초록 ▼

The invention provides a device for selective molecular recognition, the device comprising a sensing portion, wherein said sensing portion includes a substrate having coated thereon a layer comprising a hyperbranched compound having: (1) a polymer backbone portion that is at least partly randomly

The invention provides a device for selective molecular recognition, the device comprising a sensing portion, wherein said sensing portion includes a substrate having coated thereon a layer comprising a hyperbranched compound having: (1) a polymer backbone portion that is at least partly randomly branched; (2) at least one pendant group extending from the polymer backbone portion; and (3) at least one halogen substituted alcohol or phenol group substituted at the pendant group(s) of the polymer backbone portion. The compound of the invention preferably has the general formula: wherein A is the hyperbranched backbone portion of the polymer; L and M are independently selected pendant groups of said polymer backbone; X and Y are independently selected halogen substituted alcohol or phenol groups; q and r are independently selected and at least 1; and n is at least 3.

대표청구항 ▼

What is claimed is: 1. A device for selective molecular recognition, said device comprising a sensing portion, wherein said sensing portion includes a substrate having coated thereon a layer, said layer comprising a hyperbranched compound having: (1) a polymer backbone portion that is at least part

What is claimed is: 1. A device for selective molecular recognition, said device comprising a sensing portion, wherein said sensing portion includes a substrate having coated thereon a layer, said layer comprising a hyperbranched compound having: (1) a polymer backbone portion that is at least partly randomly branched; (2) at least one pendant group extending from the backbone portion; and (3) at least one halogen substituted alcohol or phenol group substituted at the pendant group(s) of the polymer backbone. 2. The device of claim 1 wherein said substrate is a surface acoustic wave (SAW) substrate. 3. The device of claim 1 wherein said compound has the general formula: wherein A is the hyperbranched backbone portion of the polymer; L and M are independently selected pendant groups of said polymer backbone; X and Y are independently selected halogen substituted alcohol or phenol groups; q and r are at least 1 and independently selected; and n is at least 3. 4. The device of claim 3 wherein A is composed of units selected from the group consisting of silicon atoms, carbon atoms, siloxane, carbosilane, silylene moieties, or a combination thereof. 5. The device of claim 3 wherein A is composed of units selected from the group consisting of Si-alkylene, Si-arylene, and--Si-alkenylene. 6. The device of claim 3 wherein: A is selected from the group consisting of--Si--(CH2 )n--, where n=1-3;--Si--(CH(CH2C6H5))--; and Si--(CH2(C═CH2)CH2)--; L and M are independently selected allyl or propylenephenylene groups; and X and Y are hexafluoroisopropanol groups. 7. The device of claim 3 wherein L and M are independently selected from the group consisting of-alkylene-Si-(alkenylene)3 and-alkylene-Si-(alkylene-arylene)3. 8. The device of claim 1 wherein said layer is deposited on said substrate by a laser-based coating technique. 9. A method of detecting the molecules of a hydrogen bond accepting vapor comprising the steps of: (a) contacting the molecules of said vapor with a device comprising a sensing portion, wherein said sensing portion includes a substrate having coated thereon a layer, said layer comprising a hyperbranched compound having: (1) a polymer backbone portion that is at least partly randomly branched; (2) at least one pendant group extending from the polymer backbone portion; and (3) at least one halogen substituted alcohol or phenol group substituted at the pendant group(s) of the polymer backbone portion, (b) collecting said molecules on said layer, wherein said molecules alter a specific physical property of said layer; and (c) detecting the amount of change in said physical property from before said contacting step (a) and after said collecting step (b). 10. The method of claim 9 wherein said substrate is a surface acoustic wave (SAW) substrate. 11. The method of claim 9 wherein said compound has the general formula: wherein A is the hyperbranched backbone portion of the polymer; L and M are independently selected pendant groups of said polymer backbone; X and Y are independently selected halogen substituted alcohol or phenol groups; q and r are at least 1 and independently selected; and n is at least 3. 12. The method of claim 11 wherein A is composed of units selected from the group consisting of silicon atoms, carbon atoms, siloxane, carbosilane, silylene moieties, and combinations thereof. 13. The method of claim 11 wherein A is composed of units selected from the group consisting of Si-alkylene, Si-arylene, or--Si-alkenylene. 14. The method of claim 11 wherein: A is selected from the group consisting of--Si--(CH2 )n--, where n=1-3;--Si--(CH(CH2C6H5))--; and Si--(CH2(C═CH2)CH2)--; L and M are independently selected allyl or propylenephenylene groups; and X and Y are hexafluoroisopropanol groups. 15. The method of claim 11 wherein L and M are independently selected from the group consisting of-alkylene-Si-(alkenylene)3 and-alkylene-Si-(alkylene-arylene)3.