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High-use temperature, lightweight polymer/inorganic nanocomposite materials are described having enhanced thermal stability and performance characteristics. These materials are made possible by new methods for synthesizing composite materials that enhance the thermal stability of the nanocomposite s

High-use temperature, lightweight polymer/inorganic nanocomposite materials are described having enhanced thermal stability and performance characteristics. These materials are made possible by new methods for synthesizing composite materials that enhance the thermal stability of the nanocomposite systems from 100-150째 C. to over 450째 C. These materials and techniques for their formation are enabled at least in part by the use of polar organic phthalonitrile monomers and oligomers that can exfoliate layered phyllosilicates, such as smectite clays, in percentages greater than 10% inorganic by weight. This approach offers a solvent-free direct melt intercalation technique that greatly reduces the cost of processing nanocomposites. Additionally, the use of unmodified phyllosilicates overcomes temperature limitations of prior art, which uses organically-modified layered silicates. The new technology provides hitherto unobtainable thermal stability and performance characteristics, and has numerous applications in the automotive, aerospace, electronic and marine industries.

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What is claimed is: 1. A method for preparing a nanocomposite comprising: dissolving a phthalonitrile monomer; mixing an inorganic material with the dissolved phthalonitrile monomer forming a mixture; polymerizing the phthalonitrile monomer in the mixture to form a polymerized mixture; and adding t

What is claimed is: 1. A method for preparing a nanocomposite comprising: dissolving a phthalonitrile monomer; mixing an inorganic material with the dissolved phthalonitrile monomer forming a mixture; polymerizing the phthalonitrile monomer in the mixture to form a polymerized mixture; and adding the polymerized mixture to a thermoplastic polymer to prepare the nanocomposite. 2. The method of claim 1 wherein the phthalonitrile monomer is selected from the group consisting of bis(3,4,-dicyanophenoxy)4,4'-biphenyl, a bis(3,4,-dicyanophenoxy)4,4'-biphenyl having at least one aliphatic group, a bis(3,4,-dicyanophenoxy)4,4'-biphenyl having at least one amine group, a bis(3,4,-dicyanophenoxy)4,4'-biphenyl having at least one hydroxyl group, and combinations thereof. 3. The method of claim 1 wherein the inorganic material is a hydrophilic silicate. 4. The method of claim 3 wherein the hydrophilic silicate is selected from the group consisting of a layered mica, a clay, a phyllosilicate, a sodium montmorillonite clay, a smectite clay, and combinations thereof. 5. The method of claim 1 wherein the step of dissolving the phthalonitrile monomer comprises melting with heat. 6. The method of claim 1 wherein the step of dissolving comprises contacting the phthalonitrile monomer with a chemical solvent. 7. The method of claim 1 wherein the step of polymerizing comprises adding heat, adding a catalyst, or both heat and a catalyst to the mixture. 8. The method of claim 1 wherein the step of polymerizing comprises adding a high-temperature amine. 9. The method of claim 8 wherein the high-temperature amine is [4-(4-aminophenoxy)phenyl]sulfone. 10. The method of claim 1 wherein the inorganic material is mixed at a ratio of between 0.1% to 40% wgt/wgt with the phthalonitrile monomer. 11. The method of claim 1 further comprising a high temperature curing step after the polymerization step. 12. The method of claim 11 wherein the high temperature curing step comprises heating the mixture to at least 250째 C. for at least one hour. 13. The method of claim 11 wherein the high temperature curing step comprises heating the mixture to at least 300째 C. for at least one hour. 14. The method of claim 1 wherein the thermoplastic polymer is selected from the group consisting of polycarbonate, Nylon, a polyamide, a polyether imide, a polyimide, a polyarylene ether, and combinations thereof. 15. The method of claim 1 further comprising contacting the inorganic material with solvent prior to mixing the inorganic material with the melted phthalonitrile monomer. 16. The method of claim 1 wherein a matrix material comprising a thermoset polymer is added prior to, during or after mixing the inorganic material with the melted phthalonitrile monomer. 17. The method of claim 16 wherein the thermoset polymer is selected from the group consisting of an epoxy, a urethane, a phenolic resin, and mixtures thereof. 18. A nanocomposite prepared by the method of claim 1. 19. A method for preparing smectite clay for making a nanocomposite, said method comprising: the step of mixing a chemical that contains nitrile-groups with said smectite clay to form a mixture; polymerizing the chemical in the mixture to form a polymerized mixture; and adding the polymerized mixture to a thermoplastic polymer wherein the chemical that contains nitrile groups is melted prior to mixing with the smectite clay. 20. The method of claim 19 wherein the chemical that contains nitrile groups is a phthalonitrile monomer or phthalonitrile oligomer. 21. The method of claim 20 further comprising the step of contacting the treated smectite clay with a solvent. 22. The method of claim 20 further comprising the step of adding a matrix material. 23. The method of claim 22 wherein the matrix material is selected from the group consisting of ceramics, epoxys, Nylon, olefins, phenolic resins, polyamides, polyarylene ethers, polycarbonates, polyimides, polyether imides, urethanes, and combinations thereof. 24. The method of claim 20 further comprising the step of curing the mixture at a temperature of at least about 150째 C. for at least two hours. 25. The method of claim 20 further comprising the step of curing the mixture at a temperature of at least about 300째 C. for at least two hours. 26. The method of claim 20 further comprising the step of post curing the mixture at a temperature of at least about 350째 C. for at least two hours. 27. A method for preparing a nanocomposite comprising: dissolving a phthalonitrile monomer; mixing a hydrophilic silicate with the dissolved phthalonitrile monomer forming a mixture; polymerizing the phthalonitrile monomer in the mixture to form a polymerized mixture; and adding the polymerized mixture to a thermoplastic polymer to prepare the nanocomposite.