초록 ▼

Polyhydroxyalkanoate compositions including hot melt adhesive compositions, biodegradable wax compositions, and protective coating compositions are provided and include a low molecular weight polyhydroxyalkanoate, a terminally-modified polyhydroxyalkanoate, or both. The compositions are biodegradab

Polyhydroxyalkanoate compositions including hot melt adhesive compositions, biodegradable wax compositions, and protective coating compositions are provided and include a low molecular weight polyhydroxyalkanoate, a terminally-modified polyhydroxyalkanoate, or both. The compositions are biodegradable and environmentally friendly. Methods of protecting an article, such as a food product like cheese, are also provided and include coating or encapsulating the article with a composition containing a low molecular weight polyhydroxyalkanoate, a terminally-modified polyhydroxyalkanoate, or both.

대표청구항 ▼

What is claimed is: 1. A hot melt adhesive composition comprising: at least one biodegradable polyhydroxyalkanoate having a molecular weight of from about 500 to less than 50,000; optionally comprising at least one tackifying resin; and optionally comprising at least one wax; wherein the hot melt a

What is claimed is: 1. A hot melt adhesive composition comprising: at least one biodegradable polyhydroxyalkanoate having a molecular weight of from about 500 to less than 50,000; optionally comprising at least one tackifying resin; and optionally comprising at least one wax; wherein the hot melt adhesive composition has a viscosity of less than about 100,000 centipoise at 150째 C., wherein the polyhydroxyalkanoate is selected from polymers of 4-hydroxyacids, 5-hydroxyacids, copolymers thereof, or blends thereof. 2. The hot melt adhesive composition of claim 1, further comprising at least one reactive monomeric component. 3. The hot melt adhesive composition of claim 2, wherein said reactive monomer is at least one of an epoxy monomer, an acrylate monomer, a methacrylate monomer, a silicone monomer, a siloxane monomer, a urethane monomer, an isocyanate monomer, an anhydride monomer, an oxime, and combinations thereof. 4. The hot melt adhesive composition of claim 1, wherein said at least one tackifying resin is present in said composition. 5. The hot melt adhesive composition of claim 1, wherein said at least one tackifying resin is present in said composition in an amount of up to about 60 wt % based on the total weight of the composition. 6. The hot melt adhesive composition of claim 1, wherein said at least one wax is present in said composition. 7. The hot melt adhesive composition of claim 1, wherein said at least one wax is present in said composition in an amount of up to about 40 wt % based on the total weight of the composition. 8. A hot melt adhesive composition comprising: at least one biodegradable polyhydroxyalkanoate having a molecular weight from about 1,000 to about 5,000, optionally comprising at least one tackifying resin, and optionally comprising at least one wax, wherein the hot melt adhesive composition has a viscosity of less than about 100,000 centipoise at 150째 C., wherein the polyhydroxyalkanoate is selected from poly(hydroxybutyrate), polyhydroxybutyrate-co-4-hydroxybutyrate, polyhydroxybutyrate-co-3-hydroxyhexanoate, polyhydroxybutyrate-co-3-hydroxyheptanoate, polyhydroxybutyrate-co-3-hydroxyoctanoate, polyhydroxybutyrate-co-3 hydroxypropionate, or polyhydroxybutyrate-4-hydroxyvalerate or wherein the polyhydroxyalkanoate is selected from polymers of 3-hydroxyacids, 4-hydroxyacids, 5-hydroxyacids, copolymers thereof, or blends thereof. 9. The hot melt adhesive composition of claim 8, wherein the molecular weight is from about 1,000 to about 3,000. 10. The hot melt adhesive composition of claim 1, wherein the polyhydroxyalkanoate comprises a mixture of thermally depolymerizable polyhydroxyalkanoates. 11. The hot melt adhesive composition of claim 1, further comprising at least one thermally depolymerizable polymer other than polyhydroxyalkanoate. 12. The hot melt adhesive composition of claim 11, wherein the thermally depolymerizable polymer is selected from polycarbonates, polyolefins, polystyrenes, polyacetals, waxes, or combinations thereof. 13. The hot melt adhesive composition of claim 1, wherein the polyhydroxyalkanoate is dissolved in a solvent or a mixture of solvents. 14. The hot melt adhesive composition of claim 1, wherein said hot melt adhesive composition is biodegradable. 15. The hot melt adhesive composition of claim 2, wherein said hot melt adhesive composition is biodegradable. 16. An article comprising two components adhered together by the hot melt adhesive composition of claim 1. 17. An article comprising two components each having a respective surface, and wherein the respective surface of the two components are adhered together with the hot melt adhesive composition of claim 1. 18. A method of adhering two components together comprising: providing two components; and applying the hot melt adhesive composition of claim 1 to said two components to adhere said two components together. 19. A method of adhering two components together comprising: providing two components; applying the hot melt adhesive composition of claim 1 to at least one of said two components; and contacting one of said two components with the other of said two components such that said hot melt adhesive composition is between said two components. 20. A hot melt adhesive composition comprising: at least one biodegradable polyhydroxyalkanoate having a molecular weight of from about 500 to less than 50,000, optionally comprising at least one tackifying resin, and optionally comprising at least one wax, wherein the hot melt adhesive composition has a viscosity of less than about 100,000 centipoise at 150째 C., wherein the polyhydroxyalkanoate is selected from poly(hydroxybutyrate), polyhydroxybutyrate-co-4-hydroxybutyrate, polyhydroxybutyrate-co-3-hydroxyhexanoate, polyhydroxybutyrate-co-3-hydroxyheptanoate, polyhydroxybutyrate-co-3-hydroxyoctanoate, polyhydroxybutyrate-co-3 hydroxypropionate, or polyhydroxybutyrate-4-hydroxyvalerate or wherein the polyhydroxyalkanoate is selected from polymers of 3-hydroxyacids, 4-hydroxyacids, 5-hydroxyacids, copolymers thereof, or blends thereof, and wherein the polyhydroxyalkanoate is terminally modified to have at least one of the terminal end groups selected from: a)--CO--CH═CR9R10; b)--OR11; c)--COOR12, d)--COR13; or e)--O-M+ wherein R9, R10, and R12 which are the same or different, represent saturated or unsaturated hydrocarbon radicals, halo-or hydroxy-substituted radicals, hydroxy radicals, nitrogen-substituted radicals, oxygen-substituted radicals, or a hydrogen atom, and wherein R11 and R13 which are the same or different, represent saturated or unsaturated hydrocarbon radicals, halo-or hydroxy-substituted radicals, hydroxy radicals, nitrogen-substituted radicals, or oxygen-substituted radicals, and M+ is a counterion. 21. The hot melt adhesive composition of claim 20, wherein one of said terminal end groups is--CO--CH═CR9R10. 22. The hot melt adhesive composition of claim 20, wherein one of said terminal end groups is--OR11. 23. The hot melt adhesive composition of claim 20, wherein one of said terminal end groups is--COOR12. 24. The hot melt adhesive composition of claim 20, wherein said polyhydroxyalkanoate has molecular weight of from about 500 to less than 20,000. 25. The hot melt adhesive composition of claim 20, further comprising at least one reactive monomeric component. 26. The hot melt adhesive composition of claim 25, wherein said reactive monomer is at least one of an epoxy monomer, an acrylate monomer, a methacrylate monomer, a silicone monomer, a siloxane monomer, a urethane monomer, an isocyanate monomer, an anhydride monomer, an oxime, and combinations thereof. 27. The hot melt adhesive composition of claim 20, wherein said at least one tackifying resin is present in said composition. 28. The hot melt adhesive composition of claim 20, wherein said at least one tackifying resin is present in said composition in an amount of up to about 60 wt % based on the total weight of the composition. 29. The hot melt adhesive composition of claim 20, wherein said at least one wax is present in said composition. 30. The hot melt adhesive composition of claim 20, wherein said at least one wax is present in said composition in an amount of up to about 40 wt % based on the total weight of the composition. 31. The hot melt adhesive composition of claim 20, wherein the polyhydroxyalkanoate is a polymer of one or more subunits having the chemical formula: {T--[--OCR1R2(CR3R4)nCO--]p }z--Q wherein n is 0 or an integer up to about 100; p is from about 0 to about 100; R1, R2, R3, and R4, which are the same as each other or different from one another, are each independently selected from saturated and unsaturated hydrocarbon radicals, halo-and hydroxy-substituted radicals, hydroxy radicals, halogen radicals, nitrogen-substituted radicals, oxygen-substituted radicals, or hydrogen atoms; T is selected from hydrogen, an alkyl, aryl, alkaryl, or aralkyl group containing from about 1 to about 20 carbon atoms, or an R'"COO carboxylate group wherein R'" is an aliphatic or aromatic hydrocarbon radical containing from about 1 to about 20 carbon atoms; and Q is selected from: a hydroxy radical or an OR" radical wherein R" is a substituted or unsubstituted alkyl, aryl, alkaryl, or aralkyl radical containing from 1 to about 20 carbon atoms; OAOH; OAOOC(CH2)yCHROH; OAO{OC(CH2)yCHRO}xH; or B; wherein each R is independently selected from hydrogen, a saturated alkyl group having from about 1 to about 16 carbon atoms, an unsaturated alkyl group having from about 2 to about 16 carbon atoms, or mixtures thereof; A is (CH2)m or (CH2CHR'O) m, where m is from about 1 to about 50 and R' is hydrogen or methyl; x is from about 2 to about 50; y is from 0 to about 3; and B is selected from: trimethylol propane when z is 1, 2, 3 or a mixture of 1, 2, and/or 3, glycerol when z is 1, 2, 3 or a mixture of 1, 2, and/or 3, triethanolamine when z is 1, 2, 3 or a mixture of 1, 2, and/or 3, or sucrose when z is 1 to p where p is the number of free hydroxyl groups or derivatives present in said compound, and wherein the number average molecular weight of the compound is at least about 500. 32. The hot melt adhesive composition of claim 20, wherein the polyhydroxyalkanoate is selected from poly(hydroxybutyrate), polyhydroxybutyrate-co-hydroxyvalerate, polyhydroxybutyrate-co-4-hydroxybutyrate, polyhydroxybutyrate-co-3-hydroxyhexanoate, polyhydroxybutyrate-co-3-hydroxyheptanoate, or polyhydroxybutyrate-co-3-hydroxyoctanoate. 33. The hot melt adhesive composition of claim 20, wherein the polyhydroxyalkanoate comprises a monomer or a polymer selected from the group consisting of 3-hydroxyacids, 4-hydroxyacids, 5-hydroxyacids, copolymers thereof, and blends thereof. 34. The hot melt adhesive composition of claim 20, wherein the polyhydroxyalkanoate comprises a mixture of thermally depolymerizable polyhydroxyalkanoates. 35. The hot melt adhesive composition of claim 20, further comprising at least one thermally depolymerizable polymer other than polyhydroxyalkanoate. 36. The hot melt adhesive composition of claim 25, wherein the thermally depolymerizable polymer is selected from polycarbonates, polyolefins, polystyrenes, polyacetals, waxes, or combinations thereof. 37. The hot melt adhesive composition of claim 20, wherein the polyhydroxyalkanoate is dissolved in a solvent or a mixture of solvents. 38. The hot melt adhesive composition of claim 20, wherein said hot melt adhesive composition is biodegradable. 39. The hot melt adhesive composition of claim 21, wherein said hot melt adhesive composition is biodegradable. 40. An article comprising two components adhered together by the hot melt adhesive composition of claim 20. 41. An article comprising two components each having a respective surface, and wherein the respective surfaces of the two components are adhered together with the hot melt adhesive composition of claim 20. 42. A method of adhering two components together comprising: providing two components; and applying the hot melt adhesive composition of claim 20 to said two components to adhere said two components together. 43. A method of adhering two components together comprising: providing two components; applying the hot melt adhesive composition of claim 20 to at least one of said two components; and contacting one of said two components with the other of said two components such that said hot melt adhesive composition is between said two components. 44. The hot melt adhesive composition of claim 1, wherein said polyhydroxyalkanoate is poly-4-hydroxybutyrate. 45. The hot melt adhesive composition of claim 20, wherein said polyhydroxyalkanoate is poly(3-hydroxybutyrate). 46. The hot melt adhesive composition of claim 4, wherein said tackifying resin is an aliphatic C5 resin, a polyterpene resin, a phenolic modified terpene resin, a hydrogenated resin, a mixed aliphatic-aromatic resin, a rosin ester, a rosin acid, a hydrogenated rosin ester, and a hydrogenated rosin acid. 47. The hot melt adhesive composition of claim 46, wherein said tackifying resin is present in an amount of from 10 wt % to 50 wt % by weight of the hot melt adhesive composition. 48. The hot melt adhesive composition of claim 6, wherein said wax is a paraffin wax, microcrystalline wax, Fischer-Tropsch wax, an oxidized Fisher-Tropsch wax, a synthetic high melting point wax, a hydroxy stearamide wax, a fatty amide wax, or a combination thereof. 49. The hot melt adhesive composition of claim 6, wherein said wax is a high density low molecular weight polyethylene wax, a by-product polyethylene wax, or a combination thereof. 50. The hot melt adhesive of claim 1, wherein said hot melt adhesive consists essentially of said biodegradable polyhydroxyalkanoate. 51. The hot melt adhesive of claim 20, wherein said hot melt adhesive consists essentially of said biodegradable polyhydroxyalkanoate. 52. The hot melt adhesive composition of claim 20, wherein one of said terminal end groups is--COR13. 53. The hot melt adhesive composition of claim 20, wherein one of said terminal end groups is--O-M+. 54. The hot melt adhesive composition of claim 20, wherein one of said terminal end groups is--COOR12 wherein R12 represents saturated or unsaturated hydrocarbon radicals, halo-or hydroxy-substituted radicals, hydroxy radicals, nitrogen-substituted radicals, or oxygen-substituted radicals.