A process for the production of a reaction product including a carbon containing compound. The process includes providing a film of a fuel source including at least one organic compound on a wall of a reactor, contacting the fuel source with a source of oxygen, forming a vaporized mixture of fuel an
A process for the production of a reaction product including a carbon containing compound. The process includes providing a film of a fuel source including at least one organic compound on a wall of a reactor, contacting the fuel source with a source of oxygen, forming a vaporized mixture of fuel and oxygen, and contacting the vaporized mixture of fuel and oxygen with a catalyst under conditions effective to produce a reaction product including a carbon containing compound. Preferred products include α-olefins and synthesis gas. A preferred catalyst is a supported metal catalyst, preferably including rhodium, platinum, and mixtures thereof.
대표청구항▼
We claim: 1. A process for the production of a compound comprising carbon, the process comprising providing a fuel source comprising at least one organic compound to a reactor, forming a film of the fuel source on a wall of the reactor, providing a source of oxygen comprising molecular oxygen to th
We claim: 1. A process for the production of a compound comprising carbon, the process comprising providing a fuel source comprising at least one organic compound to a reactor, forming a film of the fuel source on a wall of the reactor, providing a source of oxygen comprising molecular oxygen to the reactor, contacting the fuel source with the source of oxygen, forming a vaporized mixture of fuel and oxygen, then contacting the vaporized mixture of fuel and oxygen with a catalyst under conditions effective to produce a reaction product comprising a carbon containing compound. 2. The process of claim 1 wherein the process is carried out under autothermal conditions. 3. The process of claim 1 wherein the vaporized mixture of fuel and oxygen contacts the catalyst for at least about 5 milliseconds. 4. The process of claim 3 wherein the vaporized mixture of fuel and oxygen contacts the catalyst for no greater than about 25 milliseconds. 5. The process of claim 1 wherein the organic compound is a liquid hydrocarbon with at least 6 carbon atoms. 6. The process of claim 5 wherein the liquid hydrocarbon is a C6-C30 hydrocarbon. 7. The process of claim 1 wherein the process is carried out without adding water. 8. The process of claim 1 wherein the catalyst comprises a metal selected from the group consisting of a Group VIII metal, a Group IB metal, tin, and combinations thereof. 9. The process of claim 8 wherein the metal comprises rhodium. 10. The process of claim 1 wherein the source of oxygen comprises air. 11. The process of claim 1 further comprising contacting the fuel source and source of oxygen with water. 12. A process for the production of an alkene, the process comprising: providing a fuel source comprising at least one liquid hydrocarbon; providing at least one source of oxygen comprising molecular oxygen; delivering the fuel source to a reactor comprising a wall; forming a film of the fuel source on the reactor wall; contacting to fuel source with the source of oxygen; forming a vaporized mixture of fuel and oxygen; and contacting the vaporized mixture of fuel and oxygen with a catalyst under conditions effective to produce a reaction product comprising an alkene. 13. The process of claim 12 wherein the process is carried out under autothermal conditions. 14. The process of claim 12 wherein the vaporized mixture of fuel and oxygen contacts the catalyst for at least about 5 milliseconds. 15. The process of claim 14 wherein the vaporized mixture of fuel and oxygen contacts the catalyst for no greater than about 25 milliseconds. 16. The process of claim 12 wherein the liquid hydrocarbon comprises at least 6 carbon atoms. 17. The process of claim 12 wherein the alkene is ethylene. 18. The process of claim 17 wherein at least about 35 percent of the fuel source that is reacted forms ethylene. 19. The process of claim 12 wherein the alkene is propylene. 20. The process of claim 19 wherein at least about 15 percent of the fuel source that is reacted fours propylene. 21. The process of claim 20 wherein no greater than about 50 percent of the fuel source that is reacted forms propylene. 22. The process of claim 12 wherein the catalyst comprises a metal disposed on a support, wherein the metal is selected from the group consisting of a Group VIII metal, a Group IB metal, tin, and combinations thereof. 23. The process of claim 22 wherein the metal is selected from the group consisting of rhodium, platinum, and mixtures thereof. 24. The process of claim 23 wherein the catalyst further comprises tin. 25. The process of claim 22 wherein the support is a ceramic foam monolith. 26. The process of claim 12 wherein carbon is present in the fuel source in an atomic ratio of at least about 0.8:1 carbon to oxygen. 27. The process of claim 6 wherein carbon is present in the fuel source in an atomic ratio of no greater than about 5:1 carbon to oxygen. 28. The process of claim 12 wherein the source of oxygen comprises air. 29. The process of claim 12 wherein the source of oxygen is pure O2. 30. The process of claim 12 further comprising contacting the fuel source and source of oxygen with water. 31. The process of claim 12 wherein the vaporized mixture of fuel and oxygen contacts the catalyst at a flow rate of at least about 0.5 standard liters per minute. 32. The process of claim 31 wherein vaporized mixture of fuel and oxygen contacts the catalyst at a flow rate of no greater than about 20 standard liters per minute. 33. The process of claim 12 wherein the fuel source and the source of oxygen are vaporized and mixed substantially simultaneously. 34. The process of claim 33 wherein the mixture of fuel and oxygen is heated to a temperature of at least about 25째 C. above the boiling point of the fuel source prior to contacting the catalyst. 35. The process of claim 34 wherein the fuel source and the source of oxygen are heated to a temperature of no greater than about 150째 C. above the boiling point of the fuel source prior to contacting the catalyst. 36. A process for the production of an α-olefin, the process comprising: providing a fuel source comprising at least one liquid n-alkane; providing at least one source of oxygen comprising molecular oxygen; delivering the fuel source to a reactor comprising a wall; forming a film of the fuel source on the reactor wall; contacting the fuel source with the source of oxygen; forming a vaporized mixture of fuel and oxygen; and contacting the vaporized mixture of fuel and oxygen with a catalyst under conditions effective to produce a reaction product comprising an α-olefin. 37. The process of claim 36 wherein the process is carried out under autothermal conditions. 38. The process of claim 36 wherein the vaporized mixture of fuel and oxygen contacts the catalyst for at least about 5 milliseconds. 39. The process of claim 38 wherein the vaporized mixture of fuel and oxygen contacts the catalyst for no greater than about 25 milliseconds. 40. The process of claim 36 wherein the n-alkane comprises at least 6 carbon atoms. 41. The process of claim 36 wherein at least about 20 percent of the fuel source that is reacted forms an α-olefin. 42. The process of claim 41 wherein about 100 percent of the fuel source that is reacted forms an α-olefin. 43. The process of claim 36 wherein the catalyst comprises a metal disposed on a support, wherein the metal is selected from the group consisting of a Group VIII metal, a Group IB metal, tin, and combinations thereof. 44. The process of claim 43 wherein the metal is selected from the group consisting of rhodium, platinum, and mixtures thereof. 45. The process of claim 44 wherein the catalyst further comprises tin. 46. The process of claim 43 wherein the support is a ceramic foam monolith. 47. The process of claim 36 wherein carbon is present in the fuel source in an atomic ratio of at least about 2:1 carbon to oxygen. 48. The process of claim 47 wherein carbon is present in the fuel source in an atomic ratio of no greater than about 10:1 carton atom to oxygen atom. 49. The process of claim 36 wherein the source of oxygen comprises air. 50. The process of claim 36 wherein the source of oxygen is pure O2. 51. The process of claim 36 further comprising contacting the fuel source and the source of oxygen with water. 52. The process of claim 36 wherein the vaporized mixture of fuel and oxygen contacts the catalyst at a flow rate of at least about 0.5 standard liters per minute. 53. The process of claim 52 wherein the vaporized mixture of fuel and oxygen contacts the catalyst at a flow rate of no greater than about 20 standard liters per minute. 54. The process of claim 36 wherein the fuel source and the source of oxygen are vaporized and mixed substantially simultaneously. 55. The process of claim 54 wherein the mixture of fuel and oxygen are heated to a temperature of at least about 25째 C. above the boiling point of the fuel source prior to contacting the catalyst. 56. The process of claim 55 wherein the fuel source and the source of oxygen are heated to a temperature of no greater than about 150째 C. above the boiling point of the fuel source prior to contacting the catalyst. 57. A process for the production of an alkene, the process comprising: providing a liquid fuel source comprising at least one hydrocarbon; providing at least one source of oxygen comprising molecular oxygen; feeding the liquid fuel source to a wall of a reactor; contacting the liquid fuel source with the source of oxygen; forming a vaporized mixture of fuel and oxygen; and contacting the vaporized mixture of fuel and oxygen with a catalyst under conditions effective to produce a reaction product comprising an alkene. 58. A process for the production of an α-olefin, the process comprising: providing a liquid fuel source comprising at least one n-alkane; providing at least one source of oxygen comprising molecular oxygen; feeding the liquid fuel source to a wall of a reactor; contacting the liquid fuel source with the source of oxygen; forming a vaporized mixture of fuel and oxygen; and contacting the vaporized mixture of fuel and oxygen with a catalyst under conditions effective to produce a reaction product comprising an α-olefin.
연구과제 타임라인
LOADING...
LOADING...
LOADING...
LOADING...
LOADING...
이 특허에 인용된 특허 (46)
Clawson Lawrence G. ; Mitchell William L. ; Bentley Jeffrey M. ; Thijssen Johannes H. J., Apparatus for converting hydrocarbon fuel into hydrogen gas and carbon dioxide.
Hershkowitz Frank ; Deckman Harry W. ; Reynolds Robert P. ; Gonatas Constantine P. ; Fulton John W. ; Schoenman Leonard ; Ito Jack I. ; Koveal Russell J. ; Veluswamy Lavanga R. ; Taylor James H. ; Lo, Face-mixing fluid bed process and apparatus for producing synthesis gas.
Clawson Lawrence G. ; Mitchell William L. ; Bentley Jeffrey M. ; Thijssen Johannes H.J., Method and apparatus for converting hydrocarbon fuel into hydrogen gas and carbon dioxide.
Clawson Lawrence G. ; Mitchell William L. ; Bentley Jeffrey M. ; Thijssen Johannes H. J., Method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide.
Clawson Lawrence G. ; Mitchell William L. ; Bentley Jeffrey M. ; Thijssen Johannes H. J., Method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide.
Clawson Lawrence G. ; Mitchell William L. ; Bentley Jeffrey M. ; Thijssen Johannes H. J., Method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide.
Durante Vincent A. (West Chester PA) Macris Aristides (Media PA) Pitchai Rangasamy (West Chester PA) Verykios Xenophon E. (Patras GRX), Process for catalytically reforming a hydrocarbon feed in the gasoline boiling range.
Heide Helmut (Niederhochstadter Pfad 23 6231 Schwalbach ; Taunus DT) Hoffmann Ulrich (Kronthaler Weg 10 6236 Eschborn ; Niederhochstadt DT) Brotz Gunther (Weisskirchner Str. 6372 Stierstadt ; Taunus , Process for producing catalyst supports or catalyst systems having open pores.
Xenophon Verykios GR, Process for the production of hydrogen and electrical energy from reforming of bio-ethanol with the use of fuel cells and with zero emission of pollutants.
Astbury Christopher J. (London GB2) Griffiths David C. (Surrey GB2) Howard Mark J. (North Humberisde GB2) Reid Ian A. B. (London GB2), Process for the production of mono-olefins.
Font Freide Josephus J. H. M. (Meybridge GB2) Howard Mark J. (Twickenham GB2) Lomas Trevor A. (Langley GB2), Process for the production of mono-olefins.
Font Freide Joseph J. (Weybridge GB2) Howard Mark J. (Twickenham GB2) Lomas Trevor A. (Langley GB2), Process for the production of mono-olefins by the catalytic oxidative dehydrogenation of gaseous paraffinic hydrocarbons.
Sanfilippo Domenico,ITX ; Basini Luca,ITX ; Marchionna Mario,ITX, Process of catalytic partial oxidation of natural gas in order to obtain synthesis gas and formaldehyde.
Green Malcolm L. (Oxford CA GB3) Cheetham Anthony K. (Montecito CA) Vernon Patrick D. (Oxford GB3) Ashcroft Alexander T. (Lancashire ; bot of GB3), Processes for the conversion of methane to synthesis gas.
Allen, Timothy L.; Bryden, Todd R.; Howard, Kevin E.; Lakso, Steven R.; Lebaron, Peter C.; Lovelace, Jamie L.; Serafin, Juliana G.; Wallin, Sten A., Porous body precursors, shaped porous bodies, processes for making them, and end-use products based upon the same.
Bryden, Todd R.; Howard, Kevin E.; LeBaron, Peter C.; Wallin, Sten A., Porous body precursors, shaped porous bodies, processes for making them, and end-use products based upon the same.
Bryden, Todd R.; Howard, Kevin E.; Lebaron, Peter C.; Wallin, Sten A., Porous body precursors, shaped porous bodies, processes for making them, and end-use products based upon the same.
※ AI-Helper는 부적절한 답변을 할 수 있습니다.