초록 ▼

The present invention relates to a method of removing nitrogen oxides from the exhaust gas of a lean-burn internal combustion engine by selective catalytic reduction (SCR) using ammonia. The exhaust gas is routed first over a platinum-containing pre-catalyst and then over an SCR catalyst. The ammon

The present invention relates to a method of removing nitrogen oxides from the exhaust gas of a lean-burn internal combustion engine by selective catalytic reduction (SCR) using ammonia. The exhaust gas is routed first over a platinum-containing pre-catalyst and then over an SCR catalyst. The ammonia needed for the selective catalytic reduction is added to the exhaust gas upstream of the pre-catalyst at an exhaust-gas temperature below 250�� C., while it is supplied to the exhaust gas between the pre-catalyst and the SCR catalyst at an exhaust gas temperature above 150�� C. By adopting this procedure, a very large temperature range for the selective catalytic reduction with high nitrogen conversion rates is obtained.

대표청구항 ▼

What is claimed is: 1. A method of removing nitrogen oxides from the exhaust gas of a lean-burn internal combustion engine by selective catalytic reduction (SCR) using ammonia, wherein the exhaust gas is routed first over a platinum-containing pre-catalyst and then over an SCR catalyst and the exha

What is claimed is: 1. A method of removing nitrogen oxides from the exhaust gas of a lean-burn internal combustion engine by selective catalytic reduction (SCR) using ammonia, wherein the exhaust gas is routed first over a platinum-containing pre-catalyst and then over an SCR catalyst and the exhaust gas upstream of the pre-catalyst has an exhaust-gas temperature TE, wherein the platinum-containing pre-catalyst includes a filter function for the soot particles contained in the exhaust gas and wherein at an exhaust-gas temperature TE below a predetermined temperature T1, the ammonia is supplied to the exhaust gas either directly or in the form of a compound hydrolyzable to ammonia upstream of the pre-catalyst, and at an exhaust-gas temperature TE above T1, ammonia supply to the exhaust gas is changed from a supply upstream of the pre-catalyst to a supply between the pre-catalyst and the SCR catalyst, wherein when the filter needs to be regenerated, the filter function of the pre-catalyst is regenerated by ammonia being oxidized at the pre-catalyst at an exhaust-gas temperature TA above 300�� C. and the temperature of the pre-catalyst being raised above the soot ignition temperature by the released heat of oxidation. 2. The method according to claim 1, wherein the temperature T1 for changing the ammonia supply is between 220 and 270�� C. 3. The method according to claim 1, wherein the exhaust gas between the pre-catalyst and the SCR catalyst is routed over an additional hydrolysis catalyst and the ammonia or the compound hydrolyzable to ammonia is supplied to the exhaust gas upstream of the hydrolysis catalyst. 4. The method according to claim 1, wherein for oxidation of a possible ammonia leakage, the exhaust gas, after passing the SCR catalyst, is routed over an oxidation-active blocking catalyst. 5. The method according to claim 1, wherein the platinum-containing pre-catalyst includes an additional function for lowering the soot ignition temperature. 6. An exhaust-gas purification system for purifying the exhaust gas of a lean-burn internal combustion engine including a platinum-containing pre-catalyst and a downstream SCR catalyst, through which the exhaust gas successively passes, wherein the pre-catalyst is present in the form of a coating on a particulate filter and wherein a first metering device upstream of the pre-catalyst and a second metering device between the pre-catalyst and the SCR catalyst are provided for supplying ammonia or a compound hydrolyzable to ammonia to the exhaust gas of an internal combustion engine, wherein when the filter needs to be regenerated, the filter of the pre-catalyst is regenerated by ammonia being oxidized at the pre-catalyst at an exhaust-gas temperature above 300�� C. and the temperature of the pre-catalyst being raised above a soot ignition temperature by the released heat of oxidation. 7. The exhaust-gas purification system according to claim 6, wherein the platinum-containing pre-catalyst includes platinum on at least one high surface area support selected from the group consisting of aluminum oxide, silicon oxide, titanium oxide, zirconium oxide, cerium oxide, zeolite or mixtures or mixed oxides thereof. 8. The exhaust-gas purification system according to claim 6, wherein the SCR catalyst includes a solid acid system on the basis of vanadium oxide, tungsten oxide and titanium oxide or vanadium oxide, molybdenum oxide and titanium oxide or on the basis of metal-exchanged zeolites. 9. The exhaust-gas purification system according to claim 6, wherein a hydrolysis catalyst is arranged between the second metering device and the SCR catalyst. 10. The exhaust-gas purification system according to claim 6, wherein a temperature sensor for the temperature of the exhaust gas is arranged upstream of the pre-catalyst. 11. The exhaust-gas purification system according to claim 6, wherein an oxidation catalyst is arranged downstream of the SCR catalyst. 12. The exhaust-gas purification system according to claim 11, wherein the oxidation catalyst is present in the form of a coating on the outlet side of the SCR catalyst and includes platinum on a high surface area support. 13. The exhaust-gas purification system according to claim 12, wherein the pre-catalyst includes platinum on at least one high surface area support selected from the group consisting of aluminum oxide, silicon oxide, titanium oxide, zirconium oxide, cerium oxide, zeolite or mixtures or mixed oxides thereof and additionally comprises components for lowering the ignition temperature of exhaust particulates.