Interpenetrating polymer networks using blocked polyurethane/polyurea prepolymers for golf ball layers
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
A63B-037/12
A63B-037/00
C08L-063/00
C08L-075/02
C08L-075/00
출원번호
US-0900459
(2004-07-28)
발명자
/ 주소
Kuntimaddi,Manjari
Wu,Shenshen
Rajagopalan,Murali
출원인 / 주소
Acushnet Company
대리인 / 주소
Bingham McCutchen LLP
인용정보
피인용 횟수 :
13인용 특허 :
50
초록▼
The present invention is directed to a method of forming a golf ball that contains an interpenetrating polymer network, or IPN, which includes at least two polymeric systems, in one or more of the layers. The first polymeric system may include a polyurethane-based or polyurea-based system having blo
The present invention is directed to a method of forming a golf ball that contains an interpenetrating polymer network, or IPN, which includes at least two polymeric systems, in one or more of the layers. The first polymeric system may include a polyurethane-based or polyurea-based system having blocked isocyanate groups and the second polymeric system may include an epoxy-based or acrylic-based system, wherein the two systems are polymerized or cured simultaneously or sequentially to form an IPN.
대표청구항▼
What is claimed is: 1. A golf ball comprising at least one layer formed from an interpenetrating polymer network comprising: a first polymeric system comprising a polyurea prepolymer cured with a first curing agent, wherein the prepolymer comprises an isocyanate having terminal isocyanate groups, a
What is claimed is: 1. A golf ball comprising at least one layer formed from an interpenetrating polymer network comprising: a first polymeric system comprising a polyurea prepolymer cured with a first curing agent, wherein the prepolymer comprises an isocyanate having terminal isocyanate groups, a blocking agent, and a polyamine; and a second polymeric system comprising an epoxy resin and a second curing agent. 2. The golf ball of claim 1, wherein the blocking agent is selected from the group consisting of linear and branched alcohols; phenols and phenol derivatives; oximes; lactams; lactones; β-dicarbonyl compounds; hydroxamic acid esters; bisulfite addition compounds; hydroxylamines; esters of p-hydroxybenzoic acid; N-hydroxyphthalimide; N-hydroxysuccinimide; triazoles; substituted imidazolines; tetrahydropyrimidines; caprolactones; and mixtures thereof. 3. The golf ball of claim 2, wherein the blocking agent is selected from the group consisting of phenols, branched alcohols, methyl ethyl ketoxime, ε-caprolactam, ε-caprolactone, and mixtures thereof. 4. The golf ball of claim 1, wherein the second curing agent is selected from the group consisting of anhydrides, Lewis bases, amines, amides, Lewis acids, and mixtures thereof. 5. The golf ball of claim 1, wherein at least about 80 percent of the terminal isocyanate radicals groups are blocked. 6. The golf ball of claim 5, wherein at least about 95 percent or more of the terminal isocyanate groups are blocked. 7. The golf ball of claim 1, wherein the at least one layer comprises a cover layer. 8. The golf ball of claim 7, wherein the cover layer comprises an inner cover layer and an outer cover layer. 9. The golf ball of claim 8, wherein the inner cover layer is formed from the interpenetrating polymer network. 10. The golf ball of claim 8, wherein the outer cover layer is formed from the interpenetrating polymer network. 11. A golf ball comprising a core and a cover, wherein a portion of the golf ball is formed from an interpenetrating polymer network comprising: a first polymeric system comprising an isocyanate having terminal isocyanate groups, an amine-terminated component, and a blocked, delayed action curative; and a second polymeric system comprising an epoxy resin and a curing agent. 12. The golf ball of claim 11, wherein the curing agent is selected from the group consisting of anhydrides, Lewis bases, amines, amides, Lewis acids, and mixtures thereof. 13. The golf ball of claim 11, wherein the blocked delayed action amine curative comprises methylene dianiline and sodium chloride. 14. The golf ball of claim 13, wherein the blocked delayed action amine curative has a deblocking temperature of about 175° F. to about 350° F. 15. The golf ball of claim 11, wherein at least about 95 percent or more of the terminal isocyanate groups are blocked. 16. The golf ball of claim 11, wherein at least about 97 percent or more of the terminal isocyanate groups are blocked. 17. The golf ball of claim 11, wherein the portion comprises the cover.
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이 특허에 인용된 특허 (50)
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Werner Todd A. (11515 - 41st Ave. North Plymouth MN 55441), Interpenetrating polymer network of blocked urethane prepolymer, polyol, epoxy resin and anhydride.
Hill Gregory A. (Ponte Vedra Beach FL) Frisch Kurt C. (Grosse Ile MI) Sendijarevic Vahid (Troy MI) Wong Shaio-Wen (St. Clair Shores MI), Interpenetrating polymer networks for contact lens production.
Cavallaro Christopher (Attleboro MA) Rajagopsian Murali (South Darmouth MA) Boehm Herbert C. (Norwell MA) Harris Kevin M. (New Bedford MA), Multilayer golf ball.
Sorathia Usman A. (Arnold MD) Yeager William L. (Queen Anne MD) Dapp Timothy L. (Bowie MD), Polyurethane-epoxy interpenetrating polymer network acoustic damping material.
Pater Ruth H. (Yorktown VA) Hansen Marion G. (Knoxville TN), Process for controlling morphology and improving thermal-mechanical performance of high performance interpenetrating and.
Zijderveld Johannes M. (Breda BEX) Scheerlinck Philippe M. (Diechem BEX) Berghmans Hugo A. A. (Heverlee-Leuven BEX), Process for preparation of stable interpenetrating polymer blends, comprising a poly(vinyl aromatic) polymer phase and a.
Perez Mario A. ; Ylitalo David A. ; Clausen Thomas M. ; DeVoe Robert J. ; Kinzer Kevin E. ; Swan Michael D., Semi-interpenetrating polymer networks of epoxy and polyolefin resins, methods therefor, and uses thereof.
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