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A method is disclosed to purify a polymeric material by filtering a melt comprising poly(arylene ether) and poly(alkenyl aromatic) through a melt filtration system. The method provides a filtered polymeric composition having reduced levels of particulate impurities. The filtered polymeric compositio

A method is disclosed to purify a polymeric material by filtering a melt comprising poly(arylene ether) and poly(alkenyl aromatic) through a melt filtration system. The method provides a filtered polymeric composition having reduced levels of particulate impurities. The filtered polymeric composition prepared is suitable for use in data storage media applications.

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The invention claimed is: 1. A filtered polymeric composition, wherein the filtered polymeric composition comprises about 90 to about 10 percent by weight of poly(arylene ether) resin and about 10 to about 90 percent by weight of poly(alkenyl aromatic) resin, and wherein the filtered polymeric comp

The invention claimed is: 1. A filtered polymeric composition, wherein the filtered polymeric composition comprises about 90 to about 10 percent by weight of poly(arylene ether) resin and about 10 to about 90 percent by weight of poly(alkenyl aromatic) resin, and wherein the filtered polymeric composition has, based on an average of five sample measurements, at least one of: (a) less than 200 particulates having an average diameter of 20 micrometers per gram of the filtered polymeric material, (b) less than 30 particulates having an average diameter of 30 micrometers per gram of the filtered polymeric material, (c) less than 5 particulates having an average diameter of 50 micrometers per gram of the filtered polymeric material, (d) less than 50 particulates having an average diameter within the range of 20 to 100 micrometers per fifteen grams of the filtered polymeric material, and (e) zero particulates having an average diameter of at least 175 micrometers per gram of the filtered polymeric material. 2. The filtered polymeric composition of claim 1, wherein the poly(arylene ether) comprises at least one of (a) poly(2,6-dimethyl-1,4-phenylene ether) and (b) poly(2,6-dimethylphenylene ether-co-2,3,6-trimethylphenylene ether), and wherein the poly(arylene ether) has an intrinsic viscosity of about 0.10 to about 0.60 deciliters per gram as measured in chloroform at 25�� C.; and wherein the poly(alkenyl aromatic) is at least one of (i) atactic homopolystyrene and (ii) non-elastomeric block copolymer of styrene and one or more polyolefins. 3. A method of purifying a polymeric composition, comprising: melt blending poly(arylene ether) and poly(alkenyl aromatic) in an extruder to form a melt; and melt filtering the melt through a melt filtration system to produce a filtered polymeric composition; wherein the filtered polymeric composition has, based on an average of five sample measurements, at least one of: (a) less than 200 particulates having an average diameter of 20 micrometers per gram of the filtered polymeric material, (b) less than 30 particulates having an average diameter of 30 micrometers per gram of the filtered polymeric material, (c) less than 5 particulates having an average diameter of 50 micrometers per gram of the filtered polymeric material, (d) less than 50 particulates having an average diameter within the range of 20 to 100 micrometers per fifteen grams of the filtered polymeric material, and (e) zero particulates having an average diameter of at least 175 micrometers per gram of the filtered polymeric material. 4. The method of claim 3, wherein the melt filtration system comprises a sintered-metal filter, a metal mesh filter, a fiber metal felt filter, a ceramic filter, or a combination comprising at least one of the foregoing filters. 5. The method of claim 3, wherein the melt filtration system comprises a filter having a geometry that is cone, pleated, candle, stack, flat, wraparound, or a combination comprising at least one of the foregoing geometries. 6. The method of claim 3, wherein the melt filtration system comprises a filter having a pore size of about 1.0 to about 50 micrometers. 7. The method of claim 3, further comprising at least one of: (a) pelletizing the filtered polymeric composition, (b) filtering a solution comprising solvent and poly(arylene ether) through a solution filtration system to form a filtrate, removing solvent from the filtrate to form a concentrate comprising the poly(arylene ether), (c) operating the extruder at a specific throughput rate of about 0.5 kg/cm3 to about 8 kg/cm3, wherein the extruder is a twin-screw extruder, (d) operating the melt filtering wherein the melt has an average residence time in the extruder of less than or equal to about 1 minute, (e) melt blending the melt with an additive selected from the group consisting of flame retardants, mold release agents, lubricants, antioxidants, thermal stabilizers, ultraviolet stabilizers, pigments, dyes, colorants, anti-static agents, conductive agents, and combinations comprising at least one of the foregoing additives, (f) melt blending the melt with an impact modifier, (g) locating the melt filtration system at the die head of the extruder, (h) blanketing of the internal free space of the extruder with an inert gas, (i) using a melt pump, (j) melt filtering under conditions wherein less than a five-fold pressure drop is observed as compared to the initial pressure drop obtained with a clean filtration system, (k) using an in-line or off-line quality monitoring system, (l) cooling the melt with de-ionized filtered water, (m) melt filtering the melt in a Class 100 environment, (n) packaging the filtered polymeric composition in a Class 100 environment, (o) wherein the melt filtration system comprises a by-pass system, and (p) pelletizing the filtered polymeric composition with an underwater die-face pelletizer system or a water ring pelletizer system. 8. The method of claim 3, wherein the poly(arylene ether) comprises at least one of (a) poly(2,6-dimethyl-1,4-phenylene ether) and (b) poly(2,6-dimethylphenylene ether-co-2,3,6-trimethylphenylene ether), and wherein the poly(arylene ether) has an intrinsic viscosity of about 0.10 to about 0.60 deciliters per gram as measured in chloroform at 25�� C. 9. The method of claim 3, wherein the poly(alkenyl aromatic) is at least one of (i) atactic homopolystyrene and (ii) non-elastomeric block copolymer of styrene and one or more polyolefins. 10. A method of purifying a polymeric material, comprising: melt blending about 60 to about 30 weight percent of poly(arylene ether) and about 40 to about 70 weight percent of polystyrene based on the total weight of poly(arylene ether) and polystyrene in an extruder to form a melt; and melt filtering the melt through a melt filtration system to produce a filtered polymeric material, wherein the filtered polymeric material is substantially free of visible particulate impurities, wherein the melt has a residence time in the extruder of less than or equal to about 1 minute, and wherein the poly(arylene ether) comprises at least one of (a) poly(2,6-dimethyl-1,4-phenylene ether) and (b) poly(2,6-dimethylphenylene ether-co-2,3,6-trimethylphenylene ether). 11. An article comprising the filtered polymeric material of claim 1, wherein the article is formed by injection molding, blow molding, extrusion, sheet extrusion, film extrusion, profile extrusion, pultrusion, compression molding, thermoforming, pressure forming, hydroforming, or vacuum forming. 12. A data storage medium comprising the filtered polymeric material prepared by the method of claim 3. 13. A data storage medium comprising a substrate layer, data and a cover layer, wherein the data is located between the substrate layer and the cover layer, wherein the cover layer has a thickness of 100 micrometers or less through which a light source passes to read, write, or read and write the data; wherein the substrate layer comprises a filtered polymeric composition comprising about 90 to about 10 percent by weight of poly(arylene ether) resin and about 10 to about 90 percent by weight of poly(alkenyl aromatic) resin; and less than fifty particulates having average particle diameters within the range of 30 to 100 micrometers. 14. The data storage medium of claim 13, wherein the substrate layer contains no particulates having average particle diameters larger than 175 micrometers. 15. A data storage medium comprising a substrate layer, data and a cover layer, wherein the data is located between the substrate layer and the cover layer, wherein the cover layer has a thickness of 100 micrometers or less through which a light source passes to read, write, or read and write the data; wherein the substrate layer comprises a filtered polymeric composition; wherein the filtered polymeric composition comprises about 90 to about 10 percent by weight of poly(arylene ether) resin and about 10 to about 90 percent by weight of poly(alkenyl aromatic) resin and wherein the filtered polymeric composition has, based on an average of five sample measurements, at least one of: (a) less than 200 particulates having an average diameter of 20 micrometers per gram of the filtered polymeric material, (b) less than 30 particulates having an average diameter of 30 micrometers per gram of the filtered polymeric material, (c) less than 5 particulates having an average diameter of 50 micrometers per gram of the filtered polymeric material, (d) less than 50 particulates having an average diameter within the range of 20 to 100 micrometers per fifteen grams of the filtered polymeric material, and (e) zero particulates having an average diameter of at least 175 micrometers per gram of the filtered polymeric material. 16. The filtered polymeric composition of claim 1, wherein the poly(alkenyl aromatic) is a non-elastomeric block copolymer derived from an alkenyl aromatic monomer having the structure (III) and on or more polyolefins, wherein structure (III) is wherein R1 is hydrogen, C1-C8 alkyl, or halogen; Z1 is C1-C8 alkyl; and p is 0 to 5. 17. The filtered polymeric composition of claim 16, wherein R1 is hydrogen and Z1 is C1 alkyl. 18. The method of claim 3, wherein the poly(alkenyl aromatic) is a non-elastomeric block copolymer derived from an alkenyl aromatic monomer having the structure (III) and one or more polyolefins, wherein structure (III) is wherein R1 is hydrogen, C1-C8 alkyl, or halogen; Z1 is C1-C8 alkyl; and p is 0 to 5. 19. The method of claim 18, wherein R1 is hydrogen and Z1 is C1 alkyl. 20. The data storage medium of claim 15, wherein the poly(alkenyl aromatic) is a non-elastomeric block copolymer derived from an alkenyl aromatic monomer having the structure (III) and one or more polyolefins, wherein structure (III) is wherein R1 is hydrogen, C1-C8 alkyl, or halogen; Z is C1-C8 alkyl; and p is 0 to 5. 21. The data storage medium of claim 20, wherein R1 is hydrogen and Z1 is C1 alkyl. 22. The data storage medium of claim 12, wherein the data storage medium comprises a substrate layer, data and a cover layer. 23. The data storage medium of claim 22, wherein the cover layer comprises a hard coat layer.