초록

A fluoropolymer having pendant amidoxime groups, pendant amidrazone groups, or combinations thereof is provided. Also provided are methods of making such fluoropolymers, and compositions and articles containing such fluoropolymers.

대표청구항 ▼

What is claimed is: 1. A fluoropolymer comprising first interpolymerized cure site units, wherein the cure site units have at least one pendant amidoxime group, pendant amidrazone group, or combinations thereof. 2. The fluoropolymer of claim 1, wherein the fluoropolymer comprises interpolymerized

What is claimed is: 1. A fluoropolymer comprising first interpolymerized cure site units, wherein the cure site units have at least one pendant amidoxime group, pendant amidrazone group, or combinations thereof. 2. The fluoropolymer of claim 1, wherein the fluoropolymer comprises interpolymerized units derived from at least one monomer selected from tetrafluoroethylene, chlorotrifluoroethylene, CF2═CF--Rf1, CF2═CF--O--Rf2, CF2═CF--CFX--O--Rf2, and CH═CR2, wherein Rf1 is a perhaloalkyl, Rf2 is perhaloalkyl or a perhaloalkoxyalkyl, X is F or Rf2, and each R is independently selected from the group consisting of hydrogen, a halogen, or an aliphatic group; wherein the aliphatic group(s) may have one or more halogen substituent(s). 3. The fluoropolymer of claim 2, wherein the fluoropolymer comprises interpolymerized units derived from at least one monomer of the formula CF2═CF--Rf1 selected from perfluoromethyl vinyl ether, perfluoroethyl vinyl ether, perfluoropropyl vinyl ether, and combinations thereof. 4. The fluoropolymer of claim 2, wherein the fluoropolymer comprises interpolymerized units derived from at least one monomer of the formula CF2═CF--O--Rf2 selected from CF2═CFOCF2OCF2CF2CF3, CF2═CFOCF2OCF2CF3, CF2═CFOCF2OCF3, CF2═CFO(CF2)3OCF3, CF2═CFOCF2CF2OCF3, and combinations thereof. 5. The composition of claim 2, wherein from about 10 to about 45 mol % of total interpolymerized units present in the fluoropolymer comprise one or more perfluorovinyl ethers. 6. The fluoropolymer of claim 1, further comprising second interpolymerized cure site units, optionally wherein the second interpolymerized cure site units have a reactive group selected from a nitrile group, an imidate group, a pentafluorophenoxy group, bromine, iodine, and combinations thereof. 7. The fluoropolymer of claim 6, wherein the reactive group is a nitrile group, and the molar ratio of the first interpolymerized cure site units to the second interpolymerized cure site units is between about 0.5 and about 2, optionally wherein the molar ratio is between about 0.9 and about 1.1. 8. The fluoropolymer of claim 6, wherein the molar ratio of the first interpolymerized cure site units to the second interpolymerized cure site units is between about 0.25 and about 4. 9. The fluoropolymer of claim 1, wherein the fluoropolymer comprises at least 50 mol % of interpolymerized units derived from at least one of tetrafluoroethylene, chlorotrifluoroethylene, and hexafluoropropylene. 10. The fluoropolymer of claim 1, wherein the fluoropolymer comprises interpolymerized units derived from one or more hydrogen-containing monomers, which may have F or Cl substituents. 11. The fluoropolymer of claim 1, wherein the fluoropolymer comprises interpolymerized units derived from monomers selected from perfluoroolefins, partially-fluorinated olefins, non-fluorinated olefins, vinylidene fluoride, and combinations thereof. 12. The fluoropolymer of claim 1, wherein the amount of interpolymerized units having pendant amidoxime and/or amidrazone groups is between about 0.01 mol % and about 5 mol %. 13. A composition comprising the fluoropolymer of claim 1 and one or more curatives, catalysts, and/or coagents. 14. An article comprising the fluoropolymer of claim 1, optionally wherein the article is a hose, a hose lining, a seal, a gasket, or an O-ring, and optionally wherein the fluoropolymer is at least partially cured. 15. A method of making an article comprising shaping the fluoropolymer of claim 1 and optionally curing the shaped fluoropolymer.