hydrocarbyl substituent of said acid or anhydride having an average of about 8 to about 200 carbon atoms; and (II) heating said first intermediate product at an effective temperature to form a second intermediate product with water of reaction being formed, and separating a portion of said water of reaction from said second intermediate product, when (A) is said succinic anhydride the amount of water of reaction that is separated is from about 0.2 to about 0.9 moles of said water of reaction per equivalent of said succinic anhydride, when (A) is said succinic acid the amount of water of reaction that is separated is from about 1.2 to about 1.9 moles of-said water of reaction per equivalent of said succinic acid, said partially dehydrated product having a total acid number in the range of about 20 to about 100 mg of KOH/g. 25. A concentrate comprising about 10% to about 90% by weight of a normally liquid organic diluent, and the composition of claim 1.