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Disclosed are multi-purpose alkali-swellable and alkali soluble associative polymers, which are the polymerization product of a monomer mixture comprising: (a) at least one acidic vinyl monomer; (b) at least one nonionic vinyl monomer; (c) a first associative monomer having a first hydrophobic end g

Disclosed are multi-purpose alkali-swellable and alkali soluble associative polymers, which are the polymerization product of a monomer mixture comprising: (a) at least one acidic vinyl monomer; (b) at least one nonionic vinyl monomer; (c) a first associative monomer having a first hydrophobic end group; (d) a monomer selected from the group consisting of a second associative monomer having a second hydrophobic end, a semihydrophobic monomer and a combination thereof; and, optionally, (e) one or more crosslinking monomers or chain transfer agents. When monomer (d) is an associative monomer, the first and second hydrophobic end groups of monomers (c) and (d) have significantly different hydrophobic and/or steric character from one another. The multi-purpose associative polymers surprisingly provide desirable Theological and aesthetic properties in aqueous media.

대표청구항 ▼

We claim: 1. An associative polymer that is the product of polymerization of a monomer mixture comprising: (a) at least one acidic vinyl monomer or a salt thereof; (b) at least one nonionic vinyl monomer; (c) a first associative monomer having a first hydrophobic end group; (d) at least one monomer

We claim: 1. An associative polymer that is the product of polymerization of a monomer mixture comprising: (a) at least one acidic vinyl monomer or a salt thereof; (b) at least one nonionic vinyl monomer; (c) a first associative monomer having a first hydrophobic end group; (d) at least one monomer selected from a second associative monomer having a second hydrophobic end group, a semihydrophobic monomer, and a combination thereof; and, optionally, (e) a monomer selected from a crosslinking monomer, a chain transfer agent, and a combination thereof; with the proviso that when monomer (d) is a second associative monomer and said semihydrophobic monomer is not present, the first and second hydrophobic end groups of associative monomers (c) and (d) are each selected from a substituted or unsubstituted C22 and C12 linear alkyl, respectively; wherein said first and second associative monomers are selected from at least one monomer of the formula: wherein, each R2 is independently H, methyl,--C(O)OH, or--C(O)OR3; R3 is C1-C30 alkyl; A is--CH2C(O)O--,--C(O)O--,--O--,--CH2O--,--NHC(O)NH--,--C(O)NH--,--Ar--(CE2)z--NHC(O)O--,--Ar--(CE2)z--NHC(O)NH--, or--CH2CH2NHC(O)--; Ar is a divalent aryl; E is H or methyl; z is 0 or 1; k is an integer in the range of 0 to about 30, and m is 0 or 1, with the proviso that when k is 0, m is 0, and when k is in the range of 1 to about 30, m is 1; (R4--O)n is a polyoxyalkylene, which is a homopolymer, a random copolymer, or a block copolymer of C2-C4 oxyalkylene units, wherein R4 is C2H4, C3H6, C4H8, and n is an integer in the range of about 5 to about 250, Y is--R4O--,--R4NH--,--C(O)--,--C(O)NH--,--R4NHC(O)NH--, or--C(O)NHC(O)--; and R5 is a substituted or unsubstituted alkyl selected from a C8-C40 linear alkyl, a C8-C40 branched alkyl, a C8-C40 carbocyclic alkyl, a C2-C40 alkyl-substituted phenyl, an aryl-substituted C2-C40 alkyl, and a C8-C80 complex ester; wherein the R5 alkyl group optionally comprises one or more substituents selected from a hydroxyl group, an alkoxyl group, and a halogen group; and said semihydrophobic monomer is selected from at least one monomer of the formulas: wherein, in each of formulas (IV) and (V), each R6 is independently H, C1-C30 alkyl,--C(O)OH, or--C(O)OR7; R7 is C1-C30 alkyl; A is--CH2C(O)O--,--C(O)O--,--O--,--CH2O--,--NHC(O)NH--,--C(O)NH--,--Ar--(CE2)z--NHC(O)O--,--Ar--(CE2)z--NHC(O)NH--, or--CH2CH2NHC(O)--; Ar is a divalent aryl; E is H or methyl; z is 0 or 1; p is an integer in the range of 0 to about 30, and r is 0 or 1, with the proviso that when p is 0, r is 0, and when p is in the range of 1 to about 30, r is 1; (R8--O)v is a polyoxyalkylene, which is a homopolymer, a random copolymer or a block copolymer of C2-C4 oxyalkylene units, wherein R8 is C2H4, C3H6, C4H8, and v is an integer in the range of about 5 to about 250, R9 is H or C1-C4 alkyl; and D is a C8-C30 unsaturated alkyl or a carboxy-substituted C8-C30 unsaturated alkyl. 2. The polymer of claim 1 wherein the acidic vinyl monomer is selected from a carboxylic acid-containing vinyl monomer, a sulfonic acid-containing vinyl monomer, a phosphonic acid-containing vinyl monomer, and a combination thereof. 3. The polymer of claim 1 wherein the acidic vinyl monomer is acrylic acid, methacrylic acid, styrenesulfonic acid, 2-acrylamido-2-methylpropane sulfonic acid, or a combination thereof. 4. The polymer of claim 1 wherein the salt is selected from an alkali metal salt, an alkaline earth metal salt, an ammonium salt, an alkyl-substituted ammonium salt, and a combination thereof. 5. The polymer of claim 1 wherein the nonionic vinyl monomer is a compound selected from at least one of the following formulas description="In-line Formulae" end="lead"CH2═C(X)Z (I)description="In-line Formulae" end="tail" description="In-line Formulae" end="lead"CH2═CH--OC(O)R (II)description="In-line Formulae" end="tail" wherein, in each of formulas (I) and (II), X is H or methyl; Z is BC(O)OR1,--C(O)NH2,--C(O)NHR1,--C(O)N(R1)2,--C6H4R1,--C6H4OR1,--C6H4Cl,--CN,--NHC(O)CH3,--NHC(O)H2N-(2-pyrrolidonyl), N-caprolactamyl,--C(O)NHC(CH3)3,--C(O)NHCH2CH2--N-ethyleneurea,--SiR3,--C(O)O(CH2)xSiR3,--C(O)NH(CH2)xSiR3, or--(CH2)xSiR3; x is an integer in the range of 1 to about 6; each R is independently C1-C18 alkyl; each R1 is independently C1-C30 alkyl, hydroxy-substituted C1-C30 alkyl, or halogen-substituted C1-C30 alkyl. 6. The polymer of claim 1 wherein the nonionic vinyl monomer is selected from a C1-C8 ester of acrylic acid, a C1-C8 ester of methacrylic acid, and a combination thereof. 7. The polymer of claim 1 wherein the first and second associative monomers each comprise a polymerizable, unsaturated end group, a C8-C40 alkyl hydrophobic end group, and a polyoxyalkylene group disposed between and covalently bonded to the unsaturated end group and the hydrophobic end group. 8. The polymer of claim 7 wherein the polyoxyalkylene group is a homopolymer, a random copolymer, or a block copolymer comprising about 5 to about 250 C2-C4 oxyalkylene units. 9. The polymer of claim 1 wherein the monomer mixture includes at least one semihydrophobic monomer having a polymerizable, unsaturated end group and a polyoxyalkylene group covalently bonded thereto. 10. The polymer of claim 9 wherein the polyoxyalkylene group is a homopolymer, a random copolymer, or a block copolymer comprising about 5 to about 250 C2-C4 oxyalkylene units. 11. The polymer of claim 1 wherein the monomer mixture includes a semihydrophobic monomer having one of the following chemical formulas: description="In-line Formulae" end="lead"CH2═CH--O--(CH2)a--O--(C3 H6O)b--(C2H4O)c--H ordescription="In-line Formulae" end="tail" description="In-line Formulae" end="lead"CH2═CH--CH2--O--(C3H6 O)d--(C2H4O)e--H;description="In-line Formulae" end="tail" wherein a is 2, 3, or 4; b is an integer in the range of 1 to about 10; c is an integer in the range of about 5 to about 50; d is an integer in the range of 1 to about 10; and e is an integer in the range of about 5 to about 50. 12. The polymer of claim 1 wherein the monomer mixture contains at least one cross linking monomer. 13. The polymer of claim 12 wherein the crosslinking monomer is an acrylate ester of a polyol having at least two acrylate ester groups, a methacrylate ester of a polyol having at least two methacrylate ester groups or a combination thereof. 14. The polymer of claim 1 wherein the monomer mixture contains at least one chain transfer agent. 15. The polymer of claim 14 wherein the chain transfer agent is selected from a thio compound, a disulfide compound, a phosphite, a hypophosphite, a haloalkyl compound, and a combination thereof. 16. An associative polymer that is the product of polymerization of a monomer mixture comprising, on a total monomer mixture weight basis: (a) about 10 to about 75 weight percent of at least one acidic vinyl monomer or a salt thereof; (b) about 10 to about 90 weight percent of at least one nonionic vinyl monomer; (c) about 0.1 to about 25 weight percent of a first associative monomer having a first hydrophobic end group; (d) about 0.1 to about 25 weight percent of at least one monomer selected from a second associative monomer having a second hydrophobic end group, a semihydrophobic monomer, and a combination thereof; and, optionally, (e) up to about 20 weight percent of a monomer selected from a crosslinking monomer, a chain transfer agent, and a combination thereof with the proviso that when monomer (d) is a second associative monomer and said semihydrophobic monomer is not present, the first and second hydrophobic end groups of associative monomers (c) and (d) are each selected from a substituted or unsubstituted C22 and C12 linear alkyl, respectively; wherein said first and second associative monomers are selected from at least one monomer of the formula: wherein, each R2 is independently H, methyl,--C(O)OH, or--C(O)OR3; R3 is C1-C30 alkyl; A is--CH2C(O)O--,--C(O)O--,--O--,--CH2O--,--NHC(O)NH--,--C(O)NH--,--Ar--CE2)z--NHC(O)O--,--Ar--(CE2)z--NHC(O)NH--, or--CH2CH2NHC(O)--; Ar is a divalent aryl; E is H or methyl; z is 0 or 1; k is an integer in the range of 0 to about 30, and m is 0 or 1, with the proviso that when k is 0, m is 0, and when k is in the range of 1 to about 30, in is 1; (R4--O)n, is a polyoxyalkylene, which is a homopolymer, a random copolymer, or a block copolymer of C2-C4 oxyalkylene units, wherein R4 is C2H4, C3H6, C4H8, and n is an integer in the range of about 5 to about 250, Y is--R4O--,--R4NH--,--C(O)--,--C(O)NH--,--R4NHC(O)NH--, or--C(O)NHC(O)--; and R5 is a substituted or unsubstituted alkyl selected from a C8-C40 linear alkyl, a C8-C40 branched alkyl, a C8-C40 carbocyclic alkyl, a C2-C40 alkyl-substituted phenyl, an aryl-substituted C2-C40 alkyl, and a C8-C80 complex ester; wherein the R5 alkyl group optionally comprises one or more substituents selected from a hydroxyl group, an alkoxyl group, and a halogen group; and said semihydrophobic monomer is selected from at least one monomer of the formulas: wherein, in each of formulas (IV) and (V), each R6 is independently H, C1-C30 alkyl,--C(O)OH, or--C(O)OR7; R7 is C1-C30 alkyl; A is--CH2C(O)O--,--C(O)O--,--O--,--CH2O--,--NHC(O)NH--,--C(O)NH--,--Ar--(CE2)z--NHC(O)O--,--Ar--(CE2)z--NHC(O)NH--, or--CH2CH2NHC(O)--; Ar is a divalent aryl; E is H or methyl; z is 0 or 1; p is an integer in the range of 0 to about 30, and r is 0 or 1, with the proviso that when p is 0, r is 0, and when p is in the range of 1 to about 30, r is 1; (R8--O)v is a polyoxyalkylene, which is a homopolymer, a random copolymer or a block copolymer of C2-C4 oxyalkylene units, wherein R8 is C2H4, C3H6, C4H8, and v is an integer in the range of about 5 to about 250, R9 is H or C1-C4 alkyl; and D is a C8-C30 unsaturated alkyl or a carboxy-substituted C8-C30 unsaturated alkyl. 17. The polymer of claim 16 wherein the acidic vinyl monomer is selected from a carboxylic acid-containing vinyl monomer, a sulfonic acid-containing vinyl monomer, a phosphonic acid-containing vinyl monomer, and a combination thereof. 18. The polymer of claim 16 wherein the acidic vinyl monomer is acrylic acid, methacrylic acid, styrenesulfonic acid, 2-acrylamido-2-methylpropane sulfonic acid, or a combination thereof. 19. The polymer of claim 16 wherein the salt is selected from an alkali metal salt, an alkaline earth metal salt, an ammonium salt, an alkyl-substituted ammonium salt, and a combination thereof. 20. The polymer of claim 16 wherein the nonionic vinyl monomer is a compound selected from at least one of the following formulas description="In-line Formulae" end="lead"CH2═C(X)Z (I)description="In-line Formulae" end="tail" description="In-line Formulae" end="lead"CH2═CH--OC(O)R (II)description="In-line Formulae" end="tail" wherein, in each of formulas (I) and (II), X is H or methyl; Z is BC(O)OR1,--C(O)NH2,--C(O)NHR1,--C(O)N(R1)2,--C6H4R1,--C6H4OR1,--C6H4Cl,--CN,--NHC(O)CH3,--NHC(O)H, N-(2-pyrrolidonyl), N-caprolactamyl,--C(O)NHC(CH3)3,--C(O)NHCH2CH2--N-ethyleneurea,--SiR3,--C(O)O(CH2)xSiR3,--C(O)NH(CH2)xSiR3, or--(CH2)xSiR3; x is an integer in the range of 1 to about 6; each R is independently C1-C18 alkyl; each R1 is independently C1-C30 alkyl, hydroxy-substituted C1-C30 alkyl, or halogen-substituted C1-C30 alkyl. 21. The polymer of claim 16 wherein the nonionic vinyl monomer is selected from a C1-C8 ester of acrylic acid, a C1-C8 ester of methacrylic acid, and a combination thereof. 22. The polymer of claim 16 wherein the first and second associative monomers each comprise a polymerizable, unsaturated end group, a C8-C40 alkyl hydrophobic end group, and a polyoxyalkylene group disposed between and covalently bonded to the unsaturated end group and the hydrophobic end group. 23. The polymer of claim 22 wherein the polyoxyalkylene group is a homopolymer, a random copolymer, or a block copolymer comprising about 5 to about 250 C2-C4 oxyalkylene units. 24. The polymer of claim 16 wherein the monomer mixture includes at least one semihydrophobic monomer having a polymerizable, unsaturated end group and a polyoxyalkylene group covalently bonded thereto. 25. The polymer of claim 24 wherein the polyoxyalkylene group is a homopolymer, a random copolymer, or a block copolymer comprising about 5 to about 250 C2-C4 oxyalkylene units. 26. The polymer of claim 16 wherein the monomer mixture includes a semihydrophobic monomer having one of the following chemical formulas: description="In-line Formulae" end="lead"CH2═CH--O--(CH2)a--O--(C3 H6O)b--(C2H4O)c--H ordescription="In-line Formulae" end="tail" description="In-line Formulae" end="lead"CH2═CH--CH2--O--(C3H6 O)d--(C2H4O)e--H;description="In-line Formulae" end="tail" wherein a is 2, 3, or 4; b is an integer in the range of 1 to about 10; c is an integer in the range of about 5 to about 50; d is an integer in the range of 1 to about 10; and e is an integer in the range of about 5 to about 50. 27. The polymer of claim 16 wherein the monomer mixture includes about 0.1 to about 2 weight percent of a crosslinking monomer. 28. The polymer of claim 27 wherein the crosslinking monomer is an acrylate ester of a polyol having at least two acrylate ester groups, a methacrylate ester of a polyol having at least two methacrylate ester groups or a combination thereof. 29. The polymer of claim 16 wherein the monomer mixture includes about 0.1 to about 10 weight percent of at least one chain transfer agent. 30. The polymer of claim 29 wherein the chain transfer agent is selected from a thio compound, a disulfide compound, a phosphite, a hypophosphite, a haloalkyl compound, and a combination thereof. 31. An alkali-swellable associative polymer that is the product of polymerization of a monomer mixture comprising, on a total monomer mixture weight basis: (a) about 30 to about 75 weight percent of at least one acidic vinyl monomer or a salt thereof; (b) at least about 25 weight percent, but not more than 60 weight percent of at least one nonionic vinyl monomer; (c) about 0.5 to about 20 weight percent of a first associative monomer having a first hydrophobic end group; (d) about 0.5 to about 20 weight percent of at least one monomer selected from a second associative monomer having a second hydrophobic end group, a semihydrophobic monomer, and a combination thereof; and, optionally, (e) up to about 20 weight percent of a crosslinking monomer; with the proviso that when monomer (d) is a second associative monomer and said semihydrophobic monomer is not present, the first and second hydrophobic end groups of associative monomers (c) and (d) are each selected from a substituted or unsubstituted C22 and C12 linear alkyl, respectively; wherein said first and second associative monomers are selected from at least one monomer of the formula: wherein, each R2 is independently H, methyl,--C(O)OH, or--C(O)OR3; R3 is C1-C30 alkyl; A is--CH2C(O)O--,--C(O)O--,--O--,--CH2O--,--NHC(O)NH--,--C(O)NH--,--Ar--(CE2)z--NHC(O)O--,--Ar--(CE2)z--NHC(O)NH--, or--CH2CH2NHC(O)--; Ar is a divalent aryl; E is H or methyl; z is 0 or 1; k is an integer in the range of 0 to about 30, and m is 0 or 1, with the proviso that when k is 0, m is 0, and when k is in the range of 1 to about 30, m is 1; (R4--O)n is a polyoxyalkylene, which is a homopolymer, a random copolymer, or a block copolymer of C2-C4 oxyalkylene units, wherein R4 is C2H4, C3H6, C4H8, and n is an integer in the range of about 5 to about 250, Y is--R4O--,--R4NH--,--C(O)--,--C(O)NH--,--R4NHC(O)NH--, or--C(O)NHC(O)--; and R5 is a substituted or unsubstituted alkyl selected from a C8-C40 linear alkyl, a C8-C40 branched alkyl, a C8-C40 carbocyclic alkyl, a C2-C40 alkyl-substituted phenyl, an aryl-substituted C2-C40 alkyl, and a C8-C80 complex ester; wherein the R5 alkyl group optionally comprises one or more substituents selected from a hydroxyl group, an alkoxyl group, and a halogen group; and said semihydrophobic monomer is selected from at least one monomer of the formulas; wherein, in each of formulas (IV) and (V), each R6 is independently H, C1-C30 alkyl,--C(O)OH, or--C(O)OR7; R7 is C1-C30 alkyl; A is--CH2C(O)O--,--C(O)O--,--O--,--CH2O--,--NHC(O)NH--,--C(O)NH--,--Ar--(CE2)z--NHC(O)O--,--Ar--(CE2)z--NHC(O)NH--, or--CH2CH2NHC(O)--; Ar is a divalent aryl; E is H or methyl; z is 0 or 1; p is an integer in the range of 0 to about 30, and r is 0 or 1, with the proviso that when p is 0, r is 0, and when p is in the range of 1 to about 30, r is 1; (R8--O)v is a polyoxyalkylene, which is a homopolymer, a random copolymer or a block copolymer of C2-C4 oxyalkylene units, wherein R8 is C2H4, C3H6, C4H8, and v is an integer in the range of about 5 to about 250, R9 is H or C1-C4 alkyl; and D is a C8-C30 unsaturated alkyl or a carboxy-substituted C8-C30 unsaturated alkyl. 32. The polymer of claim 31 wherein the acidic vinyl monomer is selected from a carboxylic acid-containing vinyl monomer, a sulfonic acid-containing vinyl monomer, a phosphonic acid-containing vinyl monomer, and a combination thereof. 33. The polymer of claim 31 wherein the acidic vinyl monomer is acrylic acid, methacrylic acid, styrenesulfonic acid, 2-acrylamido-2-methylpropane sulfonic acid, or a combination thereof. 34. The polymer of claim 31 wherein the salt is selected from an alkali metal salt, an alkaline earth metal salt, an ammonium salt, an alkyl-substituted ammonium salt, and a combination thereof. 35. The polymer of claim 31 wherein the nonionic vinyl monomer is selected from a C1-C8 ester of acrylic acid, a C1-C8 ester of methacrylic acid, and a combination thereof. 36. The polymer of claim 31 wherein the nonionic vinyl monomer is selected from ethyl acrylate, methyl methacrylate, and a combination thereof. 37. The polymer of claim 31 wherein the first and second associative monomers each comprise a polymerizable, unsaturated end group, a C8-C40 alkyl hydrophobic end group, and a polyoxyalkylene group disposed between and covalently bonded to the unsaturated end group and the hydrophobic end group. 38. The polymer of claim 37 wherein the polyoxyalkylene group is a homopolymer, a random copolymer, or a block copolymer comprising about 5 to about 250 C2-C4 oxyalkylene units. 39. The polymer of claim 31 wherein the monomer mixture includes at least one semihydrophobic monomer having a polymerizable, unsaturated end group and a polyoxyalkylene group covalently bonded thereto. 40. The polymer of claim 39 wherein the polyoxyalkylene group is a homopolymer, a random copolymer, or a block copolymer comprising about 5 to about 250 C2-C4 oxyalkylene units. 41. The polymer of claim 31 wherein the monomer mixture includes a semihydrophobic monomer having one of the following chemical formulas: description="In-line Formulae" end="lead"CH2═CH--O--(CH2)a--O--(C3 H6O)b--(C2H4O)c--H ordescription="In-line Formulae" end="tail" description="In-line Formulae" end="lead"CH2═CH--CH2--O--(C3H6 O)d--(C2H4O)e--H;description="In-line Formulae" end="tail" wherein a is 2, 3, or 4; b is an integer in the range of 1 to about 10; c is an integer in the range of about 5 to about 50; d is an integer in the range of 1 to about 10; and e is an integer in the range of about 5 to about 50. 42. The polymer of claim 31 wherein the monomer mixture includes about 0.1 to about 2% of a crosslinking monomer. 43. The polymer of claim 42 wherein the crosslinking monomer is an acrylate ester of a polyol having at least two acrylate ester groups, a methacrylate ester of a polyol having at least two methacrylate ester groups or a combination thereof. 44. A polymer of claim 31 wherein the monomer mixture includes about 0.1 to about 2% of a chain transfer agent. 45. A polymer of claim 44 wherein the chain transfer agent is selected from a thio compound, a disulfide compound, a phosphite, a hypophosphite, a haloalkyl compound, and a combination thereof. 46. An alkali-soluble associative polymer that is the product of polymerization of a monomer mixture comprising, on a total monomer mixture weight basis: (a) about 10 to about 30 weight percent of at least one acidic vinyl monomer or a salt thereof; (b) more than 60 weight percent of at least one nonionic vinyl monomer; (c) about 0.5 to about 5 weight percent of at least one associative monomer having a hydrophobic end group; (d) about 0.5 to about 5 weight percent of at least one semihydrophobic monomer having a polymerizable, unsaturated end group and a polyoxyalkylene group covalently bonded thereto; and (e) about 0.5 to about 5 weight percent of a chain transfer agent; wherein said at least one associative monomer is selected from a monomer of the formula: wherein, each R2 is independently H, methyl,--C(O)OH, or--C(O)OR3; R3 is C1-C30 alkyl; A is--CH2C(O)O--,--C(O)O--,--O--,--CH2O--,--NHC(O)NH--,--C(O)NH--,--Ar--(CE2)z--NHC(O)O--,--Ar--(CE2)z--NHC(O)NH--, or--CH2CH2NHC(O)--; Ar is a divalent aryl; E is H or methyl; z is 0 or 1; k is an integer in the range of 0 to about 30, and m is 0 or 1, with the proviso that when k is 0, m is 0, and when k is in the range of 1 to about 30, m is 1; (R4--O)n is a polyoxyalkylene, which is a homopolymer, a random copolymer, or a block copolymer of C2-C4 oxyalkylene units, wherein R4 is C2H4, C3H6, C4H8, and n is an integer in the range of about 5 to about 250, Y is--R4O--,--R4NH--,--C(O)--,--C(O)NH--,--R4NHC(O)NH--, or--C(O)NHC(O)--; and R5 is a substituted or unsubstituted alkyl selected from a C8-C40 linear alkyl, a C8-C40 branched alkyl, a C8-C40 carbocyclic alkyl, a C2-C40 alkyl-substituted phenyl, an aryl-substituted C2-C40 alkyl, and a C8-C80 complex ester; wherein the R5 alkyl group optionally comprises one or more substituents selected from a hydroxyl group, an alkoxyl group, and a halogen group; and said semihydrophobic monomer is selected from at least one monomer of the formulas; wherein, in each of formulas (IV) and (V), each R6 is independently H, C1-C30 alkyl,--C(O)OH, or--C(O)OR7; R7 is C1-C30 alkyl; A is--CH2C(O)O--,--C(O)O--,--O--,--CH2O--,--NHC(O)NH--,--C(O)NH--,--Ar--(CE2)z--NHC(O)O--,--Ar--(CE2)z--NHC(O)NH--, or--CH2CH2NHC(O)--; Ar is a divalent aryl; E is H or methyl; z is 0 or 1; p is an integer in the range of 0 to about 30, and r is 0 or 1, with the proviso that when p is 0, r is 0, and when p is in the range of 1 to about 30, r is 1; (R8--O)v is a polyoxyalkylene, which is a homopolymer, a random copolymer or a block copolymer of C2-C4 oxyalkylene units, wherein R8 is C2H4, C3H6, C4H8, and v is an integer in the range of about 5 to about 250, R9 is H or C1-C4 alkyl; and D is a C8-C30 unsaturated alkyl or a carboxy-substituted C8-C30 unsaturated alkyl. 47. The polymer of claim 46 wherein the acidic vinyl monomer is selected from a carboxylic acid-containing vinyl monomer, a sulfonic acid-containing vinyl monomer, a phosphonic acid-containing vinyl monomer, and a combination thereof. 48. The polymer of claim 46 wherein the acidic vinyl monomer is acrylic acid, methacrylic acid, styrenesulfonic acid, 2-acrylamido-2-methylpropane sulfonic acid, or a combination thereof. 49. The polymer of claim 46 wherein the salt is selected from an alkali metal salt, an alkaline earth metal salt, an ammonium salt, an alkyl-substituted ammonium salt, and a combination thereof. 50. The polymer of claim 46 wherein the nonionic vinyl monomer is selected from a C1-C8 ester of acrylic acid, a C1-C8 ester of methacrylic acid, and a combination thereof. 51. The polymer of claim 46 wherein the nonionic vinyl monomer is selected from ethyl acrylate, methyl methacrylate, and a combination thereof. 52. The polymer of claim 51 wherein the nonionic vinyl monomer comprises a combination of ethyl acrylate and methyl methacrylate in a weight ratio of at least about 2:1, respectively. 53. The polymer of claim 46 wherein the associative monomer comprises a polymerizable, unsaturated end group, a C8-C40 alkyl hydrophobic end group, and a polyoxyalkylene group disposed between and covalently bonded to the unsaturated end group and the hydrophobic end group. 54. The polymer of claim 53 wherein the polyoxyalkylene group of the associative monomer is a homopolymer, a random copolymer, or a block copolymer comprising about 5 to about 250 C2-C4 oxyalkylene units. 55. The polymer of claim 46 wherein the polyoxyalkylene group of the semihydrophobic monomer is a homopolymer, a random copolymer, or a block copolymer comprising about 5 to about 250 C2-C4 oxyalkylene units. 56. The polymer of claim 46 wherein the semihydrophobic monomer is a compound having one of the following chemical formulas: description="In-line Formulae" end="lead"CH2═CH--O--(CH2)a--O--(C3 H6O)b--(C2H4O)c--H ordescription="In-line Formulae" end="tail" description="In-line Formulae" end="lead"CH2═CH--CH2--O--(C3H6 O)d--(C2H4O)e--H;description="In-line Formulae" end="tail" wherein a is 2, 3, or 4; b is an integer in the range of 1 to about 10; c is an integer in the range of about 5 to about 50; d is an integer in the range of 1 to about 10; and e is an integer in the range of about 5 to about 50. 57. The polymer of claim 46 wherein the chain transfer agent is selected from a thio compound, a disulfide compound, a phosphite, a hypophosphite, a haloalkyl compound, and a combination thereof.