Foamed cement compositions, additives, and associated methods
원문보기
IPC분류정보
국가/구분
United States(US) Patent
등록
국제특허분류(IPC7판)
E21B-033/13
E21B-033/138
출원번호
US-0132803
(2005-05-19)
등록번호
US-7255170
(2007-08-14)
발명자
/ 주소
Chatterji,Jiten
Brenneis,D. Chad
King,Bobby J.
Cromwell,Roger S.
Gray,Dennis W.
출원인 / 주소
Halliburton Energy Services, Inc.
대리인 / 주소
Fletcher Yoder
인용정보
피인용 횟수 :
9인용 특허 :
43
초록▼
Exemplary embodiments relate to cementing operations and, more particularly, to foamed cement compositions, foaming and stabilizing additives, and associated methods. A foaming and stabilizing additive, that comprises a mixture of an alkali salt of an alkyl ether sulfate surfactant, wherein the alka
Exemplary embodiments relate to cementing operations and, more particularly, to foamed cement compositions, foaming and stabilizing additives, and associated methods. A foaming and stabilizing additive, that comprises a mixture of an alkali salt of an alkyl ether sulfate surfactant, wherein the alkali salt of the alkyl ether sulfate surfactant comprises a mixture of an alkali salt of a C6-10 alkyl ether sulfate surfactant, and an alkali salt of a C2-4 alkyl ether sulfate surfactant, an alkyl or alkene amidopropyl betaine surfactant, an alkyl or alkene amidopropyl dimethylamine oxide surfactant, sodium chloride, and water, is provided. Also provided are foamed cement compositions that comprise the foaming and stabilizing additive, and associated methods.
대표청구항▼
What is claimed is: 1. A method of cementing, comprising: providing a foamed cement composition comprising: a hydraulic cement; water; a gas; and a foaming and stabilizing additive comprising a mixture of an alkali salt of an alkyl ether sulfate surfactant, wherein the alkali salt of the alkyl ethe
What is claimed is: 1. A method of cementing, comprising: providing a foamed cement composition comprising: a hydraulic cement; water; a gas; and a foaming and stabilizing additive comprising a mixture of an alkali salt of an alkyl ether sulfate surfactant, wherein the alkali salt of the alkyl ether sulfate surfactant comprises a mixture of an alkali salt of a C6-10 alkyl ether sulfate surfactant, and an alkali salt of a C2-4 alkyl ether sulfate surfactant, an alkyl or alkene amidopropyl betaine surfactant having the formula R--CONHCH2CH2CH2N+(CH3)2 CH2CO2, wherein R is a decyl, a cocoyl, a lauryl, a cetyl, or an oleyl radical, an alkyl or alkene amidopropyl dimethylamine oxide surfactant having the formula R--CONHCH2CH2CH2N+(CH3)2 O-, wherein R is a decyl, a cocoyl, a lauryl, a cetyl, or an oleyl radical, sodium chloride, and water; placing the foamed cement composition in a location to be cemented; and allowing the foamed cement composition to set therein. 2. The method of claim 1 wherein the alkali salt of the alkyl ether sulfate surfactant is a sodium salt, a potassium salt, an ammonium salt, or a combination thereof. 3. The method of claim 1 wherein the alkali salt of the C6-10 alkyl ether sulfate surfactant has in the range of from about 1.5 about 2 moles of ethylene oxide substitution, and wherein the alkali salt of the C2-4 alkyl ether sulfate surfactant has in the range of from about 1.8 about 2.5 moles of ethylene oxide substitution. 4. The method of claim 1 wherein the alkali salt of the C2-4 alkyl ether sulfate surfactant comprises an alkali salt of a C4 alkyl ether sulfate surfactant. 5. The method of claim 1 wherein the alkali salt of the alkyl ether sulfate surfactant further comprises an ammonium sulfate. 6. The method of claim 1 wherein the alkali salt of the alkyl ether sulfate surfactant is present in the foaming and stabilizing additive in an amount in the range of from about 35% to about 45% by weight of the foaming and stabilizing additive, wherein the alkyl or alkene amidoproply betaine surfactant is present in the foaming and stabilizing additive in an amount in the range of from about 7.5% to about 12% by weight of the foaming and stabilizing additive, wherein the alkyl or alkene amidopropyl dimethylamine oxide surfactant is present in the foaming and stabilizing additive in an amount in the range of from about 1% to about 5% by weight of the foaming and stabilizing additive, wherein the water in the foaming and stabilizing additive is present in an amount in the range of from about 35% to about 50% by weight of the foaming and stabilizing additive, and wherein the sodium chloride is present in an amount in the range of from about 35% to about 50% by weight of the foaming and stabilizing additive. 7. The method of claim 1 wherein the alkali salt of the alkyl ether sulfate surfactant comprises an ammonium salt of a C6-10 alkyl ether sulfate surfactant in an amount in the range of from about 65% to about 90% by weight of the alkali salt of the alkyl ether sulfate surfactant, the ammonium salt of the C6-10 alkyl ether sulfate surfactant having in range of from about 1.5 moles to about 2 moles of ethylene oxide substitution; and ammonium salt of a C4 alkyl ether sulfate surfactant in an amount in the range of from about 20% to about 35% by weight of the alkali salt of the alkyl ether sulfate surfactant, the ammonium salt of the C4 alkyl ether sulfate surfactant having in range of from about 1.8 moles to about 2.5 moles of ethylene oxide substitution; and ammonium sulfate in an amount in the range of from about 0.1% to about 1.5% by weight of the alkali salt of the alkyl ether sulfate surfactant. 8. The method of claim 1 wherein the location to be cementing is above ground or a portion of a subterranean formation. 9. The method of claim 1 wherein the location comprises an annulus between a pipe string and the subterranean formation. 10. A method of cementing, comprising: introducing a foamed cement composition into a subterranean formation, the foamed cement composition comprising a hydraulic cement, water, a gas, and a foaming and stabilizing additive comprising a mixture of: an alkali salt of an alkyl ether sulfate surfactant, wherein the alkali salt of the alkyl ether sulfate surfactant comprises a mixture of an alkali salt of a C6-10 alkyl ether sulfate surfactant, and an alkali salt of a C2-4 alkyl ether sulfate surfactant; an alkyl or alkene amidopropl betaine surfactant having the formula R--CONHCH2CH2CH2N+(CH3)2CH 2CO2, wherein R is a decyl, a cocoyl, a lauryl, a cetyl, or an oleyl radical; an alkyl or alkene amidopropyl dimethylamine oxide surfactant having the formula R--CONHCH2CH2CH2N+(CH3)2 O-, wherein R is a decyl, a cocoyl, a lauryl, a cetyl, or an oleyl radical; sodium chloride; and water. 11. The method of claim 10 comprising allowing the foamed cement composition to set in the subterranean formation. 12. The method of claim 10 wherein the hydraulic cement comprises at least one of the following; a Portland cement; a pozzolana cement; a gypsum cement; a high alumina content cement; a slag cement; or a silica cement. 13. The method of claim 10 wherein the water in the foamed cement composition comprises at least one of the following: freshwater; saltwater; a brine; or seawater. 14. The method of claim 10 wherein gas comprises at least one of the following: air or nitrogen. 15. The method of claim 10 wherein the foaming and stabilizing additive is present in the foamed cement composition in an amount in the range of from about 0.8% to about 10% by volume of the water in the foamed cement composition. 16. The method of claim 10 wherein the alkali salt of the alkyl ether sulfate surfactant is a sodium salt, a potassium salt, an ammonium salt, or a combination thereof. 17. The method of claim 10 wherein the alkali salt of the C6-10 alkyl ether sulfate surfactant has in the range of from about 1.5 to about 2 moles of ethylene oxide substitution, and wherein the alkali salt of the C2-4 alkyl ether sulfate surfactant has in the range of from about 1.8 to about 2.5 moles of ethylene oxide substitution. 18. The method of claim 10 wherein the alkali salt of the C2-4 alkyl ether sulfate surfactant comprises an alkali salt of a C4 alkyl ether sulfate surfactant. 19. The method of claim 10 wherein the alkali salt of the alkyl ether sulfate surfactant further comprises an ammonium sulfate. 20. The method of claim 10 wherein the alkali salt of the alkyl ether sulfate surfactant is present in the foaming and stabilizing additive in an amount in the range of from about 35% to about 45% by weight of the foaming and stabilizing additive, wherein the alkyl or alkene amidopropyl betaine surfactant is present in the foaming and stabilizing additive in an amount in the range of from about 7.5% to about 12% by weight of the foaming and stabilizing additive, wherein the alkyl or alkene amidopropyl dimethylamine oxide surfactant is present in the foaming and stabilizing additive in an amount in the range of from about 1% to about 5% by weight of the foaming and stabilizing additive, wherein the water in the foaming and stabilizing additive is present in an amount in the range of from about 35% to about 50% by weight of the foaming and stabilizing additive, and wherein the sodium chloride is present in an amount in the range of from about 35% to about 50% by weight of the foaming and stabilizing additive. 21. The method of claim 10 wherein the alkali salt of the alkyl ether sulfate surfactant comprises an ammonium salt of a C6-10 alkyl ether sulfate surfactant in an amount in the range of from about 65% to about 90% by weight of the alkali salt of the alkyl ether sulfate surfactant, the ammonium salt of the C6-10 alkyl ether sulfate surfactant having in range of from about 1.5 moles to about 2 moles of ethylene oxide substitution; an ammonium salt of a C4 alkyl ether sulfate surfactant in an amount in the range of from about 20% to about 35% by weight of the alkali salt of the alkyl ether sulfate surfactant, the ammonium salt of the C4 alkyl ether sulfate surfactant having in range of from about 1.8 moles to about 2.5 moles of ethylene oxide substitution; and ammonium sulfate in an amount in the range of from 0.1% to about 1.5% by weight of the alkali salt of the alkyl ether sulfate surfactant. 22. The method of claim 10 wherein introducing the cement composition into the formation comprises introducing the cement composition into an annulus between a pipe string and the subterranean formation. 23. The method of claim 22 comprising allowing the cement composition to set in the annulus.
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